Electrochromic Display Charge Retention Layer

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Solution Overview

Problem

Existing electrochromic display elements face challenges in achieving high white reflectance and contrast ratio while maintaining multicolor display capabilities, often resulting in low visibility due to color filter absorption and image blurring issues, and are prone to electrode erosion.

Innovation Solution

An electrochromic display element with a charge retention layer formed from a mixed film of polymer and conductive microparticles, combined with an electrolyte layer and multiple electrochromic layers, which enhances color development and dissipation efficiency, reduces voltage requirements, and improves durability by preventing charge diffusion.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If color filters are used to display multiple colors, then color display capability is improved, but white reflectance and contrast ratio are significantly lowered

Engineering Contradiction:
Improvecolor display capabilityVSAvoidwhite reflectance
Core Design Contradiction:
Adaptability or versatilityVSIllumination intensity

Solution Approach 1:

The patent employs electrochromic compounds that can reversibly change color through redox reactions when voltage is applied. Different electrochromic compounds or layers are used to achieve different colors (e.g., blue, red, green), eliminating the need for traditional light-absorbing color filters while maintaining high white reflectance in the uncolored state.

Inventive Principle:
Principle #32Color changes

Solution Approach 2:

The patent uses composite structures combining multiple electrochromic layers with different compounds (e.g., viologen for blue, phenothiazine for red, spirooxazine for green) to achieve multicolor display. This composite approach allows each layer to contribute its color-changing property without the light absorption penalties of conventional color filters.

Inventive Principle:
Principle #40Composite materials

2Adaptability or versatility

If each pixel is divided into three color parts (R, G, B) with color filters, then color display is improved, but reflectance is significantly lowered

Engineering Contradiction:
Improvecolor displayVSAvoidreflectance
Core Design Contradiction:
Adaptability or versatilityVSIllumination intensity

Solution Approach 1:

The patent changes the fundamental mechanism from passive color filtering to active color generation through electrochemical reactions. By controlling the oxidation state of electrochromic compounds via applied voltage, the display can dynamically generate colors without absorbing ambient light, thereby maintaining high reflectance while achieving full-color display capability.

Inventive Principle:
Principle #35Parameter changes

3Speed

If low resistance films with high conductivity are used, then switching speed is improved, but electrode erosion increases

Engineering Contradiction:
Improveswitching timeVSAvoidelectrode durability
Core Design Contradiction:
SpeedVSReliability

Solution Approach 1:

The patent employs porous insulating films with controlled pore structures that allow efficient ion transport while providing physical protection to the electrode interfaces. The porous structure increases surface area for electrochemical reactions, enabling fast switching without requiring high electrode conductivity that would lead to erosion.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The patent introduces insulating films as intermediary layers between conductive electrodes and electrolyte solutions. These films act as protective barriers that prevent direct contact and erosion of electrodes while maintaining ionic conductivity through their porous structures, thus decoupling the conflicting requirements of speed and durability.

Inventive Principle:
Principle #24Intermediary (Mediator)

4Manufacturing precision

If charge retention layer is formed to prevent charge diffusion, then image definition is improved, but manufacturing complexity increases

Engineering Contradiction:
Improveimage definitionVSAvoidlayer structure
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent designs porous insulating films that simultaneously serve multiple functions: preventing charge diffusion to maintain image definition, facilitating ion transport for electrochromic switching, and protecting electrode interfaces. This multi-functionality reduces the need for separate dedicated layers, thereby limiting the increase in manufacturing complexity despite improved image definition.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enables high-definition, multicolor display with improved durability and reduced manufacturing costs, maintaining excellent display quality and resolution without increasing manufacturing costs.

Implementation Method 1

Electrochromism is a phenomenon displayed by specific materials of reversibly changing optical properties when an amount of voltage is applied to the materials

Methodology Applied
Scientific EffectElectrochromism: Electrochromism

Implementation Method 2

chemical compounds, which induce a reversible redox reaction to reversibly change their colors when a voltage is applied to the chemical compounds

Methodology Applied
Scientific EffectRedox reaction: Redox Reactions

Implementation Method 3

a charge retention layer formed of an insulating film having a porosity of 10% or more and a resistivity of 1.0E+05 ohm·cm or less

Methodology Applied
Scientific EffectElectrical Resistance: Electrical Resistance

Implementation Method 4

an insulating film having a porosity of 10% or more and a resistivity of 1.0E+05 ohm·cm or less

Methodology Applied
Scientific EffectPorosity: Porosity

Data Source

PatentUS8743048B2Electrochromic display element, display device and information apparatus
Publication Date: 2014.06.03 RICOH CO LTD
  • US8743048B2 patent drawing
  • US8743048B2 patent drawing
  • US8743048B2 patent drawing

AI summary

A disclosed electrochromic display element includes a display substrate, a counter substrate facing the display substrate, display electrodes arranged between the display substrate and the counter substrate, electrochromic layers formed on the respective display electrodes, a plurality of drive elements arranged on the counter substrate at predetermined intervals, a plurality of pixel electrodes arranged on the drive elements, a charge retention layer formed over the pixel electrodes as a continuous layer, the charge retention layer being formed of a mixed film including a polymer and one of electric conductive microparticles and semiconductor microparticles, and an electrolyte layer sandwitched between the display substrate and the charge retention layer.