Electrowetting Dye Stability Against Photo-bleaching

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Electrowetting display devices experience image deterioration due to photo-bleaching of colored oils over time, particularly when exposed to radiation, leading to a decrease in the quality of the image displayed.

Innovation Solution

The use of anthraquinone and naphthoquinone dyes with specific structural features that reduce or eliminate photo-bleaching, combined with a carrier fluid that minimizes interactions with the dye, ensuring the dyes remain stable and maintain their color integrity over the operational lifetime of the display device.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If conventional dyes are used to color the oil in electrowetting display devices, then the display provides color to the radiation beam, but the dye undergoes photo-bleaching over time causing image deterioration

Engineering Contradiction:
Improvecolor intensityVSAvoidimage quality stability
Core Design Contradiction:
Illumination intensityVSReliability

Solution Approach 1:

The patent applies parameter changes by carefully selecting specific chemical structures of anthraquinone and naphthoquinone dyes that have inherent resistance to photo-bleaching. The molecular parameters (chemical structure, functional groups, substituents) are optimized to maintain color stability while preserving the desired optical properties for display operation.

Inventive Principle:
Principle #35Parameter changes

2Adaptability or versatility

If the oil is colored using a dye to provide color in the off state, then the display achieves color functionality, but the dye fades due to prolonged exposure to radiation

Engineering Contradiction:
Improvecolor display capabilityVSAvoiddye stability over time
Core Design Contradiction:
Adaptability or versatilityVSDuration of action of stationary object

Solution Approach 1:

The patent employs composite materials by combining the dye with a carrier fluid to form a stable colloidal suspension. This composite system ensures the dye remains dispersed and stable in the oil phase while maintaining resistance to photo-bleaching, thus preserving both color functionality and long-term durability.

Inventive Principle:
Principle #40Composite materials

3Productivity

If the display operates for extended periods with colored dyes, then continuous color display is achieved, but the dye degrades leading to weakened color impartation

Engineering Contradiction:
Improvecontinuous operation capabilityVSAvoiddye color intensity
Core Design Contradiction:
ProductivityVSLoss of substance

Solution Approach 1:

The patent uses a carrier fluid system that protects the dye molecules from degradation mechanisms. The carrier fluid acts as a stabilizing medium that prevents direct exposure of the dye to harmful factors (oxygen, light, heat), effectively extending the operational lifetime of the dye without requiring the dye itself to be inherently disposable or replaceable.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The selected dyes provide high-quality images with reduced or no deterioration over time, maintaining the desired color characteristics and preventing photo-bleaching, thus ensuring a prolonged period of high-quality image display.

Implementation Method 1

Anthraquinone dyes and naphthoquinone dyes may undergo photo-bleaching upon exposure to radiation with wavelengths of for example the ultra violet or visible spectrum

Methodology Applied
Scientific EffectPhoto-bleaching: Photodissociation

Implementation Method 2

a voltage is applied across the oil via an electrically conductive fluid immiscible with the oil, which exerts an electrostatic force on the conductive fluid

Methodology Applied
Scientific EffectElectrostatic force: Electrostatics

Data Source

PatentEP2346946B1Improvements in relation to electrowetting elements
Publication Date: 2021.05.12 AMAZON EURO HLDG TECH SCS
  • EP2346946B1 patent drawingFigure 1
  • EP2346946B1 patent drawing
  • EP2346946B1 patent drawing

AI summary

A dye for a fluid of an electrowetting element, the dye having a general formula selected from the group consisting of: (Formula I, II and III) wherein Q has the general formula: -HetlRl or -HetlRlR2; V has the general formula: -Het2R3 or -Het2R3R4; Hetl and Het2 are heteroatoms; Rl and R3 are H; R2 and R4 are any functional group; T and U are any functional group; W, X, Y and Z are H or an alkyl group; and F, G, L and M are H or an alkyl group, and with the proviso that the dye does not have the general formula: (IV). The present invention further relates to a fluid comprising a dye of the present invention, an electrowetting element and an optical display device comprising the fluid, and a use of the dye to reduce photo-bleaching.