Electrodeless Electron Mobility Measurement in Nano Materials

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Solution Overview

Problem

Conventional methods for analyzing vertical movement characteristics of charges in nano-electronic materials often damage the samples due to electrode interaction, and existing technologies struggle to measure these characteristics effectively without distorting physical properties, especially in thin-film structures and 3D integration scenarios.

Innovation Solution

A method that eliminates the need for electrodes by using an electron gun or photon supply unit to irradiate the sample, measuring sample current, calculating secondary electron current, and defining an effective incident current to determine electron or hole mobility through equations like JEP(μ)=−1/(1−δEP)×μKBT∇q/e, allowing for electrodeless analysis of vertical movement characteristics.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If conventional electrode patterning method is used to measure vertical movement characteristics of charges, then measurement capability is achieved, but physical properties of the sample are damaged due to electrode interaction

Engineering Contradiction:
Improvevertical movement characteristics measurementVSAvoidsample damage from electrode interaction
Core Design Contradiction:
Measurement precisionVSObject-affected harmful factors

Solution Approach 1:

The invention extracts and removes the metal electrode component from the measurement system. Instead of using conventional electrode patterning methods that require metal electrodes to be deposited on the sample surface, the patent employs a scanning electron microscope with a floating gate structure that eliminates direct electrode-sample contact. This extraction of the harmful electrode element resolves the contradiction by enabling measurement without the damaging interaction.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention introduces a floating gate structure as an intermediary between the measurement system and the sample. The floating gate, which is not directly connected to external electrodes, serves as a mediator that allows charge measurement through capacitive coupling without physical contact. This intermediary structure enables the measurement of vertical charge movement while preventing the sample damage that would result from direct electrode interaction.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If metal electrodes are used for charge measurement in nanometer-thick films, then electrical contact is established, but physical properties are distorted due to electrode formation

Engineering Contradiction:
Improveelectrical contact reliabilityVSAvoidphysical properties stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The invention removes metal electrodes from the measurement configuration. By eliminating the electrode formation process entirely, the method avoids distorting the physical properties of nanometer-thick films while still achieving reliable electrical contact through the floating gate's capacitive coupling mechanism. This extraction resolves the contradiction by decoupling electrical measurement capability from the harmful electrode formation process.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention replaces the mechanical/electrical contact system (metal electrodes physically touching the sample) with a field-based measurement system. The floating gate structure utilizes electric field coupling and capacitive effects to establish electrical contact without physical contact. This substitution maintains measurement reliability while preserving the stability of the sample's physical properties by eliminating the mechanical intrusion of electrode formation.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Object-affected harmful factors

If electrodeless measurement method is used to avoid sample damage, then sample integrity is preserved, but measurement capability must be developed without conventional electrodes

Engineering Contradiction:
Improvesample damage eliminationVSAvoidmeasurement apparatus complexity
Core Design Contradiction:
Object-affected harmful factorsVSDevice complexity

Solution Approach 1:

The invention makes the scanning electron microscope perform multiple functions by utilizing its existing electron beam generation capability for both imaging and charge measurement. The floating gate structure, integrated into the SEM, serves dual purposes: it maintains the electron beam path for imaging while simultaneously enabling electrodeless charge measurement through capacitive coupling. This multi-functionality reduces device complexity by leveraging existing SEM capabilities rather than requiring a completely new measurement apparatus.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The floating gate structure serves itself by utilizing the electron beam from the SEM to generate the measurement signal. The same electron beam that would normally be used for imaging also charges the floating gate, creating the signal needed for measurement. This self-service approach eliminates the need for separate electrode structures or additional measurement devices, thereby reducing overall system complexity while maintaining sample integrity.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach reduces material development costs and time, enables real-time measurement of material properties, and provides accurate information on charge movement mechanics without physical damage, facilitating the design and development of customized electronic structures.

Implementation Method 1

an electron irradiation step of irradiating the metal sample with electrons using the electron gun

Methodology Applied
Scientific EffectElectron beam irradiation: Electron Beam

Implementation Method 2

a secondary electron current calculation step of calculating a secondary electron current through the measured sample current

Methodology Applied
Scientific EffectSecondary electron emission: Electron Impact Desorption

Implementation Method 3

a sample current measurement step of applying a voltage to the metal sample to measure a sample current according to the applied voltage on the metal sample

Methodology Applied
Scientific EffectElectric field application: Electric Field

Implementation Method 4

measuring electron mobility in the metal sample using a value of the defined effective incident current

Methodology Applied
Scientific EffectCharge carrier drift: Electrophoresis

Implementation Method 5

photon supply unit provided in the chamber, and a metal sample provided in the sealed space to face the photon supply unit, the method including an electron irradiation step of irradiating the metal sample with photons through the photon supply unit

Methodology Applied
Scientific EffectPhotoelectric effect: Photoelectric Effect

Data Source

PatentUS11243178B2Apparatus for electrodeless measurement of electron mobility in nano material, apparatus for electrodeless measurement of hole mobility in nano material, method for electrodeless measurement of electron mobility in nano material, and method for electrodeless measurement of hole mobility in nano material
Publication Date: 2022.02.08 POSTECH ACADEMY INDUSTRY FOUNDATION
  • US11243178B2 patent drawing
  • US11243178B2 patent drawing
  • US11243178B2 patent drawing

AI summary

A method for measuring electron mobility according to the present invention, which is performed by an apparatus comprising a chamber forming a sealed space, an electron gun provided in the chamber, and a metal sample disposed opposite to the electron gun in the sealed space, comprises: an electron irradiation step of irradiating the metal sample with electrons by the electron gun; a sample current measurement step of applying a voltage to the metal sample to measure a sample current obtained in the metal sample according to the applied voltage; a secondary electron current calculation step of calculating a secondary electron current through the measured sample current; and an effective incident current definition step of defining the sum of the measured sample current and the calculated secondary electron current as an effective incident current.