Electroless Deposition Oxygen Saturation for Small Feature Plating

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Solution Overview

Problem

Current electroless deposition systems face challenges in providing stability and effectively plating on small isolated features, especially under agitated conditions, due to the limitations of existing stabilizers which either fail to maintain bath stability or allow plating on such features.

Innovation Solution

The system saturates the electroless deposition solution with an oxygen concentration ranging from about two thousand to twenty thousand parts per million, maintaining stability and enabling plating on outlier features by bubbling oxygen through the solution, which is then used in a controlled environment for surface treatment and deposition.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional stabilizers are used in electroless deposition solution, then bath stability is maintained, but plating on small isolated features is prevented

Engineering Contradiction:
Improvebath stabilityVSAvoidsmall isolated feature plating
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent changes the chemical parameters of the electroless deposition solution by incorporating specific stabilizers (such as iodide ions, thiocyanate ions, or their combinations) at controlled concentrations. This allows the solution to simultaneously maintain bath stability and enable plating on small isolated features, resolving the contradiction between reliability and manufacturing precision.

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If agitation is applied during plating to improve uniformity, then deposition uniformity is enhanced, but small isolated feature plating is inhibited by stabilizers

Engineering Contradiction:
Improvedeposition uniformityVSAvoidsmall isolated feature plating
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent modifies the chemical composition parameters of the plating solution to include specific stabilizers that are effective even under agitated conditions. These stabilizers (iodide, thiocyanate, or combinations) allow the solution to maintain both deposition uniformity during agitation and the ability to plate on small isolated features, thus resolving the contradiction between manufacturing precision and reliability.

Inventive Principle:
Principle #35Parameter changes

3Productivity

If feature size is reduced to increase circuit density, then product functionality is enhanced, but plating reliability on small features deteriorates

Engineering Contradiction:
Improvecircuit densityVSAvoidplating on small features
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent changes the chemical parameters of the electroless deposition solution by introducing specific stabilizers (iodide ions, thiocyanate ions, or their combinations) that enable reliable plating on progressively smaller features. This allows manufacturers to reduce feature size and increase circuit density while maintaining plating reliability, thus resolving the contradiction between productivity and reliability.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach achieves stable plating on small isolated features with a consistent deposition layer thickness, enhancing the performance and efficiency of the electroless deposition process while maintaining solution stability across a wide oxygen concentration range.

Implementation Method 1

saturating the deposition solution with an oxygen concentration in a range from about two thousand parts per million to about twenty thousand parts per million

Methodology Applied
Scientific EffectGas absorption/dissolution: Absorption (physical)

Data Source

PatentUS7913644B2Electroless deposition system
Publication Date: 2011.03.29 LAM RES CORP
  • US7913644B2 patent drawing
  • US7913644B2 patent drawing
  • US7913644B2 patent drawing

AI summary

An electroless deposition system includes a deposition solution, and saturating the deposition solution with an oxygen concentration in a range from about two thousand parts per million to about twenty thousand parts per million.