Storage Battery Electrode Slurry pH Control to Prevent Binder Gelation

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Solution Overview

Problem

Current methods for manufacturing storage battery electrodes face challenges in achieving high capacity, stability, and uniform thickness, while also simplifying the manufacturing process to facilitate mass production and ensuring high strength and preventing issues like binder gelation and active material aggregation.

Innovation Solution

A method involving the formation of a storage battery electrode through steps including mixing an active material with an oxidized derivative of a conductive additive, reducing the oxidized derivative, and combining it with a second conductive additive and binder, followed by coating a current collector, which helps in maintaining a uniform thickness and preventing strong basicity and gelation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If the proportion of binder to active material is increased to improve binding, then the electrical conductivity between active materials and current collector is improved, but the proportion of active material in the electrode is relatively decreased, resulting in lower discharge capacity

Engineering Contradiction:
Improvebinding strengthVSAvoiddischarge capacity
Core Design Contradiction:
StrengthVSQuantity of substance

Solution Approach 1:

The patent introduces a conductive additive as an intermediary substance between the binder and active material. This conductive additive serves dual functions: it maintains electrical conductivity pathways while enabling effective binding. The binder binds to the conductive additive rather than directly to active materials, allowing the conductive additive to form a conductive network that connects active materials to the current collector without requiring excessive binder content, thus preserving discharge capacity.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If a complex manufacturing process is used to achieve high capacity and stability, then the electrode performance is improved, but the manufacturing complexity increases, making mass production difficult

Engineering Contradiction:
Improveelectrode stabilityVSAvoidmanufacturing process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent merges multiple functions into a single integrated manufacturing process. The slurry preparation step simultaneously achieves uniform mixing of active material, conductive additive, and binder; the coating process deposits the electrode layer with controlled thickness; and the drying process removes solvent while maintaining the conductive network structure. This integrated approach eliminates the need for separate processing steps for each function, reducing manufacturing complexity while ensuring high capacity and stability through proper material distribution and conductive network formation.

Inventive Principle:
Principle #5Merging (Combining)

3Quantity of substance

If the thickness of the electrode is increased to improve capacity, then the discharge capacity is improved, but the uniformity of thickness becomes difficult to maintain, affecting performance consistency

Engineering Contradiction:
Improvedischarge capacityVSAvoidthickness uniformity
Core Design Contradiction:
Quantity of substanceVSManufacturing precision

Solution Approach 1:

The patent controls electrode thickness and uniformity by adjusting slurry parameters such as viscosity, solids content, and composition ratios before coating. By optimizing the slurry formulation and coating conditions, the process achieves uniform thickness deposition even at higher thickness levels required for high capacity. The conductive additive network formation is also controlled through parameter optimization, ensuring consistent electrical properties throughout the electrode thickness.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method results in a storage battery electrode with high capacity and stability, improved electrical conductivity, and enhanced mechanical strength, while simplifying the manufacturing process and preventing issues like binder gelation and active material aggregation.

Implementation Method 1

the second step includes a step of forming a first mixture by reducing the oxidized derivative of the first conductive additive by drying the first aqueous solution

Methodology Applied
Scientific EffectReduction: Reduction

Data Source

PatentUS11881578B2Storage battery electrode, manufacturing method thereof, storage battery, and electronic device
Publication Date: 2024.01.23 SEMICON ENERGY LAB CO LTD
  • US11881578B2 patent drawing
  • US11881578B2 patent drawing
  • US11881578B2 patent drawing

AI summary

In manufacturing a storage battery electrode, a method for manufacturing a storage battery electrode with high capacity and stability is provided. As a method for preventing a mixture for forming an active material layer from becoming strongly basic, a first aqueous solution is formed by mixing an active material exhibiting basicity with an aqueous solution exhibiting acidity and including an oxidized derivative of a first conductive additive; a first mixture is formed by reducing the oxidized derivative of the first conductive additive by drying the first aqueous solution; a second mixture is formed by mixing a second conductive additive and a binder; a third mixture is formed by mixing the first mixture and the second mixture; and a current collector is coated with the third mixture. The strong basicity of the mixture for forming an active material layer is lowered; thus, the binder can be prevented from becoming gelled.