Water Electrolysis Electrode Structure for Uniform Membrane Pressure

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Solution Overview

Problem

The electrolyte membrane in existing electrode structures for water electrolysis is prone to deterioration due to locally applied high pressure from reticular metal components, leading to reduced durability and hydrogen generation efficiency.

Innovation Solution

Incorporating a porous component and a reticular component in the electrode structure with a standard deviation of pressure distribution at the surface contact between the anode and cathode electrodes of 2.7 MPa or less, ensuring uniform pressure distribution and preventing high pressure from being locally applied to the electrolyte membrane.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If reticular metal components are used as flow path forming components in the electrode structure, then water and gas circulation is enabled, but the electrolyte membrane is prone to deterioration due to locally applied high pressure

Engineering Contradiction:
Improvewater and gas circulationVSAvoidelectrolyte membrane durability
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

A porous component is introduced as an intermediary layer between the reticular metal component and the electrolyte membrane. This porous component acts as a mediator that distributes the pressure from the reticular component uniformly across the electrolyte membrane surface, preventing local high pressure concentration while maintaining the flow path formation function. The porous component's uniform pressure distribution capability resolves the contradiction by protecting the membrane from deterioration caused by direct contact with the reticular component's uneven surface.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The porous component with its porous structure is specifically designed to distribute pressure uniformly. The porous structure allows fluid passage while providing a large surface area contact with the electrolyte membrane, thereby distributing the mechanical load. This application of porous materials directly addresses the pressure distribution issue and prevents membrane deterioration while maintaining operational functionality.

Inventive Principle:
Principle #31Porous materials

2Ease of operation

If reticular components with surface uneven shape are used, then flow paths are formed, but high pressure is locally applied to the electrolyte membrane causing deterioration

Engineering Contradiction:
Improveflow path formationVSAvoidlocal high pressure on electrolyte membrane
Core Design Contradiction:
Ease of operationVSObject-affected harmful factors

Solution Approach 1:

The porous component serves as an intermediary that decouples the flow path formation function from the pressure application to the electrolyte membrane. The reticular component maintains its flow path formation capability with its uneven surface structure, while the porous component in between absorbs and redistributes the mechanical stress, preventing the transmission of localized high pressure to the membrane.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The porous component's porous structure enables it to function as a pressure-distributing interface. The pores and voids in the porous material allow it to conform to the uneven reticular component surface while providing uniform contact pressure distribution to the electrolyte membrane, thereby eliminating the harmful localized high pressure effect.

Inventive Principle:
Principle #31Porous materials

3Reliability

If uniform pressure distribution is achieved, then electrolyte membrane durability is improved, but electrode structure complexity increases due to additional porous component

Engineering Contradiction:
Improveelectrolyte membrane durabilityVSAvoidelectrode structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The porous component is integrated with the electrode structure as a unified assembly, merging the pressure distribution function with the existing electrode components. This integration approach minimizes the increase in overall structural complexity while achieving the desired uniform pressure distribution effect. The porous component becomes an inherent part of the electrode assembly rather than a separate add-on system.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The porous component performs multiple functions simultaneously: it distributes pressure uniformly to protect the electrolyte membrane, maintains flow paths for water and gas circulation, and provides structural support. This multi-functionality reduces the need for additional specialized components, thereby limiting the increase in device complexity while achieving improved membrane durability.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Data Source

PatentUS20240417861A1Electrode structure for water electrolysis, membrane electrode assembly for water electrolysis, and water electrolyzer
Publication Date: 2024.12.19 TORAY INDUSTRIES INC
  • US20240417861A1 patent drawing
  • US20240417861A1 patent drawing
  • US20240417861A1 patent drawing

AI summary

An object of the present invention is to provide an electrode assembly for water electrolysis, in which an electrolyte membrane is kept from being deteriorated. The present invention provides an electrode structure for water electrolysis, including an anode electrode and a cathode electrode disposed to face each other, characterized in that at least one of the anode electrode and the cathode electrode includes a porous component and a reticular component in order from the facing surface side, and the standard deviation of a pressure distribution at the surface of contact between the anode electrode and the cathode electrode, determined by the following measurement method, is 2.7 MPa or less.<Measurement Method>After a test piece that has a pressure measurement film sandwiched between the anode electrode and the cathode electrode is pressurized at 4 MPa for 2 minutes, the pressure distribution obtained by a pressure analysis from a color image of the pressure measurement film, obtained from a pressure image analysis system, is defined as a pressure distribution at the surface of contact between the anode electrode and the cathode electrode, and the standard deviation of the pressure distribution is determined.