Electrode Slurry Drying with Zoned Induction Heating

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Solution Overview

Problem

The manufacturing of secondary battery electrodes faces challenges in achieving stable drying without defects, such as cracks and binder migration, which affect performance due to variations in drying temperature and solvent content, leading to issues with productivity and electrode quality.

Innovation Solution

A method and apparatus using induction heating in conjunction with hot air to dry the electrode slurry, with a drying apparatus featuring multiple zones and an induction heating unit positioned at a reference zone to ensure uniform and efficient drying, preventing defects and improving productivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional drying methods are used to dry the slurry, then the drying process can be completed, but cracks and binder migration occur resulting in electrode defects

Engineering Contradiction:
Improvedrying stabilityVSAvoidelectrode quality
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The drying process is divided into multiple zones (first drying zone, second drying zone, third drying zone) with progressively different temperature conditions. The induction heating unit is positioned specifically in the second drying zone to provide localized rapid heating, segmenting the thermal treatment to prevent uniform overheating that causes cracks and binder migration.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention changes the temperature parameter dynamically across different zones and time periods. The induction heating unit provides rapid temperature increase in the second drying zone when the slurry reaches a specific solids content range (60-80%), optimizing drying conditions at each stage to prevent defects while ensuring complete drying.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If high temperature drying is applied to improve drying efficiency, then productivity increases, but thermal wrinkles and cracks occur reducing electrode quality

Engineering Contradiction:
Improvedrying efficiencyVSAvoidelectrode surface quality
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

Different zones of the drying apparatus are assigned different temperature qualities: the first drying zone uses moderate heating, the second drying zone (where the induction heating unit is located) applies intense localized heating when needed, and the third drying zone provides gentle finishing. This local differentiation allows high productivity without widespread thermal damage.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The induction heating unit operates periodically or selectively based on the slurry's progression through the dryer and its solids content. Rather than continuous high-temperature heating, the system applies rapid induction heating at critical moments (when solids content reaches 60-80% in the second drying zone), achieving efficient drying without sustained thermal stress that causes wrinkles and cracks.

Inventive Principle:
Principle #19Periodic action

3Loss of time

If rapid drying is performed to increase productivity, then drying time is reduced, but binder migration occurs leading to lithium plating and increased resistance

Engineering Contradiction:
Improvedrying timeVSAvoidelectrode performance
Core Design Contradiction:
Loss of timeVSReliability

Solution Approach 1:

The first drying zone performs preliminary drying at moderate temperatures to remove excess solvent before the slurry enters the second drying zone. This preliminary action prepares the slurry for the subsequent rapid induction heating by reducing the total solvent load, enabling faster drying in the second zone without causing binder migration or lithium plating.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The drying process maintains continuous action through the three zones with the induction heating unit providing uninterrupted rapid heating in the second drying zone. This continuous controlled heating ensures complete solvent removal and proper binder setting without interruption, preventing the moisture-related defects that would occur with intermittent or insufficient drying while maintaining high productivity.

Inventive Principle:
Principle #20Continuity of useful action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables stable and efficient drying of the electrode, reducing defects and improving adhesion, thereby enhancing the quality and productivity of the electrode manufacturing process without thermal wrinkles or cracks.

Implementation Method 1

drying the slurry using induction heating of an induction heating unit

Methodology Applied
Scientific EffectInduction heating: Induction Heating

Implementation Method 2

when a degree of drying of the slurry reaches a reference value while the current collector passes through a drying apparatus

Methodology Applied
Scientific EffectEvaporation: Evaporation

Data Source

PatentUS20230282802A1Manufacturing method and drying apparatus of electrode
Publication Date: 2023.09.07 SK ON CO LTD
  • US20230282802A1 patent drawing
  • US20230282802A1 patent drawing
  • US20230282802A1 patent drawing

AI summary

According to embodiments of the present disclosure, a method of manufacturing an electrode includes applying slurry comprising an active material and a solvent on a current collector, and when a degree of drying of the slurry reaches a reference value while the current collector passes through a drying apparatus, drying the slurry using induction heating of an induction heating unit.