Wound Electrode Assembly Half-Coating for Deformation Control
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Solution Overview
Problem
Lithium secondary batteries are prone to structural collapse, oxidation of the electrolyte, and precipitation of lithium due to excessive reactions between the positive electrode active material and the electrolyte, which can lead to ignition or explosion.
Innovation Solution
The electrode assembly includes a first electrode plate with half-coating portions on both leading and trailing edges, and a second electrode plate with a cover tape on its leading edge, reducing the thickness of the positive electrode plate's leading edge and creating an unreacted region to prevent internal deformation.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Use of energy by moving object
If the positive electrode plate is fully coated with active material on both surfaces, then the energy density is improved, but the leading edge region becomes prone to internal deformation and structural collapse
Solution Approach 1:
The patent applies local quality by creating a half-coating portion on the leading edge of the positive electrode plate where active material is coated on only one surface instead of both surfaces. This localized modification prevents excessive reactions in the leading edge region while maintaining full coating in other regions to preserve energy density. The half-coating portion is specifically positioned at the leading edge where the negative electrode plate's active material begins, creating an unreacted region that prevents internal deformation.
2Quantity of substance
If the electrode assembly is wound tightly to increase energy density, then the space utilization is improved, but the leading edge region becomes susceptible to deformation and structural collapse
Solution Approach 1:
The patent applies beforehand cushioning by creating an unreacted region in the leading edge through the half-coating configuration. This unreacted region acts as a buffer zone that prevents excessive reactions during battery operation, thereby cushioning against internal deformation and structural collapse. The half-coating portion is positioned beforehand at the leading edge where deformation is most likely to occur during winding and operation.
3Quantity of substance
If the positive electrode plate thickness is increased to improve capacity, then the energy storage is improved, but the leading edge region becomes more prone to internal deformation
Solution Approach 1:
The patent applies local quality by modifying only the leading edge region of the positive electrode plate through half-coating, while maintaining the full thickness and coating in other regions. This allows the electrode plate to have sufficient overall capacity while creating a localized unreacted region at the leading edge that prevents internal deformation. The half-coating portion reduces the effective thickness and reactivity in the critical leading edge area without compromising the overall capacity of the electrode plate.
Data Source
AI summary
An electrode assembly and a secondary battery are provided. In an exemplary embodiment, an electrode assembly includes: a first electrode plate having a first electrode tab attached thereto; a second electrode plate having at least one second electrode tab attached thereto; and a separator between the first electrode plate and the second electrode plate, the electrode assembly wound in a state in which the first electrode plate, the separator, and the second electrode plate are stacked, and the first electrode plate includes coating portions formed by coating an active material on first and second surfaces thereof, and a half-coating portion formed by coating the active material on only one of the first and second surfaces at a region corresponding to a leading edge, on the basis of a winding direction, where an active material of the second electrode plate begins.


