Electroslag Welding Wire Composition for 9% Ni Steel Joints

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Solution Overview

Problem

Existing welding methods for 9% Ni steel, such as coated arc welding and TIG welding, result in weld metals with lower strength and cryogenic toughness compared to the base metal, necessitating thicker designs and higher heat input, while also posing challenges in working environment and mechanical performance.

Innovation Solution

Development of an electroslag welding wire and flux combination with specific chemical compositions, including 6.0-15.0% Ni, C, Si, Mn, and Fe, along with optional elements like Cu, Cr, Mo, W, Nb, V, and B, and a slag forming agent, to achieve high heat input welding with improved mechanical properties and reduced atmospheric interference.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional welding methods (coated arc welding, TIG welding) are used for 9% Ni steel, then cryogenic toughness is improved, but strength decreases and design plate thickness must be increased

Engineering Contradiction:
Improvecryogenic toughnessVSAvoidweld metal strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The invention changes the chemical composition parameters of the weld material by specifying precise ranges for C (0.005-0.10%), Si (0.01-0.50%), Mn (0.01-1.00%), Ni (6.0-15.0%), and other alloying elements, along with their interactions (e.g., Ni×C≥0.006, (Ni+Cr+Mo)×C≥0.008). These parameter changes enable the weld metal to simultaneously achieve high strength and excellent cryogenic toughness, resolving the contradiction between strength and reliability.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If conventional welding methods are used, then cryogenic toughness is maintained, but heat input increases and working environment deteriorates

Engineering Contradiction:
Improvecryogenic toughnessVSAvoidheat input
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The invention replaces conventional arc welding methods with electroslag welding, substituting the arc heating mechanism with resistive heating through molten flux. This substitution reduces heat input (to 10 kJ/mm or more, which is lower than conventional methods for achieving similar results) and improves working conditions by eliminating arc radiation and spatter, while the controlled composition ensures cryogenic toughness is maintained.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Reliability

If Ni-based weld material is used to improve cryogenic toughness, then toughness is enhanced, but strength decreases and productivity is reduced

Engineering Contradiction:
Improvecryogenic toughnessVSAvoidwelding efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The invention optimizes the Ni content parameter to 6.0-15.0% and establishes specific interaction parameters (Ni×C≥0.006, (Ni+Cr+Mo)×C≥0.008) that enable lower Ni usage compared to conventional Ni-based weld materials. This parameter optimization achieves the required cryogenic toughness while reducing material cost and improving welding productivity through the electroslag process.

Inventive Principle:
Principle #35Parameter changes

4Use of energy by moving object

If electroslag welding is used to reduce heat input, then energy efficiency is improved, but achieving high strength and toughness simultaneously becomes difficult

Engineering Contradiction:
Improveheat inputVSAvoidweld metal strength
Core Design Contradiction:
Use of energy by moving objectVSStrength

Solution Approach 1:

The invention creates a composite chemical composition system combining multiple alloying elements (C, Si, Mn, Ni, Cr, Mo, B, etc.) with specific interaction relationships. This composite material approach, applied to the electroslag welding process, enables the weld metal to achieve high strength (comparable to base metal) and excellent toughness simultaneously, while maintaining the energy efficiency benefits of electroslag welding with controlled heat input of 10 kJ/mm or more.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enables weld joints with enhanced strength and cryogenic toughness, even at high heat inputs of 10 kJ/mm or more, improving working conditions and mechanical performance by reducing arc radiation and spatter, and eliminating the need for shielding gas.

Implementation Method 1

electroslag welding

Methodology Applied
Scientific EffectJoule heating: Joule Heating

Implementation Method 2

a molten flux barrier that shields the weld pool from atmospheric contamination, eliminating the need for external shielding gas

Methodology Applied
Scientific EffectMolten slag shielding:

Implementation Method 3

reduces heat input and improves energy efficiency compared to conventional arc welding methods

Methodology Applied
Scientific EffectControlled thermal energy:

Data Source

PatentEP3513901B1Wire for electroslag welding, flux for electroslag welding and welded joint
Publication Date: 2022.01.12 KOBE STEEL LTD
  • EP3513901B1 patent drawingFigure 1
  • EP3513901B1 patent drawing
  • EP3513901B1 patent drawing

AI summary

The present invention relates to a wire for electroslag welding, which is characterized by containing, in mass% relative to the total mass of the wire, more than 0% but 0.07% or less of C, more than 0% but 0.50% or less of Si, more than 0% but 1.0% or less of Mn, from 6.0% to 15.0% of Ni and 79% or more of Fe, while satisfying formula (1). The present invention also relates to: a flux for electroslag welding, which is used in electroslag welding together with the wire for electroslag welding; and a welded joint which is produced by electroslag welding that uses the wire for electroslag welding and the flux for electroslag welding. 0.150 ≤ C + Si/30 + Mn/20 + Ni/60 ≤ 0.300 (1)