Electrophoretic Dispersion Liquid Transition Metal Control

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Solution Overview

Problem

The existing electrophoretic dispersion liquids do not achieve optimal dispersibility of electrophoretic particles due to the presence of transition metal impurities from catalysts, such as group 8 elements, which hinder the desired level of particle dispersion and electrophoretic properties.

Innovation Solution

The electrophoretic dispersion liquid is formulated with a controlled content of transition metal of group 8 elements, specifically within the range of greater than 0 ppm to equal to or less than 2 ppm, using catalysts for particle surface treatment and dispersants, and employing methods like centrifugation, adsorption, or phase separation to remove excess metal, ensuring the metal is present in a complex or salt form, thereby improving particle dispersibility.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If siloxane-based compounds are used to improve dispersibility of electrophoretic particles, then the affinity between polymer and dispersion medium is improved, but transition metal impurities from catalysts remain in the dispersion liquid and deteriorate dispersibility

Engineering Contradiction:
Improvedispersibility of electrophoretic particlesVSAvoidtransition metal impurities
Core Design Contradiction:
Manufacturing precisionVSObject-affected harmful factors

Solution Approach 1:

The patent applies extraction by removing transition metal impurities from the dispersion liquid through adsorption using specific compounds. The adsorbent selectively binds transition metals (such as Pt, Pd, Rh, Ru, Ir, Os) that remain after siloxane-based compound synthesis, extracting them from the dispersion medium to restore and improve particle dispersibility.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent uses an adsorbent as an intermediary substance to resolve the contradiction. This adsorbent acts as a mediator between the harmful transition metal impurities and the dispersion system, capturing the metals without interfering with the beneficial siloxane-based compounds or electrophoretic particles, thereby eliminating the harmful effect while preserving the improved affinity.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Ease of manufacture

If catalysts containing transition metals are used to generate siloxane-based compounds, then the electrophoretic dispersion liquid can be formulated with improved particle dispersibility, but the transition metals involuntarily remain and prevent optimal dispersibility

Engineering Contradiction:
Improveformulation of electrophoretic dispersion liquidVSAvoiddispersibility of electrophoretic particles
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent converts the harmful presence of transition metal impurities into a manageable situation by using the same transition metal-containing adsorbents to capture and remove these impurities. The adsorbent materials (such as activated carbon, alumina, silica gel) that may contain trace transition metals are used to adsorb the free transition metal ions, transforming the contamination problem into a controlled purification process.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances the dispersibility and electrophoretic properties of the particles, allowing for improved migration and maintaining contrast without particle aggregation, thus enhancing the performance and reliability of electrophoretic devices.

Implementation Method 1

the fact that when an electric field is applied to a disperse system in which fine particles are dispersed in a fluid, the fine particles move (migrate) in the fluid by Coulomb's force has been known. This phenomenon is called electrophoresis

Methodology Applied
Scientific EffectElectrophoresis: Electrophoresis

Implementation Method 2

employing methods like centrifugation, adsorption, or phase separation to remove excess metal

Methodology Applied
Scientific EffectCentrifugation: Centrifugal Separation

Implementation Method 3

employing methods like centrifugation, adsorption, or phase separation to remove excess metal

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 4

an electrophoretic dispersion liquid including at least one type of electrophoretic particles and a dispersion medium

Methodology Applied
Scientific EffectDispersion: Dispersion (of waves)

Data Source

PatentUS10968354B2Electrophoretic dispersion liquid, production method of electrophoretic dispersion liquid, electrophoretic sheet, electrophoretic device and electronic apparatus
Publication Date: 2021.04.06 E INK CORP
  • US10968354B2 patent drawing
  • US10968354B2 patent drawing
  • US10968354B2 patent drawing

AI summary

According to the invention, an electrophoretic dispersion liquid includes at least one type of an electrophoretic particle, and a dispersion medium, in which the content of transition metal of group 8 elements derived from a catalyst which is used to generate at least one of a block copolymer (a particle surface treatment agent) used to form the electrophoretic particle and the dispersion medium is in a range of greater than 0 ppm to equal to or less than 2 ppm in the electrophoretic dispersion liquid.