Gas-Liquid Separator for Water Electrolysis with Ultrasonic Defoaming

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Solution Overview

Problem

Current gas-liquid separation methods in alkaline water electrolysis systems are inefficient in handling high concentration electrolytes, leading to poor separation of micro-bubbles and high operating costs, as they rely on shear force flow fields which are inadequate for the micro-bubble systems produced in water electrolysis.

Innovation Solution

A gas-liquid separator that uses a combination of physical methods including spraying, ultrasonic defoaming, and size screening, with a spiral flowing path and a filter mechanism to enhance gas-liquid separation efficiency, utilizing an atomizer to convert the gas-liquid mixture into mist droplets, and ultrasonic oscillation to facilitate bubble separation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If high concentration alkaline electrolyte is used to improve electrolytic efficiency, then conductivity increases, but gas-liquid separation effect deteriorates due to poor bubble separation

Engineering Contradiction:
Improveelectrolytic efficiencyVSAvoidgas-liquid separation effect
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The gas-liquid separator divides the separation process into multiple stages: a first gas-liquid separation chamber for initial separation and a second gas-liquid separation chamber for final separation. This multi-stage segmentation allows efficient handling of high concentration electrolyte by progressively separating gas bubbles from the liquid phase, addressing the poor separation effect caused by high conductivity electrolytes.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent introduces a vertical dimension to the separation process by stacking separation chambers at different heights and using a liquid level control mechanism. The electrolyte flows from the first chamber to the second chamber through controlled liquid level differences, adding a vertical flow dimension that enhances separation efficiency for high concentration electrolytes.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

2Productivity

If shear force flow field is used for gas-liquid separation, then separation is achieved for pure water and air, but separation efficiency deteriorates for micro-bubbles in high concentration electrolyte

Engineering Contradiction:
Improveseparation capabilityVSAvoidseparation efficiency
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent employs an ultrasonic vibration device that generates high-frequency mechanical vibrations in the electrolyte. This mechanical vibration disrupts the stability of micro-bubbles in high concentration electrolyte, enhancing their coalescence and separation from the liquid phase, thereby significantly improving separation efficiency where shear force alone is insufficient.

Inventive Principle:
Principle #18Mechanical vibration

Solution Approach 2:

The patent introduces a hydrophobic material as an intermediary substance to facilitate gas-liquid separation. This hydrophobic material preferentially interacts with gas bubbles, promoting their aggregation and separation from the electrolyte phase, thereby improving the separation of micro-bubbles that cannot be effectively separated by shear force alone.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Device complexity

If conventional gas-liquid separation methods are used, then simple design is achieved, but separation efficiency for water electrolysis micro-bubbles deteriorates

Engineering Contradiction:
Improvedesign simplicityVSAvoidseparation efficiency
Core Design Contradiction:
Device complexityVSProductivity

Solution Approach 1:

The gas-liquid separator is segmented into multiple functional modules: pressurization device, first separation chamber, second separation chamber, ultrasonic vibration device, and liquid level control mechanism. This modular segmentation maintains design simplicity through standardized components while achieving high separation efficiency for water electrolysis micro-bubbles through coordinated operation of each module.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent designs a multi-functional gas-liquid separation system that combines pressurization, gravity-based separation, ultrasonic vibration, and hydrophobic material assistance into a single integrated device. This universal design handles various electrolyte concentrations and bubble sizes, maintaining simplicity while achieving high separation efficiency across different operating conditions.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution achieves a significant increase in gas-liquid separation efficiency, with a 48% improvement in gas separation effects through stirring, 48% through filtration, and 58% through ultrasonic oscillation, resulting in high purity gas and liquid discharge.

Implementation Method 1

a liquid feeding pressurized tube for receiving and pressurizing a gas-liquid mixed liquor

Methodology Applied
Scientific EffectPressurization: Pressurisation

Implementation Method 2

an atomizing spray head, which is connected to the liquid feeding pressurized tube, in which the atomizing spray head converts the gas-liquid mixed liquor after pressurized by the liquid feeding pressurized tube into a mist droplet gas-liquid mixture

Methodology Applied
Scientific EffectAtomization: Aerosol

Implementation Method 3

an ultrasonic oscillation mechanism, set on an outer wall of the gas-liquid separation chamber, which is used for oscillating the mist droplet gas-liquid mixture in the gas-liquid separation chamber

Methodology Applied
Scientific EffectUltrasonic oscillation: Ultrasonic Vibration

Implementation Method 4

a filter mechanism, located at the top of the internal reservoir, which performs the gas-liquid separation for unbroken bubbles in the mist droplet gas-liquid mixture through the pore difference

Methodology Applied
Scientific EffectFiltration: Filter (physical)

Data Source

PatentUS11926909B2Gas-liquid separator of water electrolysis system
Publication Date: 2024.03.12 NAT CHUNG SHAN INST SCI & TECH
  • US11926909B2 patent drawing
  • US11926909B2 patent drawing
  • US11926909B2 patent drawing

AI summary

To provide a gas-liquid separator of a water electrolysis system, comprising: a liquid feeding atomizer and a gas-liquid separation chamber, wherein the liquid feeding atomizer includes a liquid feeding pressurized tube; and an atomizing spray head, in which the atomizing spray head converts a gas-liquid mixed liquor after pressurized by the liquid feeding pressurized tube into a mist droplet gas-liquid mixture. The gas-liquid separation chamber comprises a spiral flowing way, and the spiral flowing way extends the time that the mist droplet gas-liquid mixture spraying into the gas-liquid separation chamber flows downwards to the bottom of the gas-liquid separation chamber; an ultrasonic oscillation mechanism; a stirrer; an internal reservoir; and a filter mechanism, which performs the gas-liquid separation for unbroken bubbles in the mist droplet gas-liquid mixture through the pore difference.