Electrochromic Device Scribe Structure Reduces Leakage

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Solution Overview

Problem

Electrochromic devices face issues with intrinsic electronic leakage and electronic breakdown due to lateral migration of charge compensating ions, leading to potential short circuits, and the deposition process is inefficient for mass production due to vacuum cycling and dust-related defects.

Innovation Solution

The electrochromic device design includes wider scribed channels between transparent conductive layers to prevent ion migration and incorporates a method for depositing layers in a single continuous vacuum step with minimal laser processing, reducing electronic leakage and increasing yield by ensuring the channel width exceeds the ion migration length.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If the scribe width is increased to prevent ion migration and electronic leakage, then the reliability of the device is improved, but the manufacturing complexity and difficulty of laser processing increase

Engineering Contradiction:
Improveelectronic leakage preventionVSAvoidscribe structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies segmentation by dividing the scribe structure into multiple discrete channels separated by ridges. Instead of a single wide scribe, the lower transparent conductive layer is segmented into multiple segments with intervening ridges between them. This segmentation prevents ion migration while maintaining manufacturability, as each channel can be processed independently and the ridges provide natural barriers to ion diffusion paths.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent introduces a third dimension by creating raised ridges between the scribe channels. Rather than simply increasing the two-dimensional scribe width, the solution adds vertical dimension with ridges that extend upward from the substrate. This dimensional change provides effective ion blocking without proportionally increasing the horizontal footprint or laser processing complexity, as the ridges can be formed through controlled deposition or etching processes.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

2Manufacturing precision

If multiple vacuum cycling steps are used for layer deposition, then the manufacturing precision can be maintained, but the productivity and yield decrease due to dust-related defects

Engineering Contradiction:
Improvelayer deposition qualityVSAvoidmass production yield
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent merges multiple deposition steps into a single continuous vacuum process. All layers including the lower transparent conductive layer, electrochromic layers, ion conductor layers, and upper transparent conductive layer are deposited without breaking vacuum. This combining of steps eliminates dust contamination from vacuum cycling while maintaining manufacturing precision through controlled in-situ deposition processes and laser scribing performed within the same vacuum environment.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent ensures continuity of the deposition action by maintaining vacuum throughout the entire manufacturing process. The useful action of layer deposition continues uninterrupted without vacuum breaks, and laser scribing operations are performed continuously within the vacuum chamber. This continuous process eliminates the start-stop nature of multiple vacuum cycles, preventing dust contamination and improving yield while maintaining the precision required for functional layers.

Inventive Principle:
Principle #20Continuity of useful action

3Reliability

If laser scribing is performed to create isolation channels, then the electronic leakage is reduced, but the device complexity and processing difficulty increase

Engineering Contradiction:
Improveelectronic leakage preventionVSAvoidlaser processing difficulty
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent applies local quality by concentrating laser processing only in specific localized regions where scribing is needed, rather than processing the entire device uniformly. The laser creates precise isolation channels and ridges only at the busbar regions and between conductive segments, leaving the functional electrochromic areas untouched. This localized approach reduces overall processing difficulty and time while maintaining effective electronic leakage prevention at critical locations.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent introduces ridges as intermediary structures between the scribe channels. These ridges act as mediators that provide ion blocking functionality without requiring deep or wide scribes. The ridges can be formed through controlled material deposition or partial etching, serving as intermediate structures that simplify the laser processing requirements compared to creating deep isolation channels, while still effectively preventing ion migration and electronic leakage.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This design effectively reduces electronic leakage and enhances the yield of electrochromic devices by maintaining electrical isolation and minimizing defects, allowing for more efficient mass production while maintaining visual appeal and performance.

Implementation Method 1

two transparent conductive layers ('TCLs') 11 and 15 which serve to apply an electrical potential to the electrochromic device

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Implementation Method 2

an electrochromic electrode layer ('EC') 14 which produces a change in absorption or reflection upon oxidation or reduction

Methodology Applied
Scientific EffectElectrochromism: Electrochromism

Implementation Method 3

an ion conductor layer ('IC') 13 which functionally replaces an electrolyte, allowing the passage of ions while blocking electronic current

Methodology Applied
Scientific EffectIonic conduction: Conduction (electrical)

Implementation Method 4

charge compensating ions can migrate laterally (i.e., sideways in FIG. 2) in the layer according to the usual laws of diffusion

Methodology Applied
Scientific EffectDiffusion: Diffusion

Data Source

PatentUS9152001B2Electrochromic devices having improved structure for reducing current leakage across lower transparent conductor layers
Publication Date: 2015.10.06 SAGE ELECTROCHROMICS INC
  • US9152001B2 patent drawing
  • US9152001B2 patent drawing
  • US9152001B2 patent drawing

AI summary

One object of the present invention is to provide an electrochromic device having improved insulating film structure to reduce electrical leakage. The improved structure includes a lower conductive layer, upper transparent conductive layer, an electrochromic electrode layer, a counter electrode layer, and at least one ion-conductor layer sandwiched between the electrochromic electrode layer and the counter electrode layer. The lower transport conductive layer is scribed and the gap formed from the scribing is filled with the layer(s) formed above the lower conductive layer, such as the electrode layer formed directly above the lower conductive layer. The effective linewidth of the scribe is greater than the migration length of the lithium ions intercalated into the electrode layer, such that the electrode materials occupying the gap do not convert the electrode layer into an electrically conductive region.