Negative Electrode Hole Patterning for Fast-Charging Battery Safety
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Solution Overview
Problem
Secondary batteries suffer from poor fast-charging ability and safety performance due to uncontrollable hole formation in negative electrode film layers, leading to concentration polarization and potential safety risks from lithium dendrite formation.
Innovation Solution
A method involving a photosensitive adhesive is used to create a negative electrode plate with controlled recessed portions and holes, improving ion transport and absorption, which enhances the kinetic and safety performance by accurately adjusting the structural form and distribution of holes in the negative electrode film layer.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Reliability
If traditional negative electrode plate preparation methods are used, then the manufacturing process is simple, but the fast-charging ability and safety performance are poor
Solution Approach 1:
The patent applies preliminary action by pre-forming recessed portions in the negative electrode film layer before electrochemical processing. These recessed portions are created through a controlled process involving photosensitive adhesive coating, UV exposure, and development, which prepares the electrode structure in advance to facilitate subsequent ion transport and prevent dendrite formation during charging operations.
Solution Approach 2:
The patent utilizes porous material principles by creating a controlled porous structure within the negative electrode film layer through the recessed portions. This porous architecture increases the surface area and provides pathways for electrolyte penetration and ion transport, thereby improving fast-charging ability and safety performance without significantly complicating the overall manufacturing process.
2Productivity
If hole structure is added to improve ion transport, then fast-charging performance improves, but the manufacturing precision requirements increase
Solution Approach 1:
The patent employs an intermediary approach by using photosensitive adhesive as a temporary structuring agent. The photosensitive adhesive is coated on the negative electrode current collector, exposed to UV light through a mask to form recessed portions, and then removed after serving its purpose. This intermediary material enables precise hole structure formation without requiring direct precision manufacturing of the final electrode structure.
Solution Approach 2:
The patent replaces mechanical precision drilling or punching methods with a photochemical system. Instead of using mechanical tools to create holes with high precision, the patent uses UV light exposure through a mask to selectively cure photosensitive adhesive, which is then removed to form the desired hole structure. This substitution of mechanical processes with photochemical processes achieves higher precision with less complex manufacturing equipment.
3Speed
If photosensitive adhesive processing is used to control hole distribution, then ion transport rate improves, but the processing time increases
Solution Approach 1:
The patent applies parameter changes by optimizing the photosensitive adhesive formulation and UV exposure parameters to reduce processing time. By adjusting the sensitivity of the photosensitive adhesive to UV light and optimizing the exposure duration, the patent achieves rapid formation of recessed portions. Additionally, the use of conventional development solutions and controlled drying parameters minimizes the overall processing time while maintaining the quality of the hole structure for effective ion transport.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The method improves the fast-charging performance and safety of secondary batteries by enhancing ion transport and reducing the risk of concentration polarization and dendrite formation, thereby ensuring better kinetic and safety performance.
Implementation Method 1
coating at least one surface of the negative electrode current collector with a photosensitive adhesive and curing same to form a photosensitive layer; patterning light into a preset pattern, and allowing the incidence of the light from the surface of the photosensitive layer that is away from the negative electrode current collector to the photosensitive layer to expose the photosensitive layer
Implementation Method 2
the negative electrode film layer absorbs an electrolyte solution with the aid of the hole structure, which is beneficial to improving the transport rate of active ions in the liquid phase
Data Source
AI summary
The present application provides a negative electrode plate, a preparation method therefor, a secondary battery and a power consuming device. The method comprises: providing a negative electrode current collector; coating at least one surface of the negative electrode current collector with a photosensitive adhesive and curing same to form a photosensitive layer; patterning light into a preset pattern, and allowing the incidence of the light from the surface of the photosensitive layer that is away from the negative electrode current collector to the photosensitive layer to expose the photosensitive layer; developing the exposed photosensitive layer to obtain a photosensitive layer having a recessed portion; filling the recessed portion with a negative electrode slurry, and curing the negative electrode slurry to form a negative electrode film layer; and removing at least a part of the photosensitive layer to obtain the negative electrode plate.


