Electrophoretic Particle Coating for Dispersibility and Mobility

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Solution Overview

Problem

Electrophoretic particles in displays exhibit low mobility due to reduced charge when the density of polymer molecules attached to their surfaces is high, affecting their dispersibility and functionality in electrophoretic dispersions.

Innovation Solution

The development of electrophoretic particles with a core particle coated by a layer containing a polymer and a silane coupling agent with a nonionic charged group, which enhances both dispersibility and mobility by controlling the weight fraction and hydrophobicity of the coating layer, allowing for improved charge distribution and stability in the dispersion medium.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If the density of polymer molecules attached to the surface of electrophoretic particles is increased to improve dispersibility, then the dispersibility is improved, but the charge of the particles is reduced, resulting in low mobility

Engineering Contradiction:
ImprovedispersibilityVSAvoidmobility
Core Design Contradiction:
Stability of the object's compositionVSSpeed

Solution Approach 1:

The patent applies local quality by creating a coating layer with specific local characteristics (silane coupling agent containing nonionic charged groups) on the particle surface, rather than uniformly distributing all functional groups throughout the polymer. This localized functional grouping maintains charge density in specific regions while allowing overall polymer coverage for dispersibility.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent uses composite materials by combining polymer molecules with silane coupling agents that contain nonionic charged groups. This composite structure on the particle surface provides both the dispersibility benefits of polymer coverage and the charge benefits of ionizable groups, resolving the contradiction between these two properties.

Inventive Principle:
Principle #40Composite materials

2Stability of the object's composition

If a coating layer is added to improve dispersibility, then dispersibility is improved, but the particle charge is reduced, affecting mobility

Engineering Contradiction:
ImprovedispersibilityVSAvoidmobility
Core Design Contradiction:
Stability of the object's compositionVSReliability

Solution Approach 1:

The patent applies parameter changes by modifying the chemical composition parameters of the coating layer to include silane coupling agents with nonionic charged groups. This changes the charge density parameter and electrical properties of the coating, enabling both good dispersibility and maintained mobility through appropriate parameter selection.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enables electrophoretic particles to exhibit both excellent dispersibility and mobility, leading to high reliability in electrophoretic dispersions, sheets, devices, and apparatuses, with enhanced performance and stability under various conditions.

Implementation Method 1

when an electric field is applied to a dispersion containing a liquid and fine particles dispersed therein, the fine particles move (electrophoretically migrate) in the liquid because of the Coulomb force. This phenomenon is referred to as electrophoresis.

Methodology Applied
Scientific EffectElectrophoresis: Electrophoresis

Implementation Method 2

the fine particles move (electrophoretically migrate) in the liquid because of the Coulomb force

Methodology Applied
Scientific EffectCoulomb force: Coulomb's Law

Implementation Method 3

a polymerization site formed by polymerizing a monomer using the polymerizable group as a starting point

Methodology Applied
Scientific EffectPolymerization: Photopolymerisation

Data Source

PatentUS8817361B2Electrophoretic particle, method for producing electrophoretic particle, electrophoretic dispersion, electrophoretic sheet, electrophoretic device, and electronic apparatus
Publication Date: 2014.08.26 E INK CORP
  • US8817361B2 patent drawing
  • US8817361B2 patent drawing
  • US8817361B2 patent drawing

AI summary

An electrophoretic particle includes a core particle and a coating layer covering at least one portion of the core particle. The coating layer contains a polymer and a silane coupling agent containing a nonionic charged group attached to the surface of the core particle. The polymer contains a silane coupling agent containing a polymerizable group attached to the surface of the core particle and a polymerization site formed by polymerizing a monomer using the polymerizable group as a starting point.