Water Electrolysis Catalyst Ink Hansen Solubility Control

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

In water electrolysis, the aggregation of catalyst materials in electrode catalyst ink leads to clogging issues and uneven film thickness, resulting in variations in electrode performance, increased manufacturing costs, and reduced productivity, due to inadequate dispersibility of catalysts in the ink.

Innovation Solution

The electrode catalyst ink includes a layered double hydroxide, an organic polymer, and a solvent with specific Hansen solubility parameter distances, ensuring optimal affinity and dispersibility by adjusting the solvent's compatibility with both the catalyst and the organic polymer, preventing aggregation and maintaining good dispersion.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If catalyst materials are used in electrode catalyst ink without controlling solvent affinity, then catalyst activity is achieved, but aggregation occurs leading to clogging and uneven film thickness

Engineering Contradiction:
Improvecatalyst activityVSAvoidfilm thickness uniformity
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent applies parameter changes by controlling the Hansen solubility parameter distance between solvent and catalyst within a specific range (15.0 ≤ Ra1 < 20.5 MPa^1/2) and between solvent and organic polymer (10.0 ≤ Ra2 ≤ 14.0 MPa^1/2). This quantitative control of solvent-catalyst and solvent-polymer affinity parameters prevents catalyst aggregation while ensuring proper dispersion and film formation, thereby maintaining catalyst activity and achieving uniform film thickness simultaneously.

Inventive Principle:
Principle #35Parameter changes

2Stability of the object's composition

If catalyst dispersibility in ink is improved by adjusting solvent compatibility, then aggregation is prevented, but manufacturing complexity increases due to precise Hansen parameter control requirements

Engineering Contradiction:
Improvecatalyst dispersibilityVSAvoidmanufacturing process complexity
Core Design Contradiction:
Stability of the object's compositionVSDevice complexity

Solution Approach 1:

The patent establishes specific numerical ranges for Hansen solubility parameter distances (Ra1 and Ra2) that define the optimal affinity between solvent, catalyst, and organic polymer. By specifying these quantitative parameters, the patent provides clear manufacturing guidelines that ensure stable catalyst dispersibility without requiring complex empirical optimization, thus improving compositional stability while maintaining manageable manufacturing complexity.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration results in an electrode catalyst ink with excellent dispersibility, maintaining catalyst activity and reducing overvoltage in water electrolysis cells, thereby enhancing the efficiency and durability of the electrode catalyst.

Implementation Method 1

the Hansen solubility parameter distance Ra1 between the solvent and the catalyst is 15.0 MPa1⁄2 or more and less than 20.5 MPa1⁄2, and the Hansen solubility parameter distance Ra2 between the solvent and the organic polymer is 10.0 MPa1⁄2 or more and 14.0 MPa1⁄2 or less

Methodology Applied
Scientific EffectSolvation: Solvation

Data Source

PatentUS20230235467A1Electrode catalyst ink of water electrolysis cell, electrode catalyst, water electrolysis cell, and water electrolyzer
Publication Date: 2023.07.27 PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO LTD
  • US20230235467A1 patent drawing
  • US20230235467A1 patent drawing
  • US20230235467A1 patent drawing

AI summary

The electrode catalyst ink for a water electrolysis cell includes a catalyst including a layered double hydroxide, an organic polymer, and a solvent. The Hansen solubility parameter distance Ra1 between the solvent and the catalyst is 15.0 MPa½ or more and less than 20.5 MPa½. The Hansen solubility parameter distance Ra2 between the solvent and the organic polymer is 10.0 MPa½ or more and 14.0 MPa½ or less.