Electron Beam Heating Sapphire Substrates

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Solution Overview

Problem

Current thermal loading methods in epitaxy processes, such as electrical heating, are ineffective for optically thin and transparent sapphire substrates due to poor absorption and uneven heating, requiring high operational temperatures and long processing times, which hinder the growth of high-quality single crystalline layers like SiGe on sapphire substrates.

Innovation Solution

The use of a flood electron beam to heat and restructure sapphire substrates at a lower temperature, energizing atoms in flux to deform the cubic crystalline structure into a rhombohedral form, allowing for efficient and uniform heating and morphological alignment, reducing the substrate temperature and processing time.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If electrical heating elements are used for thermal loading in epitaxy processes, then heating can be provided to the sapphire substrate, but the heating is ineffective due to poor absorption by the optically thin and transparent sapphire substrates and uneven contact causing uneven heating

Engineering Contradiction:
Improvesubstrate temperatureVSAvoidheating effectiveness
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

The patent replaces electrical heating elements (mechanical/thermal system) with an electron beam system that uses electromagnetic energy to directly heat the sapphire substrate. The electron beam penetrates and deposits energy within the substrate volume, bypassing the absorption limitations of transparent materials and eliminating contact-related uneven heating.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the heating mechanism from conventional thermal conduction/radiation to electron beam irradiation, fundamentally altering the energy delivery parameters. This enables effective heating of optically thin and transparent sapphire substrates by using a different physical interaction mechanism that does not rely on optical absorption.

Inventive Principle:
Principle #35Parameter changes

2Temperature

If high operational temperature is used to energize the cubic structure for rhombohedral epitaxy, then the crystal structure can be rotated and deformed, but the processing time increases and quality of epitaxial layers decreases

Engineering Contradiction:
Improveoperational temperatureVSAvoidepitaxy processing efficiency
Core Design Contradiction:
TemperatureVSProductivity

Solution Approach 1:

The patent employs periodic or controlled electron beam irradiation to progressively energize atoms in flux, enabling the cubic structure to rotate and deform into a rhombohedron at lower temperatures. This controlled, time-dependent energy delivery achieves the desired crystal transformation without requiring sustained high-temperature processing.

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

The patent changes the temperature parameter from high operational temperature to lower substrate temperature by introducing electron beam energy as an alternative heating mechanism. This parameter change enables rhombohedral epitaxy to proceed at moderate temperatures, significantly improving processing efficiency and epitaxial layer quality.

Inventive Principle:
Principle #35Parameter changes

3Temperature

If conventional radiative or conductive heat transfer is used, then heating can be provided to the sapphire substrate, but poor absorption by the optically thin and transparent sapphire substrates results in ineffective heating

Engineering Contradiction:
Improvesubstrate temperatureVSAvoidenergy absorption
Core Design Contradiction:
TemperatureVSUse of energy by moving object

Solution Approach 1:

The patent replaces radiative or conductive heat transfer (thermal energy transfer mechanisms) with electron beam irradiation (electromagnetic energy transfer). This substitution enables effective energy delivery to optically thin and transparent sapphire substrates by using a different energy transfer mechanism that does not depend on optical absorption properties.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the energy transfer parameter from thermal radiation or conduction to electron beam energy deposition. This fundamental parameter change allows the sapphire substrate to effectively absorb energy through electron interaction rather than optical absorption, solving the poor absorption problem of transparent materials.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables rapid and effective heating of sapphire substrates, reducing the need for high-temperature thermal soaking, enhancing the yield and quality of epitaxial layers by providing stable and uniform thermal control, and facilitating quick and high-quality epitaxy processing.

Implementation Method 1

The use of a flood electron beam to heat and restructure sapphire substrates at a lower temperature

Methodology Applied
Scientific EffectElectron beam heating: Electron Beam

Implementation Method 2

energizing the atoms in flux

Methodology Applied
Scientific EffectKinetic energy transfer:

Implementation Method 3

energizing the atoms in flux, thereby reducing the substrate temperature to a moderate level

Methodology Applied
Scientific EffectAtomic flux:

Implementation Method 4

sufficiently energized atoms provide the essential energy needed for the rhombohedral epitaxy process which deforms the original cubic crystalline structure approximately into a rhombohedron

Methodology Applied
Scientific EffectCrystalline structure deformation: Deformation

Implementation Method 5

The use of a flood electron beam to heat and restructure sapphire substrates

Methodology Applied
Scientific EffectSurface restructuring:

Implementation Method 6

allowing for efficient and uniform heating and morphological alignment

Methodology Applied
Scientific EffectMorphological alignment:

Data Source

PatentUS11299820B2Electron beam heating and atomic surface restructuring of sapphire surface
Publication Date: 2022.04.12 UNITED STATES OF AMERICA AS REPRESENTED BY THE ADMINISTRATOR NAT AERONAUTICS & SPACE ADMINISTRATION
  • US11299820B2 patent drawing
  • US11299820B2 patent drawing
  • US11299820B2 patent drawing

AI summary

Systems, methods, and devices of the various embodiments may provide a mechanism to enable the growth of a rhombohedral epitaxy at a lower substrate temperature by energizing the atoms in flux, thereby reducing the substrate temperature to a moderate level. In various embodiments, sufficiently energized atoms provide the essential energy needed for the rhombohedral epitaxy process which deforms the original cubic crystalline structure approximately into a rhombohedron by physically aligning the crystal structure of both materials at a lower substrate temperature.