Electrochemically Modulated Molten Salt Reactor Corrosion Control

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Solution Overview

Problem

Molten salt reactors face challenges due to the instability of molten fuel salt, which leads to corrosion and unsafe operating conditions, exacerbated by fission products and complex chemistry, necessitating improved reactor performance and structural material longevity.

Innovation Solution

An electrochemically modulated molten salt reactor (EMMSR) with a vessel containing fuel salt, a neutron moderator, and an insulator, where electrical signals from a power source modulate the electrochemical reactions, controlling ion movement and reducing corrosion by applying positive and negative potentials, thus stabilizing the reactor components.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Power

If traditional molten salt reactor operation is used, then nuclear power generation is achieved, but corrosion of structural materials occurs due to fuel salt instability and fission products

Engineering Contradiction:
Improvenuclear power generationVSAvoidstructural material longevity
Core Design Contradiction:
PowerVSReliability

Solution Approach 1:

The patent applies electrochemical potential modulation to change the chemical state of the fuel salt. By controlling the oxidation-reduction potential through electrochemical reactions, the stability of the fuel salt composition is improved, thereby reducing corrosion of structural materials while maintaining nuclear power generation.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The system uses electrochemical sensors to monitor the oxidation-reduction potential of the fuel salt in real-time and feeds this information back to the power source. The power source then adjusts the electrochemical potential accordingly to maintain optimal fuel salt stability and minimize corrosion effects on structural materials.

Inventive Principle:
Principle #23Feedback

2Power

If molten fuel salt operates at high temperature, then efficient nuclear power generation is achieved, but fuel salt instability increases causing corrosion and unsafe conditions

Engineering Contradiction:
Improvenuclear power generation efficiencyVSAvoidfuel salt stability
Core Design Contradiction:
PowerVSStability of the object's composition

Solution Approach 1:

The patent changes the chemical parameter of the fuel salt by controlling its oxidation-reduction potential through electrochemical reactions. This allows the fuel salt to maintain stability at high operating temperatures, preventing decomposition and corrosion while preserving efficient nuclear power generation.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces traditional mechanical or thermal control methods with electrochemical control. By using electrochemical reactions to regulate fuel salt composition and stability, the system achieves better control at high temperatures without relying solely on thermal management.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Reliability

If electrochemical modulation is applied to stabilize fuel salt, then corrosion is reduced and material lifespan is extended, but additional equipment and system complexity are introduced

Engineering Contradiction:
Improvestructural material longevityVSAvoidreactor system complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent integrates the electrochemical modulation system into the existing reactor structure, where the power source and electrodes serve multiple functions: controlling fuel salt stability, preventing corrosion, and potentially enabling on-line fuel processing. This multi-functionality reduces the need for separate dedicated systems.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The electrochemical modulation system uses the fuel salt itself as the electrolyte and the structural materials as electrodes, allowing the system to self-regulate fuel salt composition without requiring external chemical additives or complex processing equipment. The fuel salt essentially serves its own stabilization needs.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The EMMSR effectively mitigates corrosion, enhances neutron moderation, and extends the lifespan of structural materials by reducing oxidative attacks and neutron absorption, providing a safer and more efficient nuclear power generation.

Implementation Method 1

electrical signals from a power source modulate the electrochemical reactions, controlling ion movement

Methodology Applied
Scientific EffectElectrochemical reactions: Electrolysis

Implementation Method 2

The neutron moderator is configured to slow down fast neutrons produced by the dissolved fissile isotopes

Methodology Applied
Scientific EffectNeutron scattering: Scattering

Implementation Method 3

The fuel salt includes enough dissolved fissile isotopes to cause continued self-sustaining fission reactions

Methodology Applied
Scientific EffectNuclear fission: Nuclear Fission

Data Source

PatentUS11069449B2Electrochemically modulated molten salt reactor
Publication Date: 2021.07.20 THE UNITED STATES AS REPRESENTED BY THE DEPARTMENT OF ENERGY
  • US11069449B2 patent drawing
  • US11069449B2 patent drawing
  • US11069449B2 patent drawing

AI summary

An electrochemically modulated molten salt reactor (EMMSR) that contains a vessel and a power source. The vessel houses a fuel salt, at least a portion of a neutron moderator, and at least a portion of an insulator. The fuel salt includes enough dissolved fissile isotopes to cause continued self-sustaining fission reactions during the operation of the EMMSR. The neutron moderator is configured to slow down fast neutrons produced by the dissolved fissile isotopes. The insulator is configured to electrically isolate the neutron moderator from the vessel. The power source has a positive potential and a negative potential. The positive potential is received by the neutron moderator and the negative potential is received by the vessel.