Electrochemical Gas Sensor Testing via Multiplexed AC-DC Signals

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Solution Overview

Problem

Electrochemical gas sensors often fail due to electrolyte drying or contamination, leading to undetected failures as the signal for non-functionality resembles the absence of gas, and existing testing methods are either invasive, time-consuming, or require additional circuits.

Innovation Solution

An electrochemical gas sensor testing device that applies a multiplexed signal with alternating current (AC) and direct current (DC) components, using existing circuitry to assess the sensor's functionality without interrupting gas detection, employing a processor to analyze AC signals and compare them to stored values for determining cell viability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a dedicated test circuit is used to test the electrochemical cell, then the reliability of cell testing is improved, but the device complexity increases

Engineering Contradiction:
Improvecell testing reliabilityVSAvoidcircuit complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent combines the gas detection function and the cell testing function into a single integrated circuit. The same circuit that detects gas concentrations during normal operation is also used to apply test signals and evaluate cell health, eliminating the need for separate dedicated test circuits while maintaining testing reliability

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The circuit is designed to perform multiple functions: it operates as a gas detection circuit during normal monitoring and automatically switches to a cell testing mode when needed. This multi-functionality allows the single circuit to both detect gas concentrations and assess electrochemical cell viability without requiring additional specialized hardware

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Reliability

If a bump test is performed to verify sensor functionality, then the reliability of gas detection is improved, but the loss of time increases

Engineering Contradiction:
Improvegas detection reliabilityVSAvoidtesting time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

Instead of requiring manual bump tests at scheduled intervals, the system automatically performs brief electrical impedance measurements at regular intervals. These periodic automated tests continuously monitor cell health without requiring the time-consuming manual exposure to test gas mixtures, significantly reducing the time loss while maintaining detection reliability

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

The system performs preliminary automated impedance checks continuously in the background during normal operation. By proactively monitoring cell health through these preliminary actions, the system can detect degradation trends before they lead to failure, eliminating the need for time-consuming reactive bump tests

Inventive Principle:
Principle #10Preliminary action

3Reliability

If the electrochemical cell is tested frequently to detect failures early, then the reliability is improved, but the productivity decreases due to interruptions

Engineering Contradiction:
Improvesensor functionality reliabilityVSAvoidgas detection productivity
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The circuit maintains continuous gas detection functionality while performing cell health assessments. The testing is integrated into the normal operation flow, allowing the system to continuously monitor both gas concentrations and cell viability without stopping the useful gas detection function, thus maintaining productivity while improving reliability through frequent testing

Inventive Principle:
Principle #20Continuity of useful action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables automatic, non-invasive testing of electrochemical gas sensors to detect failures without disrupting gas detection, using existing bias voltage circuits and allowing for continuous operation, thereby preventing unnoticed sensor failures.

Implementation Method 1

applying an alternating current test signal and a direct current bias voltage to a counter electrode of an electrochemical gas sensor... transmitting the AC test signal from the sensing electrode to a processor, analyzing the AC signal received by the processor

Methodology Applied
Scientific EffectElectrochemical impedance:

Implementation Method 2

when a gas dissolves into the electrolyte, an oxidation reaction occurs at one electrode and a reduction reaction occurs at the other electrode. This is referred to as the 'redox' reaction. Electrons flow from the oxidizing electrode to the reducing electrode. This electron flow (i.e., electrical current) is then measured

Methodology Applied
Scientific EffectRedox reaction: Redox Reactions

Data Source

PatentUS9057690B2Device for monitoring an electrochemical gas sensor
Publication Date: 2015.06.16 SENSOR ELECTRONICS CORP
  • US9057690B2 patent drawing
  • US9057690B2 patent drawing
  • US9057690B2 patent drawing

AI summary

An electrochemical gas sensor testing device that includes a test signal generator that generates a multiplexed signal that includes a first test signal that includes alternating current (AC) and is free from a direct current (DC) component and a second signal that includes a DC bias voltage, an electrochemical cell that includes a counter electrode, a sensing electrode, and an electrolyte, the counter electrode and the sensing electrode being in electrical communication with the electrolyte and each other, the counter electrode being in electrical communication with the signal generator to receive the multiplexed signal generated by the signal generator, and a processor that receives an AC signal from the sensing electrode and that analyzes the AC signal.