Electrostatic Ink With Non-Metallic Pigments

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Solution Overview

Problem

Electrostatic printing processes using metallic pigments often result in undesired discharge when subjected to high electric fields, which affects the quality of the printed image.

Innovation Solution

An electrostatic ink composition comprising a liquid carrier, chargeable particles made of a co-polymer of an alkylene monomer and an acrylic acid monomer, and a pearlescent, non-metallic pigment, which are dispersed in the carrier, allowing for the formation of a latent electrostatic image that adheres to a surface and transfers well to a print substrate without metallic discharge issues.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If metallic pigments are used in electrostatic ink compositions, then the printed image achieves a metallic appearance, but discharge occurs in high electric fields affecting image quality

Engineering Contradiction:
Improvemetallic appearanceVSAvoiddischarge in high electric fields
Core Design Contradiction:
Illumination intensityVSReliability

Solution Approach 1:

The harmful metallic property (discharge tendency) is extracted from the pigment material itself by replacing metallic pigments with non-metallic pearlescent pigments, while retaining the desired metallic appearance through optical effects rather than electrical conductivity

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The chemical composition parameter of the pigment is changed from metallic to non-metallic (pearlescent), fundamentally altering the electrical properties while maintaining or enhancing the visual metallic appearance through light reflection and interference effects

Inventive Principle:
Principle #35Parameter changes

2Device complexity

If conventional electrostatic ink compositions are used, then the printing process is simple, but transfer efficiency to print substrate is insufficient

Engineering Contradiction:
Improveprinting process complexityVSAvoidtransfer efficiency
Core Design Contradiction:
Device complexityVSProductivity

Solution Approach 1:

The polymer composition parameters are optimized by selecting specific polymers with appropriate glass transition temperatures and charge densities, improving the toner particles' adhesion to the photoconductive surface and transfer efficiency to the print substrate without complicating the overall printing process

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The ink composition uses composite materials combining specific polymers (with glass transition temperatures of 50-150°C and charge densities of 0.01-0.1 µC/cm²) with non-metallic pearlescent pigments, creating a formulation that enhances transfer efficiency while maintaining process simplicity

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ink composition achieves a metallic appearance on the print substrate with improved transfer efficiency and reduced discharge in high electric fields, maintaining image quality and substrate compatibility.

Implementation Method 1

The charged toner particles adhere to the image areas of the latent image while the background areas remain clean

Methodology Applied
Scientific EffectElectrostatic attraction: Electrostatics

Implementation Method 2

The image is then transferred to a print substrate (e.g. paper) directly or, by being first transferred to an intermediate transfer member

Methodology Applied
Scientific EffectElectrostatic transfer: Electrostatics

Data Source

PatentEP2951246B1Electrostatic ink compositions, methods and print substrates
Publication Date: 2019.03.13 HEWLETT PACKARD DEVELOPMENT COMPANY LP
  • EP2951246B1 patent drawingFigure 1
  • EP2951246B1 patent drawing
  • EP2951246B1 patent drawing

AI summary

Described herein is an electrostatic ink composition comprising a liquid carrier; and chargeable particles comprising a co-polymer of an alkylene monomer and an acrylic acid monomer, and a pearlescent, non-metallic pigment, wherein the chargeable particles are dispersed in the liquid carrier. Also described herein are a method of electrophotographic printing and a print substrate.