Electrostatic Adhesive Deposition with Delayed Curing

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Solution Overview

Problem

Electrostatic deposition of adhesive materials faces challenges such as agglomeration, stickiness, and immediate curing, which hinder effective layer formation and usability, particularly when requiring delayed activation and bonding of substrates.

Innovation Solution

The method involves electrostatically delivering a powdered adhesive precursor in a dry solid state using an electromagnetic brush printing apparatus, allowing for controlled layer thickness and delayed curing by transforming the particles into a cross-linked reaction product capable of bonding substrates, with the adhesive remaining in a powdered form during storage and deposition.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If adhesive materials are deposited using electrostatic deposition, then layer thickness control is improved, but agglomeration and stickiness occur reducing effectiveness

Engineering Contradiction:
Improvelayer thickness controlVSAvoidadhesive effectiveness
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The invention changes the physical-chemical parameters of the adhesive material by using a two-component system where Component A remains non-tacky at deposition temperature while Component B is added later to initiate curing. This parameter change (temperature-dependent viscosity and reactivity) allows the adhesive to be deposited without agglomeration and then cured on-demand, resolving the contradiction between thickness control and adhesive effectiveness

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention performs preliminary action by pre-mixing Component A with reactive diluents and hardeners that remain dormant at deposition temperature. The adhesive is prepared in advance in a stable, non-tacky state suitable for electrostatic deposition, and the actual curing action is delayed until Component B is added post-deposition, thus preventing agglomeration during deposition while ensuring effectiveness after bonding

Inventive Principle:
Principle #10Preliminary action

2Strength

If immediate curing is performed as common with electrostatically deposited materials, then adhesion is achieved, but substrate must be immediately adhered to second substrate which is not always desirable

Engineering Contradiction:
Improveadhesion strengthVSAvoidmanufacturing flexibility
Core Design Contradiction:
StrengthVSEase of operation

Solution Approach 1:

The invention introduces dynamic control over the curing process by using a two-component system where the adhesive transitions from a stable, non-curing state (Component A alone) to an active curing state (Component A + Component B). This dynamic approach allows the adhesive to remain operational and repositionable during manufacturing, then cure immediately when bonding is required, providing both strong adhesion and manufacturing flexibility

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The adhesive is prepared in advance as Component A in a preliminary state that is stable and non-tacky, allowing for delayed curing. This preliminary preparation enables the adhesive to be deposited and handled without immediate curing, providing manufacturing flexibility, while the pre-included reactive components ensure strong adhesion once Component B is added and curing is initiated

Inventive Principle:
Principle #10Preliminary action

3Stability of the object's composition

If adhesive is formulated to remain stable during storage, then storage stability is improved, but curing activation must be delayed until desired stage

Engineering Contradiction:
Improvestorage stabilityVSAvoidcure delay time
Core Design Contradiction:
Stability of the object's compositionVSLoss of time

Solution Approach 1:

The invention segments the adhesive into two separate components: Component A (stable base with reactive diluents and hardeners) and Component B (curing agent). This segmentation allows Component A to be stored indefinitely in a stable, non-tacky state, while the actual curing action is deferred until Component B is mixed in at the desired stage, thus resolving the contradiction between storage stability and cure timing control

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Component A is prepared in advance with all necessary reactive components (dilulents, hardeners, catalysts) in a preliminary mixed state that remains stable during storage. The actual curing action is preliminarily prepared but not activated until Component B is added, allowing the adhesive to maintain storage stability while enabling cure activation at the desired time stage

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the formation of a thin, tack-free adhesive film that can be handled easily during assembly, achieving durable adhesion and allowing for delayed curing, thus addressing the issues of agglomeration and immediate curing in electrostatic deposition.

Implementation Method 1

electrostatically delivering a powdered adhesive precursor to a substrate to form a precursor layer

Methodology Applied
Scientific EffectElectrostatic deposition: Electrostatic Deposition

Implementation Method 2

The step of physically transforming the particles may include a step of heating the particles to a temperature of at least 60-80°C less than the temperature for the step of heating the precursor layer film

Methodology Applied
Scientific EffectThermal heating: Heating

Implementation Method 3

The step of subjecting the precursor layer film to a reaction activation condition may include heating the film to a temperature above a cross-linking activation temperature for cross-linking the precursor layer film

Methodology Applied
Scientific EffectThermal cross-linking: Heating

Data Source

PatentEP3916062B1Method and apparatus for adhesive deposition
Publication Date: 2024.11.06 ZEPHYROS INC

AI summary

An improved approach toward the electrostatic deposition of activatable adhesive formulations is disclosed. The activatable adhesive formulations are formed for transforming from a dry powder precursor layer to a precursor layer film.