Electroplating Metal Alloy Features Composition Control

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Solution Overview

Problem

The challenge in forming metal alloy features, such as lead-free solders and Permalloy, is the variability in the weight ratio of alloying metals due to differing reduction potentials, leading to inconsistent composition and performance issues in microelectronic applications, where uniformity is crucial for magnetic and soldering properties.

Innovation Solution

A method involving an electroplating process where the electric potential is adjusted to control current densities and deposition rates, allowing for precise control of the weight ratio of alloying metals within the metal alloy feature, either maintaining uniformity or achieving desired variations by adjusting current densities and agitation speeds during the deposition process.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional electroplating is used with alloying metals of different reduction potentials, then deposition occurs, but composition uniformity deteriorates

Engineering Contradiction:
Improvecomposition uniformityVSAvoidalloy composition consistency
Core Design Contradiction:
Manufacturing precisionVSStability of the object's composition

Solution Approach 1:

The patent applies dynamic control of deposition parameters by adjusting current density and agitation speed during the electroplating process. The system transitions from static conventional plating to dynamic parameter adjustment, where current density and agitation are varied in real-time to compensate for composition drift, thereby maintaining uniform alloy composition throughout deposition.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The patent implements parameter changes by modifying current density and agitation speed as process variables. By changing these parameters during deposition, the system compensates for the inherent compositional instability caused by different reduction potentials, achieving consistent alloy composition through active parameter control.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If electroplating is performed without parameter adjustment, then process simplicity is maintained, but deposition rate control deteriorates

Engineering Contradiction:
Improvedeposition rateVSAvoidprocess control complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent utilizes parameter changes to control deposition rate by adjusting current density and agitation speed. This allows precise productivity control while managing the increased process complexity through systematic parameter management rather than hardware complexity.

Inventive Principle:
Principle #35Parameter changes

3Productivity

If high current density is used, then deposition speed increases, but composition uniformity deteriorates

Engineering Contradiction:
Improvedeposition speedVSAvoidalloy composition uniformity
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent applies dynamic control where current density is adjusted during deposition rather than maintained at a constant high level. This dynamic adjustment allows the system to achieve high overall deposition speed while maintaining composition uniformity by optimizing current density at different stages of the process.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The patent implements periodic action through pulsed or cyclic adjustment of current density and agitation speed. This periodic modulation prevents the compositional non-uniformity that would result from continuous high current density while maintaining high average deposition speed through optimized cycling patterns.

Inventive Principle:
Principle #19Periodic action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach minimizes compositional variations within metal alloy features, ensuring consistent performance and preventing issues like incomplete reflow in soldering and maintaining desired magnetic properties, thereby enhancing the reliability and integrity of microelectronic components.

Implementation Method 1

The microfeature workpiece is contacted with an electroplating bath that is also in contact with an electrode. Applying an electric potential between the metal feature and the electrode produces a current density that causes a metal alloy to be deposited within the recessed feature.

Methodology Applied
Scientific EffectElectroplating: Electroplating

Implementation Method 2

Applying an electric potential between the metal feature and the electrode produces a current density that causes a metal alloy to be deposited within the recessed feature.

Methodology Applied
Scientific EffectElectrodeposition: Electrodeposition

Implementation Method 3

When metal ions in an electroplating solution have similar reduction potentials, the weight ratio of the metals deposited as an alloy tend to be similar to the ratio of concentrations of the metal ions in the electroplating solution.

Methodology Applied
Scientific EffectReduction: Reduction

Data Source

PatentUS9359683B2Method of forming metal and metal alloy features
Publication Date: 2016.06.07 APPLIED MATERIALS INC
  • US9359683B2 patent drawing
  • US9359683B2 patent drawing
  • US9359683B2 patent drawing

AI summary

Electric potential, current density, agitation, and deposition rate are controlled to deposit metal alloys, such as tin based solder alloys or magnetic alloys, with minimal variations in the weight ratios of alloying metals at different locations within the deposited metal alloy feature. Alternative embodiments include processes that form metal alloy features wherein the variation in weight ratio of alloying metals within the feature is not necessarily minimized, but is controlled to provide a desired variation. In addition to metal alloys, alternative embodiments include processes for improving the deposition of single metal features.