Electrowinning Cell Spacer Plate Segmentation

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Solution Overview

Problem

Existing electrowinning processes face inefficiencies in preventing the circulation of anodic products back to the cathode, which reduces current efficiency and leads to unwanted reduction of copper ions at the cathode during copper electrowinning in ammoniacal solutions.

Innovation Solution

The introduction of a spacer plate design in the electrowinning cell that separates the anode and cathode compartments using flow restrictors, preventing the backflow of oxidized copper ions by directing the electrolyte flow to minimize their transport to the cathode, thereby maintaining separate hydrodynamic conditions for anodic and cathodic reactions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If the electrowinning cell uses a conventional design without flow restrictors, then the structure is simpler, but anodic products circulate back to the cathode reducing current efficiency

Engineering Contradiction:
Improvecurrent efficiencyVSAvoidcell structure complexity
Core Design Contradiction:
Loss of energyVSDevice complexity

Solution Approach 1:

The electrowinning cell is segmented into distinct anodic and cathodic compartments using spacer plates with flow restrictors. This segmentation prevents the circulation of anodic products to the cathode, thereby improving current efficiency while maintaining a manageable structural complexity through modular design.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Flow restrictors are introduced as intermediary elements within the spacer plates. These restrictors act as mediators that control and direct electrolyte flow between compartments, preventing harmful backflow while allowing necessary ionic transport, thus improving current efficiency without requiring complete compartment isolation.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Loss of energy

If flow restrictors are added to separate compartments, then current efficiency improves, but the spacer plate design becomes more complex

Engineering Contradiction:
Improveelectron usage efficiencyVSAvoidspacer plate design
Core Design Contradiction:
Loss of energyVSDevice complexity

Solution Approach 1:

The flow restrictors are merged into the spacer plate structure itself, combining the spacing function with the flow control function in a single integrated component. This reduces the need for separate flow control devices and simplifies the overall assembly process despite the enhanced functionality.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The spacer plate is designed to perform multiple functions simultaneously: maintaining electrode spacing, directing electrolyte flow, and preventing backflow of anodic products. This multi-functionality reduces the need for additional components and simplifies the overall cell design while improving current efficiency.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This design enhances current efficiency by ensuring that only the intended reactants reach the cathode for deposition, reducing unnecessary electron usage and improving the purity of copper obtained during the electrowinning process.

Implementation Method 1

A flow restrictor carried on the body extends across the electrolyte chamber and divides the electrolyte chamber into a cathode compartment and an anode compartment

Methodology Applied
Scientific EffectFluid flow restriction:

Implementation Method 2

passing the electrolyte with the ions of the metal through the new and improved electrowinning cell. This includes, but is not limited to, the winning of copper metal from the electrolyte comprising copper ions

Methodology Applied
Scientific EffectElectrodeposition: Electrodeposition

Data Source

PatentUS20230082450A1Electrowinning cells for the segregation of the cathodic and anodic compartments
Publication Date: 2023.03.16 UNIVERSITY OF KENTUCKY RESEARCH FOUNDATION
  • US20230082450A1 patent drawing
  • US20230082450A1 patent drawing
  • US20230082450A1 patent drawing

AI summary

An electrowinning cell includes a first anode associated with a first anode compartment, a cathode in a cathode compartment, a second anode associated with a second anode compartment, a first spacer plate between the first anode and the cathode and a second spacer plate between the cathode and the second anode compartment.