Positive Electrode Primer Layer for High-Density Battery Sheets
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Solution Overview
Problem
Increasing the compacted density of positive electrode sheets in secondary batteries to enhance energy density often leads to the destruction of the oxide film on aluminum foils, causing safety issues due to electrolyte corrosion.
Innovation Solution
A positive electrode sheet design that includes a primer layer with a specific thickness, which protects the oxide film on the aluminum foil from being crushed by the positive electrode active material, thereby enhancing safety and maintaining energy density.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Quantity of substance
If the compacted density of the positive electrode sheet is increased to improve energy density, then the energy density is improved, but the oxide film on the aluminum foil surface is destroyed, causing safety problems
Solution Approach 1:
The patent introduces a primer layer as an intermediary between the positive electrode active material and the aluminum foil current collector. This primer layer acts as a protective mediator that prevents direct contact and mechanical crushing of the oxide film by the active material particles, thereby resolving the contradiction between achieving high compacted density for energy density and maintaining oxide film integrity for battery safety.
2Quantity of substance
If the compacted density of the positive electrode sheet is increased, then the energy density is improved, but the oxide film protection is compromised, leading to electrolyte corrosion
Solution Approach 1:
The patent applies preliminary action by forming the primer layer on the aluminum foil surface before applying the positive electrode active material. This preliminary protective layer is prepared in advance to prevent the harmful effect of oxide film destruction that would occur during subsequent high-density compaction, thereby allowing energy density improvement without compromising oxide film protection.
3Reliability
If a primer layer is added to protect the oxide film, then the safety is improved, but the device complexity increases
Solution Approach 1:
The patent controls the thickness of the primer layer within a specific range (1-10 μm) to optimize the balance between safety improvement and structure simplicity. By precisely controlling this parameter, the primer layer provides adequate protection without excessive thickness that would increase device complexity or reduce energy density, thus resolving the contradiction between safety enhancement and structural simplicity.
Data Source
AI summary
Provided are a positive electrode sheet, a secondary battery, and an electrical device. The positive electrode sheet includes: a positive electrode current collector; a primer layer, located on at least one side of the positive electrode current collector, including a conductive agent and a binder; a positive electrode active substance layer, located on one side of the primer layer far away from the positive electrode current collector, including a positive electrode active material; wherein a thickness of the primer layer is denoted as L, and the thickness of the primer layer satisfies: 0.1≤L/(Dv50−5)*(PD/3.5)≤0.5; wherein Dv50 represents a corresponding particle size when a cumulative particle size distribution number of particles in a volume distribution of the positive electrode active material reaches 50%, and a unit of Dv50 is μm; PD represents a compacted density of the positive electrode sheet, and a unit of PD is g/cm3.

