Water-Soluble Electroconductive Binder for Lithium Battery

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Solution Overview

Problem

Current lithium batteries face challenges in achieving high capacity and long lifetime due to limitations in electrode materials and binders, which affect the electrical conductivity and binding strength of active materials to current collectors.

Innovation Solution

A water-soluble electroconductive polymer with a carboxylate functional group is used as a binder for lithium battery electrodes, providing high electrical conductivity and strong binding strength while being environmentally friendly and compatible with aqueous processes, potentially allowing for a higher active material loading and improved electrode performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional binders are used for lithium battery electrodes, then manufacturing process is simple, but electrical conductivity and binding strength are insufficient

Engineering Contradiction:
Improveelectrical conductivity and binding strengthVSAvoidmanufacturing process complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent modifies the chemical structure of the binder by introducing carboxylate functional groups into the polymer chain, which fundamentally changes the binding mechanism and electrical conductivity properties. This chemical parameter change enables the binder to achieve both high conductivity and strong binding strength simultaneously

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a composite binder system combining electroconductive polymer backbone with carboxylate functional groups, creating a multi-functional material that integrates binding, conducting, and stabilizing properties in a single component, thereby improving reliability without significantly complicating manufacturing

Inventive Principle:
Principle #40Composite materials

2Quantity of substance

If higher capacity active materials are used, then battery capacity increases, but binding strength and stability deteriorate

Engineering Contradiction:
Improvebattery capacityVSAvoidbinding strength and stability
Core Design Contradiction:
Quantity of substanceVSStability of the object's composition

Solution Approach 1:

The patent applies local quality enhancement by introducing carboxylate functional groups at specific positions along the polymer chain, creating localized high-binding-strength zones that anchor active materials effectively. This localized modification allows the use of higher capacity materials while maintaining overall structural stability

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The chemical composition parameter of the binder is changed by incorporating carboxylate groups, which alter the interaction mechanism between binder and active material. This enables stable binding even when using higher capacity materials that typically challenge conventional binder performance

Inventive Principle:
Principle #35Parameter changes

3Reliability

If conducting agents are added to improve electrical conductivity, then electrical conductivity improves, but device complexity and manufacturing difficulty increase

Engineering Contradiction:
Improveelectrical conductivityVSAvoidelectrode composition complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent merges the functions of binder and conducting agent into a single integrated material. The electroconductive polymer with carboxylate groups simultaneously provides binding strength and electrical conductivity, eliminating the need for separate conducting agent additives and simplifying electrode composition

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The binder material achieves multi-functionality by combining the binding function with electrical conduction function in one material system. This universal binder replaces multiple specialized additives, reducing device complexity while maintaining or improving electrical conductivity

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of this binder enhances the electrical conductivity and binding strength of lithium battery electrodes, leading to increased capacity and stability, with the potential for reduced conducting agent usage and improved manufacturing compatibility with water-based processes.

Implementation Method 1

a water-soluble electroconductive polymer having a carboxylate functional group in a main chain

Methodology Applied
Scientific EffectElectrical conductivity: Conduction (electrical)

Implementation Method 2

the water-soluble electroconductive polymer may be self-doped with the carboxylate functional group

Methodology Applied
Scientific EffectSelf-doping: Dopants

Implementation Method 3

providing high electrical conductivity and strong binding strength

Methodology Applied
Scientific EffectAdhesion: Adhesive

Data Source

PatentUS9231253B2Binder for electrode of lithium battery, binder composition including the binder, and lithium battery containing the binder
Publication Date: 2016.01.05 SAMSUNG SDI CO LTD
  • US9231253B2 patent drawing

AI summary

In an aspect, a binder for a lithium battery electrode, a binder composition including the binder, and a lithium battery including the binder are provided. The binder may include a water-soluble electroconductive polymer having a carboxylate functional group.