Electrophoretic Particle Coating for Uniform Dispersion and Charge Control

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Solution Overview

Problem

In electrophoresis display devices, controlling the charging amount of electrophoretic particles to achieve a suitable migration speed is challenging due to the difficulty in uniformly dispersing and charging these particles in the dispersion liquid.

Innovation Solution

The use of electrophoretic particles with a specific configuration, including a block copolymer with a dispersion portion and a bonding portion, a non-polar group, and a charging group, which are bonded to the particle surface using silane coupling agents, enhances dispersibility and chargeability, allowing for precise control of charging amounts.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If a simple polymer coating layer is provided on base material particles, then the manufacturing process is simple, but the dispersibility and chargeability cannot be uniformly controlled

Engineering Contradiction:
Improvemanufacturing simplicityVSAvoiduniformity of dispersibility and chargeability
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The coating layer is segmented into multiple functional layers: a first coating layer containing silane coupling agent for base bonding, and a second coating layer containing block copolymer for dispersibility. This segmentation allows each layer to independently optimize its function, achieving both uniform dispersibility and controlled chargeability while maintaining manufacturing feasibility through sequential coating processes.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The coating layer uses composite material structure combining silane coupling agent (for strong particle bonding) and block copolymer (for dispersibility and chargeability control). This composite approach integrates the advantages of different materials: the silane provides uniform anchoring to base particles, while the block copolymer provides controlled interaction with dispersion medium, resolving the contradiction between manufacturing simplicity and uniform performance control.

Inventive Principle:
Principle #40Composite materials

2Speed

If the charging amount of electrophoretic particles is increased to improve migration speed, then the migration speed increases, but the dispersibility deteriorates and aggregation occurs

Engineering Contradiction:
Improvemigration speedVSAvoiddispersibility
Core Design Contradiction:
SpeedVSStability of the object's composition

Solution Approach 1:

The block copolymer in the second coating layer provides local quality differentiation: the polar portion interacts with charged surfaces to control chargeability, while the nonpolar portion interacts with nonpolar dispersion media to ensure dispersibility. This local quality assignment allows the particle to simultaneously achieve adequate charging for migration speed while maintaining stable dispersion through the nonpolar portion's interaction with the dispersion medium.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The invention changes the chemical and physical parameters of the coating layer by introducing block copolymer with specific polar and nonpolar portions. This parameter change enables independent control of chargeability (through polar portion composition and quantity) and dispersibility (through nonpolar portion composition), allowing optimization of migration speed without sacrificing dispersibility.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration ensures uniform dispersion and controlled charging of electrophoretic particles, improving their performance in electrophoresis dispersion liquids, leading to enhanced display properties such as high contrast and low power consumption.

Implementation Method 1

a silane coupling agent 531 having a polymerization initiation group is bonded to the surface of the base material particles 502

Methodology Applied
Scientific EffectChemical Bonding: Chemical Bonding

Implementation Method 2

the fine particles are moved (migrate) in the liquid due to Coulomb force when an electrical field is operated in a dispersion system

Methodology Applied
Scientific EffectCoulomb force: Coulomb's Law

Implementation Method 3

This phenomenon is known as electrophoresis

Methodology Applied
Scientific EffectElectrophoresis: Electrophoresis

Data Source

PatentUS10597541B2Electrophoretic particle, method of manufacturing electrophoretic particle, electrophoresis dispersion liquid, electrophoresis sheet, electrophoresis device, and electronic apparatus
Publication Date: 2020.03.24 E INK CORP
  • US10597541B2 patent drawing
  • US10597541B2 patent drawing
  • US10597541B2 patent drawing

AI summary

An electrophoretic particle includes a base particle (particle), a first compound, a second compound, and a third compound bonded to the base particle. The first compound is a polymer having a dispersion portion derived from a first monomer, and a bonding portion derived from a second monomer, and is connected to the base particle at the bonding portion. The second compound includes a non-polar group and a second functional group and is connected to the base particle at the second functional group. The third compound includes a charging group and a second functional group and is connected to the base particle at the second functional group.