Embedded Silver Conductive Glass for Environmental Resistance

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Solution Overview

Problem

Existing electrically conductive glass articles face challenges with environmental degradation, high manufacturing costs, and aesthetic concerns due to the use of metallic conductors on exterior surfaces, and the processes for embedding conductors within glass substrates are expensive and can introduce defects, limiting design flexibility.

Innovation Solution

The development of electrically conductive glass articles with discrete layers of metallic silver embedded within a monolithic glass body, where each layer has a thickness of 0.1 μm to 0.5 μm and an electrical resistivity of 50 nΩ·m to 2000 nΩ·m, spaced apart from the surface by 0.1 μm to 20 μm, allowing for enhanced durability and design flexibility while maintaining aesthetic appeal.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If metallic conductors are placed on the exterior surface of glass articles, then manufacturing cost is reduced and electrical conductivity is achieved, but environmental degradation occurs and aesthetic appeal is compromised

Engineering Contradiction:
Improvemanufacturing costVSAvoidenvironmental resistance
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent embeds metallic conductor layers within the glass substrate itself, nesting the conductor inside the glass matrix rather than placing it on the exterior surface. This nested configuration protects the conductor from environmental exposure while maintaining electrical functionality, resolving the contradiction between low-cost exterior conductors and environmentally resistant embedded conductors.

Inventive Principle:
Principle #7Nested doll (Nesting)

Solution Approach 2:

The glass substrate acts as an intermediary medium that encapsulates the metallic conductor layers. This intermediary glass matrix provides environmental protection to the conductor while allowing electrical signals to pass through, thereby mediating between the need for low-cost conductors and the need for environmental resistance.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Ease of manufacture

If metallic conductors are placed on the exterior surface of glass articles, then manufacturing cost is reduced, but aesthetic appeal is compromised due to visible height discontinuities

Engineering Contradiction:
Improvemanufacturing costVSAvoidaesthetic appeal
Core Design Contradiction:
Ease of manufactureVSShape

Solution Approach 1:

By nesting the metallic conductor layers within the glass substrate during the glass forming process, the conductors become invisible from the exterior surfaces. This eliminates the visible height discontinuities that plague exterior conductors while maintaining the same low-cost metallic materials, thus preserving aesthetic appeal without sacrificing manufacturing economy.

Inventive Principle:
Principle #7Nested doll (Nesting)

3Reliability

If conductors are sandwiched between glass substrates, then environmental resistance is improved, but manufacturing cost increases and defects are introduced

Engineering Contradiction:
Improveenvironmental resistanceVSAvoidmanufacturing cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent merges the conductor formation step with the glass substrate formation step by incorporating metallic powders or organic conductive materials directly into the glass melt during melting or forming. This combined process eliminates the need for separate sandwiching and sealing operations, reducing manufacturing complexity and cost while maintaining the environmental protection benefits of embedded conductors.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The conductor layers are preliminarily incorporated into the glass substrate during the glass melting or forming process, before the final article is completed. This preliminary incorporation ensures the conductors are already protected within the glass matrix, eliminating the need for subsequent expensive sealing operations to achieve environmental resistance.

Inventive Principle:
Principle #10Preliminary action

4Reliability

If conductors are sandwiched between glass substrates, then environmental resistance is improved, but manufacturing complexity increases due to critical sealing steps

Engineering Contradiction:
Improveenvironmental resistanceVSAvoidprocess complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent combines the conductor embedding and glass forming operations into a single integrated process step. By incorporating metallic materials directly into the glass melt or forming the glass around the conductors during shaping, the patent eliminates the need for separate, critical sealing steps required by sandwich construction methods, thereby reducing process complexity while maintaining environmental protection.

Inventive Principle:
Principle #5Merging (Combining)

5Reliability

If conventional high temperature pressing and sintering are used to seal conductors, then conductor embedding is achieved, but design flexibility is limited to flat rectangular shapes

Engineering Contradiction:
Improveconductor embeddingVSAvoiddesign flexibility
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The conductors are preliminarily incorporated into the glass material before final shaping operations. By including metallic powders or conductive organic materials in the glass composition prior to forming, the conductors are automatically positioned within the glass matrix regardless of the final article shape, enabling complex three-dimensional geometries without requiring subsequent high-temperature sealing operations that would constrain design flexibility.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent changes the processing parameters from high-temperature pressing and sintering required for sealing to lower-temperature glass forming processes where conductors are incorporated into the melt. This parameter change allows the glass and conductor to be formed simultaneously in complex shapes using techniques like blow molding or drawing, greatly expanding design flexibility beyond flat rectangular forms.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This solution provides robust, cost-effective, and aesthetically pleasing electrically conductive glass articles with improved environmental resistance and flexibility in design, as the embedded metallic silver layers are protected from environmental exposure, maintaining consistent resistivity and preventing damage.

Implementation Method 1

an electrically conducting element formed in the body. The element includes a discrete layer, or a plurality of discrete layers, of metallic silver

Methodology Applied
Scientific EffectPhysical Vapour Deposition: Physical Vapour Deposition

Implementation Method 2

exchanging sodium ions in the glass body for silver ions; and forming the silver ions in the glass body into an electrically conducting element within the body

Methodology Applied
Scientific EffectIon Exchange: Ion Exchange

Data Source

PatentUS10116035B2Electrically conductive articles with discrete metallic silver layers and methods for making same
Publication Date: 2018.10.30 CORNING INC
  • US10116035B2 patent drawing
  • US10116035B2 patent drawing
  • US10116035B2 patent drawing

AI summary

An electrically conductive article that includes a monolithic glass body having a first primary surface; and an electrically conducting element formed in the body. The element includes a discrete layer, or a plurality of discrete layers, of metallic silver. Each layer has a thickness T such that 0.1 μm≤T≤0.5 μm and an electrical resistivity of about 50 nΩ·m to about 2000 nΩ·m. In addition, the element is spaced apart from the first primary surface by a distance D, wherein 0.1 μm≤D≤20 μm. In some aspects, the electrically conducting element and/or the monolithic glass body are configured as an antenna assembly, an optical fiber or a flexible glass substrate.