Electrolysis Stack Flow Monitoring for Membrane Thinning Detection

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Solution Overview

Problem

Membranes in electrolysis cells degrade over time, particularly through thinning, which cannot be reliably detected by voltage measurements, leading to contamination of the electrolysis medium and products.

Innovation Solution

A method for monitoring membrane degradation in electrolysis cells by determining the flow rate of the electrolysis medium, where enhanced recombination of electrolysis products by a catalyst reduces the medium demand, indicating membrane thinning and overall degradation, allowing for timely maintenance and safety measures.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If voltage measurement is used to monitor membrane degradation, then the monitoring method is simple, but it cannot reliably detect membrane thinning

Engineering Contradiction:
Improvemonitoring method simplicityVSAvoidmembrane thinning detection accuracy
Core Design Contradiction:
Ease of operationVSMeasurement precision

Solution Approach 1:

The patent replaces the electrical measurement method (voltage measurement) with a chemical measurement method (monitoring electrolysis medium consumption). Instead of measuring electrical parameters to infer membrane state, the invention directly measures the chemical consumption of electrolysis medium, which provides reliable detection of membrane thinning while maintaining operational simplicity through flow rate monitoring.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Ease of operation

If membrane degradation is not monitored, then the system operation is simple, but contamination of electrolysis medium and products occurs

Engineering Contradiction:
Improvesystem operation simplicityVSAvoidcontamination of electrolysis medium and products
Core Design Contradiction:
Ease of operationVSObject-affected harmful factors

Solution Approach 1:

The patent implements a feedback mechanism where the consumption of electrolysis medium is continuously monitored and used to detect membrane degradation. When membrane thinning is detected through increased electrolysis medium consumption, the system can trigger alerts or automatic shutdowns to prevent contamination of the electrolysis medium and products, thus maintaining operational simplicity while preventing harmful effects.

Inventive Principle:
Principle #23Feedback

3Measurement precision

If flow rate measurement is implemented to monitor membrane degradation, then detection accuracy improves, but device complexity increases

Engineering Contradiction:
Improvemembrane thinning detection accuracyVSAvoidmonitoring system complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent utilizes the existing electrolysis medium feed system and its flow rate measurement capabilities to monitor membrane degradation. The system serves itself by using the same infrastructure already in place for electrolysis medium delivery, eliminating the need for separate complex monitoring equipment. The flow rate data from the feed system directly provides membrane health information.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Effectively monitors membrane degradation, particularly thinning, enabling proactive maintenance and safety interventions, thereby preventing contamination and ensuring safe operation of industrial-scale electrolysis processes.

Implementation Method 1

a membrane that separates the anode space and the cathode space from each other

Methodology Applied
Scientific EffectIon transport through membrane: Semipermeable Membrane

Implementation Method 2

a recombination catalyst

Methodology Applied
Scientific EffectCatalysis: Catalysis

Data Source

PatentEP4249638A1Performing an electrolysis
Publication Date: 2023.09.27 LAIR LIQUIDE SA POUR LETUDE & LEXPLOITATION DES PROCEDES GEORGES CLAUDE
  • EP4249638A1 patent drawingFigure 1~2
  • EP4249638A1 patent drawingFigure 3
  • EP4249638A1 patent drawing

AI summary

Method for performing an electrolysis using an electrolysis stack (2) having multiple electrolysis cells (3), wherein each of the electrolysis cells (3) has: - an anode space (4) with an anode (6), - a cathode space (5) with a cathode (7), - a membrane (8) that separates the anode space (4) and the cathode space (5) from each other, - a recombination catalyst (9), wherein the method comprises: - feeding an electrolysis medium to the electrolysis stack (2) and determining a flow rate at which the electrolysis medium is fed to the electrolysis stack (2), - providing electrical energy to the electrolysis stack (2) for performing the electrolysis with the electrolysis medium fed to the electrolysis stack (2), - determining a degree of degradation of the membranes (8) based on the determined flow rate of the electrolysis medium.