Electrochromic Material Red Color Stability

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Solution Overview

Problem

Current electrochromic devices lack red electrochromic materials, which are essential for achieving full-color displays, and organic electrochromic materials have limitations in long-term stability compared to inorganic materials.

Innovation Solution

Development of a novel electrochromic material represented by Formula 1, which can produce a red color when a voltage is applied, and its integration into an electrochromic device structure with transparent and opposite electrodes to form a functional electrochromic layer.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If organic electrochromic materials are used, then flexibility and ease of thin film formation are improved, but long-term stability deteriorates

Engineering Contradiction:
ImproveflexibilityVSAvoidlong-term stability
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent employs a composite material strategy by combining the organic electrochromic compound (Formula 1) with an inorganic electrochromic material (tungsten oxide, molybdenum oxide, or their alloys) in the electrochromic layer. This composite structure allows the device to inherit the flexibility and thin film formation capability from the organic component while gaining the long-term stability from the inorganic component, thus resolving the contradiction between flexibility and stability.

Inventive Principle:
Principle #40Composite materials

2Adaptability or versatility

If red electrochromic materials are developed, then full-color display capability is improved, but material discovery difficulty increases

Engineering Contradiction:
Improvefull-color display capabilityVSAvoidmaterial discovery difficulty
Core Design Contradiction:
Adaptability or versatilityVSDifficulty of detecting and measuring

Solution Approach 1:

The patent achieves red electrochromic color by systematically varying the molecular structure parameters of the organic compound, specifically by changing the substituents (R1, R2, R3) at different positions of the core molecular framework. By adjusting these structural parameters, the patent successfully tuned the electrochromic color to red while maintaining the benefits of organic materials, thus achieving full-color display capability without excessive discovery difficulty.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If inorganic electrochromic materials are used, then long-term stability is improved, but flexibility and thin film formation capability deteriorate

Engineering Contradiction:
Improvelong-term stabilityVSAvoidflexibility
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent creates a composite electrochromic layer that integrates inorganic electrochromic materials (tungsten oxide, molybdenum oxide, or their alloys) with organic electrochromic compounds. The inorganic component provides the necessary long-term stability, while the organic component and the overall composite structure enable flexibility and ease of thin film formation through wet processing techniques, thus resolving the contradiction between stability and flexibility.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The electrochromic device using the novel material can change colors in response to applied voltages, achieving red and other colors effectively, enhancing the potential for full-color displays and overcoming stability issues of organic materials.

Implementation Method 1

Electrochromism is the phenomenon displayed by some chemical species which have a reversibly changeable color when a voltage is applied thereto. A material capable of undergoing reversible changes of optical properties by the electrochemical redox reaction accompanying such electrochromic properties is called an electrochromic material.

Methodology Applied
Scientific EffectElectrochromism: Electrochromism

Implementation Method 2

A material capable of undergoing reversible changes of optical properties by the electrochemical redox reaction accompanying such electrochromic properties is called an electrochromic material.

Methodology Applied
Scientific EffectElectrochemical redox reaction: Redox Reactions

Data Source

PatentUS8970937B2Electrochromic materials and electrochromic devices using the same
Publication Date: 2015.03.03 SAMSUNG ELECTRONICS CO LTD
  • US8970937B2 patent drawing
  • US8970937B2 patent drawing
  • US8970937B2 patent drawing

AI summary

Disclosed herein are novel electrochromic materials. The electrochromic materials produce various colors. The electrochromic materials can be used to form red electrochromic layers in a simple manner. Therefore, the electrochromic materials are suitable for use in the fabrication of RGB full-color electrochromic devices. Also disclosed herein are electrochromic devices fabricated using the electrochromic materials.