Electrochemical Sensor Array for Boar Taint Detection

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Solution Overview

Problem

Current methods for detecting and quantifying boar taint compounds, such as skatole and androstenone, in pork are either non-specific, costly, time-consuming, or require specialized equipment, making them unsuitable for practical applications in the pork industry.

Innovation Solution

A sensor array system utilizing electrochemical or optical methods with 3-hydroxysteroid dehydrogenase and NAD(P)H to detect androstenone and skatole directly in carcasses or live animals, allowing for simultaneous or parallel detection and providing absolute values, which is rapid, precise, and cost-effective.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If traditional detection methods (GC, HPLC, ELISA) are used to detect androstenone and skatole, then measurement precision is improved, but device complexity and cost increase significantly

Engineering Contradiction:
Improvedetection accuracy of androstenone and skatoleVSAvoidcomplexity of detection equipment
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent replaces complex mechanical/chemical laboratory equipment (GC, HPLC, ELISA systems) with an electrochemical sensor system that uses electrode-based detection. The sensor array with multiple electrodes detects androstenone and skatole through electrochemical reactions, eliminating the need for complex chromatography or immunological equipment while maintaining detection capability.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent employs disposable screen-printed electrodes that can be discarded after single use. These inexpensive, pre-fabricated electrodes replace expensive, reusable laboratory equipment. Each electrode contains the necessary enzymatic layers for detection, and after one measurement, the entire electrode assembly is discarded, eliminating cleaning, calibration, and maintenance of complex equipment.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Measurement precision

If traditional detection methods are used, then measurement precision is improved, but detection time increases

Engineering Contradiction:
Improvedetection accuracy of androstenone and skatoleVSAvoiddetection time
Core Design Contradiction:
Measurement precisionVSLoss of time

Solution Approach 1:

The electrodes are pre-prepared with enzymatic layers (acetylcholinesterase, butyrylcholinesterase, or choline oxidase) immobilized on the surface before use. This preliminary preparation of the detection surface allows immediate detection upon contact with the sample, eliminating time-consuming sample preparation steps required by traditional methods.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent replaces time-consuming chromatographic separation and immunological assay procedures with direct electrochemical detection. The electrochemical sensor provides real-time measurement within seconds or minutes, compared to the hours required by GC, HPLC, or ELISA methods.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Measurement precision

If traditional detection methods are used, then measurement precision is improved, but cost increases

Engineering Contradiction:
Improvedetection accuracy of androstenone and skatoleVSAvoidcost of detection system
Core Design Contradiction:
Measurement precisionVSEase of manufacture

Solution Approach 1:

The patent uses inexpensive screen-printed electrodes that can be manufactured at low cost using printable electronics techniques. These disposable electrodes replace expensive laboratory equipment, reducing both capital investment and per-test costs. The electrodes are fabricated using screen printing of conductive inks on flexible substrates, enabling mass production at scale.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent replaces costly laboratory instrumentation (gas chromatographs, HPLC systems, ELISA readers) with simple electrochemical measurement devices. The electrochemical sensor system requires only basic voltage application and current measurement circuitry, dramatically reducing equipment cost while maintaining detection precision through the specificity of enzymatic-electrochemical reactions.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

4Ease of operation

If simple detection methods are used, then ease of operation is improved, but measurement precision deteriorates

Engineering Contradiction:
Improvesimplicity of detection procedureVSAvoiddetection accuracy of androstenone and skatole
Core Design Contradiction:
Ease of operationVSMeasurement precision

Solution Approach 1:

The patent employs enzymatic intermediaries (acetylcholinesterase, butyrylcholinesterase, or choline oxidase) that specifically catalyze reactions with androstenone and skatole. These enzymes act as selective mediators between the target analytes and the electrochemical detection system, providing both operational simplicity and measurement precision through their high substrate specificity.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent develops a universal sensor array platform that can detect multiple compounds (androstenone and skatole) simultaneously using the same basic electrochemical detection system. Different enzyme coatings on different electrodes provide multi-functionality, allowing a single device to perform multiple detection tasks with equal precision and simplicity.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables efficient and cost-effective detection and monitoring of boar taint compounds, preventing tainted carcasses from entering the food chain and allowing for premium quality grading, addressing the limitations of existing methods by providing a practical and reliable solution.

Implementation Method 1

3-hydroxysteroid dehydrogenase and NAD(P)H to detect androstenone

Methodology Applied
Scientific EffectEnzyme catalysis: Enzyme

Implementation Method 2

NAD(P)H to detect androstenone

Methodology Applied
Scientific EffectRedox reaction: Redox Reactions

Implementation Method 3

electrochemical or optical methods to detect androstenone and skatole

Methodology Applied
Scientific EffectElectrochemical detection:

Implementation Method 4

electrochemical or optical methods to detect androstenone and skatole

Methodology Applied
Scientific EffectOptical detection:

Data Source

PatentEP2966441B1Sensor and method for detecting androstenone or skatole in boar taint
Publication Date: 2017.07.26 UNIV OF THE WEST OF ENGLAND BRISTOL
  • EP2966441B1 patent drawingFigure 1~2
  • EP2966441B1 patent drawingFigure 3~4
  • EP2966441B1 patent drawingFigure 5~6

AI summary

The present application is concerned with a sensor system for and a method of detecting, and preferably quantifying, androstenone (CAS Reg.No. 18339-16-7) and/or skatole (CAS Reg. No. 83-34-1), the chemicals associated with boar taint. In a preferred embodiment, the sensor system comprises an array comprising (i) an enzyme electrode based on 3-hydroxysteroid dehydrogenase (3-HSD) which metabolises androstenone in the presence of cofactor NAD(P)H, together with a mediator, eg. Meldola's Blue (CAS Reg.No. 7057-57-0); and (ii) a sensor for the voltammetric detection of skatole, especially via direct oxidation at an electrode. The sensor system can be used to detect and quantify boar taint in pig carcasses or live pigs and so can be used to prevent the entrance of tainted carcasses into the food chain and to allow the grading of carcasses as "premium quality".