Electrostatic Nanoporous Stamps for Sub-10 μm Printing

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Solution Overview

Problem

Current printing technologies, such as inkjet and relief printing, face limitations in achieving high resolution and uniformity due to the size of ink droplets and hydrodynamic instability, which restricts feature sizes to 50 μm or larger.

Innovation Solution

The use of electrostatic nanoporous stamps with vertically aligned carbon nanotubes and a dielectric coating allows for precise control of ink loading and release through electrostatic forces, enabling printing with feature sizes smaller than 10 μm and achieving high resolution and uniformity by adjusting the voltage applied to the conductive microstructures.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If inkjet printing uses smaller droplet sizes to achieve higher resolution, then printing resolution improves, but the force required to eject droplets exceeds the capability of transducers

Engineering Contradiction:
Improveprinting resolutionVSAvoidforce required to eject droplets
Core Design Contradiction:
Manufacturing precisionVSForce

Solution Approach 1:

The patent replaces the mechanical inkjet ejection system with an electrostatic contact printing system. Instead of using transducers to eject droplets through mechanical force, the invention uses electrostatic forces to load ink into nanoporous stamps and transfer it to substrates, enabling sub-10 μm resolution without the force limitations of inkjet transducers

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent employs nanoporous stamps with pore sizes of 100 nm or less to achieve high-resolution printing. The porous structure allows precise control of ink loading and transfer, enabling feature sizes below 10 μm while avoiding the droplet size limitations of inkjet printing

Inventive Principle:
Principle #31Porous materials

2Manufacturing precision

If relief printing uses thin liquid films to achieve higher resolution, then printing resolution improves, but the film dewets from the surface due to hydrodynamic instability

Engineering Contradiction:
Improveprinting resolutionVSAvoidfilm stability
Core Design Contradiction:
Manufacturing precisionVSStability of the object's composition

Solution Approach 1:

The patent uses nanoporous stamps with controlled pore sizes (100 nm or less) to hold ink in a stable manner. The porous structure prevents hydrodynamic instability and dewetting by confining the ink within the porous network, allowing thin film transfer without the instability issues of conventional relief printing

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The patent employs composite structures combining conductive materials (for electrostatic control) with porous materials (for ink loading and transfer). This composite approach enables precise control of ink film stability while achieving high-resolution printing, overcoming the limitations of conventional relief printing materials

Inventive Principle:
Principle #40Composite materials

3Quantity of substance

If relief printing uses thick liquid films to achieve higher ink coverage, then ink transfer improves, but the film spreads outwards from the contact area

Engineering Contradiction:
Improveink transfer amountVSAvoidpattern fidelity
Core Design Contradiction:
Quantity of substanceVSShape

Solution Approach 1:

The patent uses nanoporous stamps with controlled porosity and pore size to regulate ink transfer. The porous structure allows sufficient ink loading while preventing outward spreading during transfer, maintaining pattern fidelity even with increased ink coverage through electrostatic control of the ink-stamp-substrate interface

Inventive Principle:
Principle #31Porous materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables high-resolution printing with feature sizes below 10 μm and uniform layer thickness, suitable for electronic device fabrication, with improved control over the amount of ink transferred and pattern formation.

Implementation Method 1

applying a voltage between a conductive layer in the nanoporous print stamp and the ink to load the ink into a dielectric-coated porous medium disposed on the conductive layer based at least in part on an electrostatic force between the nanoporous print stamp and the ink

Methodology Applied
Scientific EffectElectrostatic force: Electrostatics

Implementation Method 2

contacting the nanoporous print stamp with a target substrate and adjusting an amplitude of the voltage between the conductive layer and the ink to release the ink from the nanoporous print stamp and onto the target substrate so as to form a pattern

Methodology Applied
Scientific EffectElectrostatic force: Electrostatics

Data Source

PatentUS11396196B2Apparatus and methods for contact-printing using electrostatic nanoporous stamps
Publication Date: 2022.07.26 MASSACHUSETTS INST OF TECH
  • US11396196B2 patent drawing
  • US11396196B2 patent drawing
  • US11396196B2 patent drawing

AI summary

Methods and apparatus for contacting printing via electrostatic force. In one example, an apparatus for contact printing using an ink includes a substrate, a conductive layer disposed on the substrate, and a group of microstructures disposed on the conductive layer. Each microstructure includes a group of conductive porous medium extending from the conductive layer. The apparatus also includes a dielectric layer conformally disposed on the microstructures and configured to electrically insulate the microstructures from the ink during use. The conductive layer is configured to apply a voltage on the group of microstructures to facilitate the loading and dispensing of ink.