In Situ Electrolysis Alkalinity Boost for Ash-Based Detergents

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Solution Overview

Problem

Ash-based detergents lack sufficient alkalinity for effective cleaning, posing risks to workers handling concentrated forms and requiring additional chemical additives to match the performance of caustic detergents.

Innovation Solution

Electrolysis is used to enhance the alkalinity of ash-based detergents by converting sodium carbonate into hydroxide alkalinity in situ, without adding chemicals, thereby increasing the hydroxide to carbonate alkalinity ratio, thereby improving cleaning efficacy.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If ash-based detergents are used to provide nonhazardous and consumer-friendly properties, then safety and environmental benefits are improved, but alkalinity and cleaning performance are insufficient

Engineering Contradiction:
ImprovesafetyVSAvoidcleaning performance
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent applies parameter changes by converting the chemical composition of the detergent through electrolysis. Sodium carbonate (ash) is electrochemically converted to sodium hydroxide (caustic), fundamentally changing the alkalinity parameter from carbonate-based to hydroxide-based, thereby achieving both safety and high cleaning performance

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces chemical addition (adding caustic chemicals) with an electrochemical process (electrolysis). Instead of mechanically mixing in hazardous chemicals to boost alkalinity, an electrical field is used to generate hydroxide ions in situ, eliminating the need for additional chemical inputs

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Reliability

If caustic detergents are used to provide sufficient alkalinity and cleaning performance, then cleaning efficacy is improved, but safety risks and handling hazards increase

Engineering Contradiction:
Improvecleaning performanceVSAvoidsafety
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The system performs self-service by generating its own caustic agent through electrolysis. The ash-based detergent solution is passed through an electrolytic cell where electrical energy converts carbonate to hydroxide, allowing the system to self-regenerate the active cleaning ingredient without external chemical additions

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The electrolytic cell acts as an intermediary device between the safe ash-based detergent and the effective caustic detergent. This intermediate device transforms the harmless carbonate solution into a potent hydroxide solution, bridging the gap between safety and performance

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If chemical additives are added to ash-based detergents to boost alkalinity, then cleaning performance is improved, but additional waste streams and chemical hazards are created

Engineering Contradiction:
Improvecleaning performanceVSAvoidwaste
Core Design Contradiction:
ReliabilityVSLoss of substance

Solution Approach 1:

The patent substitutes chemical addition with electrochemical transformation. Instead of adding more chemicals to the system, electrical energy is used to transform existing carbonate ions into hydroxide ions, eliminating waste generation and chemical hazards while achieving the desired alkalinity boost

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method provides a sustainable and nonhazardous detergent with enhanced alkalinity, matching the performance of caustic detergents while maintaining safety and environmental benefits, without generating additional waste streams.

Implementation Method 1

Electrolysis is used to enhance the alkalinity of ash-based detergents by converting sodium carbonate into hydroxide alkalinity in situ

Methodology Applied
Scientific EffectElectrolysis: Electrolysis

Implementation Method 2

The reaction of water in an electrolytic cell is a redox process, as an oxidation reaction occurs at the anode while a reduction reaction occurs at the cathode

Methodology Applied
Scientific EffectRedox reactions: Redox Reactions

Data Source

PatentUS9045835B2On site generation of alkalinity boost for ware washing applications
Publication Date: 2015.06.02 ECOLAB USA INC
  • US9045835B2 patent drawing
  • US9045835B2 patent drawing
  • US9045835B2 patent drawing

AI summary

Methods for enhancing alkalinity and performance of ash-based detergents are disclosed. Nonhazardous ash-based detergent alkalinity is enhanced through increasing the ratio of sodium hydroxide to ash-based alkalinity. Methods according to the invention do not require the addition of chemical ingredients, do not generate additional waste streams and use the entirety of the ash-based detergent. The methods according to the invention provide alkalinity-enhanced detergent use solutions that are sufficiently concentrated for adequate cleaning capability while only requiring minimal amounts of the use solution to be dispensed for an in situ cleaning process.