Electrode Assembly Composition for Higher Lithium-Ion Energy Density

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Solution Overview

Problem

Lithium ion batteries have a lower energy density, making them inadequate for meeting the increasing demands of portable electronic devices and electric vehicles, which requires improved performance and endurance.

Innovation Solution

An electrode assembly is designed with a positive electrode plate containing a quinone compound and a negative electrode plate with a conductive polymer material, optimizing the mass content and capacity ratios to enhance lithium storage and kinetic performance, thereby increasing the energy density of lithium ion batteries.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If conventional electrode materials are used, then the battery structure is simple and easy to manufacture, but the energy density is low and cannot meet increasing demands

Engineering Contradiction:
Improveenergy densityVSAvoidelectrode structure complexity
Core Design Contradiction:
Quantity of substanceVSDevice complexity

Solution Approach 1:

The patent applies composite materials by combining quinone compounds with conventional positive electrode active materials (such as lithium iron phosphate, lithium cobalt oxide, or lithium nickel cobalt manganese oxide) and conductive polymer materials with negative electrode active materials (such as graphite or lithium titanate). This composite approach increases energy density while maintaining manageable structural complexity through systematic formulation.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent implements parameter changes by precisely controlling the mass content ratios of quinone compounds (0.5-3% of positive electrode active material mass) and conductive polymer materials (specific mass percentages in negative electrode), as well as controlling areal densities of electrode active material layers. These parameter optimizations enable energy density improvement while keeping the electrode structure manufacturable.

Inventive Principle:
Principle #35Parameter changes

2Quantity of substance

If quinone compound and conductive polymer are added to increase energy density, then lithium storage capacity and kinetic performance improve, but electrode formulation and manufacturing precision requirements increase

Engineering Contradiction:
Improvelithium storage capacityVSAvoidmass content control precision
Core Design Contradiction:
Quantity of substanceVSManufacturing precision

Solution Approach 1:

The patent establishes specific parameter ranges for quinone compound mass content (0.5-3% relative to positive electrode active material) and conductive polymer mass content (specific percentages relative to negative electrode active material), along with areal density ranges for electrode active material layers. These defined parameters provide clear manufacturing targets that balance performance improvement with manufacturability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies local quality by specifying different mass content requirements for different components: quinone compounds at 0.5-3% in the positive electrode active material layer, conductive polymer materials at specific mass percentages in the negative electrode active material layer, and controlled areal densities for different electrode layers. This localized optimization enables precise control over lithium storage capacity while maintaining manufacturing feasibility through component-specific formulation guidelines.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The cooperative control of quinone compound and conductive polymer proportions in the electrode assembly significantly improves the energy density of lithium ion batteries, enhancing their performance and endurance in power-consuming devices.

Implementation Method 1

the quinone compound comprised in the positive electrode active material layer of the positive electrode plate of the present application provides additional lithium intercalation vacancies to increase the lithium storage capacity of the positive electrode plate

Methodology Applied
Scientific EffectIntercalation: Absorption (physical)

Implementation Method 2

the conductive polymer material comprised in the negative electrode active material layer is used to improve the kinetic performance of the negative electrode plate and increase the content of lithium de-intercalated from the lithium ion battery during discharging

Methodology Applied
Scientific EffectDe-intercalation: Desorption

Data Source

PatentUS11791460B2Electrode assembly, secondary battery, battery module, battery pack and power consuming device
Publication Date: 2023.10.17 CONTEMPORARY AMPEREX TECHNOLOGY (HONG KONG) LIMITED
  • US11791460B2 patent drawing
  • US11791460B2 patent drawing

AI summary

An electrode assembly may comprise a positive electrode plate and a negative electrode plate, wherein a positive electrode active material layer of the positive electrode plate may comprise a positive electrode active material and a quinone compound; and a negative electrode active material layer of the negative electrode plate may comprise a negative electrode active material and a conductive polymer material, wherein based on the mass of the positive electrode active material layer, the mass content of the quinone compound mc % may be 0.5% to 3%; the capacity per gram of the quinone compound may be Capc; the capacity per gram of the positive electrode active material may be Cap; and based on the mass of the negative electrode active material layer, the mass content of the conductive polymer material may be mA %, satisfying the relationship of:0.2≤C⁢a⁢pC-CapCap×mC/mA≤5.