Electrophoretic Particle Coating for Charge Control

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Solution Overview

Problem

Existing electrophoresis display devices face challenges in controlling the charging amount of electrophoretic particles to achieve suitable migration speed, leading to difficulties in uniform dispersion and aggregation prevention in electrophoresis dispersion liquids.

Innovation Solution

The use of block copolymers with specific monomers and silane coupling agents to form a coating layer on electrophoretic particles, enhancing dispersibility and allowing for precise control of charging amounts by interposing a second compound with a non-polar group between the first compounds connected to the particles, thereby improving dispersion and preventing aggregation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If a simple polymer coating is provided on base material particles, then the particles can be dispersed in electrophoresis dispersion liquid, but the charging amount cannot be controlled to a suitable range

Engineering Contradiction:
Improvecharging amountVSAvoidcontrol of charging amount
Core Design Contradiction:
Quantity of substanceVSEase of manufacture

Solution Approach 1:

The coating is segmented into multiple functional layers: a first compound (block copolymer) that provides dispersibility and a second compound (silane coupling agent) that controls charge. This segmentation allows independent optimization of dispersibility and charging properties, enabling precise control of charging amount while maintaining ease of manufacture through a systematic multi-step coating process.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent uses a composite coating structure combining a block copolymer (first compound) and a silane coupling agent (second compound). The block copolymer provides the dispersibility function while the silane coupling agent provides the charge control function. This composite material approach allows simultaneous achievement of suitable dispersibility and controllable charging amount.

Inventive Principle:
Principle #40Composite materials

2Reliability

If electrophoretic particles are dispersed in electrophoresis dispersion liquid, then display function is achieved, but aggregation occurs reducing display quality

Engineering Contradiction:
Improvedispersion uniformityVSAvoidaggregation
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The first compound (block copolymer) acts as an intermediary between the base material particles and the electrophoresis dispersion liquid. Its dispersion portion interacts with the liquid medium while its bonding portion attaches to the particle surface, preventing direct particle-particle contact and thereby preventing aggregation. This intermediary mechanism ensures reliable uniform dispersion and maintains high display quality.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent modifies the surface parameters of electrophoretic particles by introducing compounds with specific functional groups that change the surface properties. The block copolymer changes the surface hydrophobicity/hydrophilicity balance to improve dispersibility, while the silane coupling agent modifies surface charge characteristics. These parameter changes prevent aggregation and ensure uniform dispersion.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in electrophoretic particles with superior dispersibility and controlled charging, leading to enhanced performance in electrophoresis dispersion liquids, including improved display contrast and reduced aggregation, thus addressing the challenges of uniform dispersion and migration speed control.

Implementation Method 1

the first compound is a block copolymer that includes a dispersion portion derived from a first monomer including a site that contributes to dispersibility in a dispersion medium, and a bonding portion derived from a second monomer including a second functional group having reactivity with the first functional group, and is connected to the particle by the reacting the first functional group and the second functional group in the bonding portion

Methodology Applied
Scientific EffectChemical Bonding: Chemical Bonding

Implementation Method 2

the second compound has a lower molecular weight than the first compound, includes a non-polar group and the second functional group, and is connected to the particle by reacting the second functional group reacting with the first functional group

Methodology Applied
Scientific EffectVan der Waals force reduction: Van der Waals Force

Implementation Method 3

when a dispersion system in which fine particles are dispersed in a liquid is acted on by an electrical field, the fine particles are moved (migrate) in the liquid due to Coulomb force

Methodology Applied
Scientific EffectCoulomb force: Coulomb's Law

Implementation Method 4

This phenomenon is known as electrophoresis, and in recent years, electrophoresis display devices in which desired information (images) is displayed using electrophoresis have garnered attention as new display devices

Methodology Applied
Scientific EffectElectrophoresis: Electrophoresis

Data Source

PatentUS10001692B2Electrophoretic particle, method of manufacturing electrophoretic particle, electrophoresis dispersion liquid, electrophoresis sheet, electrophoresis device, and electronic apparatus
Publication Date: 2018.06.19 E INK CORP
  • US10001692B2 patent drawing
  • US10001692B2 patent drawing
  • US10001692B2 patent drawing

AI summary

An electrophoretic particle includes a base particle (particle) that includes a first functional group, and a first compound and a second compound bonded to the base particle. The first compound is a polymer that includes a dispersion portion derived from a first monomer that contributes to dispersibility and a bonding portion derived from a second monomer including a second functional group having reactivity to the first functional group, and is connected to the base particle at the bonding portion. The second compound has a lower molecular weight than the first compound, includes a non-polar group and the second functional group, and is connected to the base particle at the second functional group.