Electroplating Jet Array for High Mass-Transfer

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Solution Overview

Problem

Conventional electroplating systems face challenges in achieving uniformity of the plated film across semiconductor wafers, particularly due to irregularities in the electric field, mass-transfer rates, and deep trench features, which can lead to co-planarity issues and limited deposition rates.

Innovation Solution

The introduction of a submerged spray jet array within the electroplating vessel, which sprays pressurized jets of electrolyte against the wafer, significantly increases the strain rate and mass transfer rate, enabling higher deposition rates and improved co-planarity, especially in deep trench features.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional electroplating methods are used, then the process is simpler to implement, but the mass transfer rate is insufficient leading to limited deposition rates and poor co-planarity

Engineering Contradiction:
Improvedeposition rateVSAvoidelectroplating system complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent employs a spray jet array that delivers pressurized electrolyte directly to the wafer surface through multiple small orifices. This hydraulic approach creates high-velocity jets that dramatically enhance mass transfer of metal ions to the substrate, enabling deposition rates approximately an order of magnitude higher than conventional electroplating while maintaining system complexity at a manageable level through the use of standard pump and spray component technology

Inventive Principle:
Principle #29Pneumatics and hydraulics

2Manufacturing precision

If conventional electroplating is used, then the system is easier to operate, but uniformity of plated film across the wafer is poor due to irregularities in mass transfer rates

Engineering Contradiction:
Improveplated film uniformityVSAvoidelectroplating process operation
Core Design Contradiction:
Manufacturing precisionVSEase of operation

Solution Approach 1:

The electrolyte delivery system is segmented into multiple discrete spray jets distributed across the wafer surface. Each jet independently delivers electrolyte to a specific region, ensuring uniform mass transfer rates across the entire substrate. This segmented approach compensates for variations in wafer geometry and electric field distribution, achieving consistent plated film uniformity while maintaining straightforward operational procedures

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The spray jet array provides locally optimized electrolyte delivery by positioning multiple jets at specific locations across the wafer surface. Each jet is tailored to deliver appropriate electrolyte flow to its corresponding region, accounting for local variations in current density and mass transfer requirements. This local quality approach ensures uniform deposition across the entire wafer while keeping the overall system easy to operate

Inventive Principle:
Principle #3Local quality

3Manufacturing precision

If conventional electroplating methods are used, then the equipment is less complex, but co-planarity in deep trench features is poor

Engineering Contradiction:
Improveco-planarityVSAvoidspray jet array complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

High-velocity pressurized spray jets are directed into deep trench features to forcibly deliver electrolyte to the bottom surfaces and sidewalls. The hydraulic pressure overcomes the difficulty of reaching into deep geometries, ensuring uniform mass transfer and co-planar deposition even in challenging deep trench structures, while the spray jet array itself remains a relatively simple component configuration

Inventive Principle:
Principle #29Pneumatics and hydraulics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances the mass transfer rate by approximately an order of magnitude, allowing for higher deposition rates and improved co-planarity across semiconductor wafers, while also reducing the complexity and cost associated with conventional methods.

Implementation Method 1

sprays pressurized jets of electrolyte against the wafer

Methodology Applied
Scientific EffectPressurized fluid flow: Pressure Gradient

Implementation Method 2

significantly increases the strain rate and mass transfer rate

Methodology Applied
Scientific EffectMass transfer: Diffusion

Implementation Method 3

electric current is conducted through an electrolyte to the wafer, to deposit a blanket layer or patterned layer of a metal or other conductive material onto the seed layer

Methodology Applied
Scientific EffectElectroplating: Electroplating

Implementation Method 4

electric current is conducted through an electrolyte to the wafer, to deposit

Methodology Applied
Scientific EffectElectrodeposition: Electrodeposition

Data Source

PatentUS20250116028A1Electroplating chamber using jet array to enable high mass-transfer
Publication Date: 2025.04.10 APPLIED MATERIALS INC
  • US20250116028A1 patent drawing
  • US20250116028A1 patent drawing
  • US20250116028A1 patent drawing

AI summary

Exemplary electroplating systems may include a vessel. The systems may include a head that is configured to hold a substrate. The head may be positionable within an interior of the vessel. The systems may include a spray jet array disposed within the interior of the vessel. The spray jet array may include a plate defining a plurality of apertures through a thickness of the plate. The systems may include at least one fluid pump that is fluidly coupled with an inlet end of each of the plurality of apertures.