Electronic Component Sulfur-Enriched Ni Plated Layer Hydrogen Trapping

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Solution Overview

Problem

Conventional electronic components experience degradation in electrical characteristics due to the diffusion of hydrogen atoms into the body portion, particularly when a Ni plated layer is formed, leading to a decrease in insulation resistance.

Innovation Solution

The electronic component incorporates a base electrode layer with a first Ni plated layer having a sulfur concentration of not less than 5.2×10^18 atoms/cm^3, which acts as a hydrogen trap, and an upper plated layer, to prevent hydrogen diffusion into the body portion, thereby maintaining insulation resistance and reducing component size.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If a Ni plated layer is formed on the base electrode layer, then solder wettability is improved, but hydrogen atoms diffuse into the body portion causing degradation of electrical characteristics

Engineering Contradiction:
Improvesolder wettabilityVSAvoidelectrical characteristics
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

A first Ni plated layer with high sulfur concentration (≥5.2×10^18 atoms/cm³) is introduced as an intermediary between the base electrode layer and the upper plated layer. This layer acts as a mediator that traps hydrogen atoms through sulfur-hydrogen interactions, preventing hydrogen diffusion into the body portion while still allowing the upper plated layer to provide good solder wettability.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The sulfur concentration in the first Ni plated layer is specifically controlled to be not less than 5.2×10^18 atoms/cm³. By changing the chemical composition parameter (sulfur concentration) of the Ni plated layer, the layer gains hydrogen trapping capability while maintaining its electrical and soldering functions.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If the component size is reduced, then productivity is improved, but insulation resistance may be compromised

Engineering Contradiction:
Improvecomponent size reductionVSAvoidinsulation resistance
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The hydrogen atoms that would normally cause harmful diffusion into the body portion are converted into a beneficial effect by being trapped in the first Ni plated layer. The sulfur in this layer binds with hydrogen atoms, transforming the harmful hydrogen diffusion problem into a beneficial hydrogen trapping mechanism that protects the body portion even in smaller component designs.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration effectively reduces or prevents the degradation of electrical characteristics by trapping hydrogen atoms in the Ni plated layer, enhancing insulation resistance and improving solder wettability, while allowing for a smaller component size without compromising insulation resistance.

Implementation Method 1

The first Ni plated layer has a S (sulfur) concentration of not less than about 5.2×10^18 atoms/cm³. The first Ni plated layer acts as a hydrogen trap to prevent hydrogen diffusion into the body portion

Methodology Applied
Scientific EffectHydrogen trapping: Absorption (physical)

Data Source

PatentUS11380485B2Electronic component
Publication Date: 2022.07.05 MURATA MFG CO LTD
  • US11380485B2 patent drawing
  • US11380485B2 patent drawing
  • US11380485B2 patent drawing

AI summary

An electronic component includes a body portion and an external electrode on a surface of the body portion. The external electrode includes a base electrode layer, a first Ni plated layer, and an upper plated layer. The first Ni plated layer is provided on the base electrode layer. The upper plated layer is provided above the first Ni plated layer. The first Ni plated layer has a S concentration of not less than about 5.2×1018 atoms/cm3.