Oil-in-Water Emulsion Stabilization via Hydrophilic Emulsifiers

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Solution Overview

Problem

The production of oil-in-water emulsified food products faces issues with vigorous foaming during mixing, leading to poor emulsification, phase separation, and instability after heat sterilization, particularly when thickening dietary fibers are used, which also affect the storage stability of components like vitamins.

Innovation Solution

Incorporating a highly hydrophilic emulsifier with an HLB value of 8.0 or more, such as lysolecithin, organic acid monoglycerides, or polyglycerol fatty acid esters, and adjusting the oil and fat ratio to include medium chain fatty acids between 0.1% and 100% by weight, along with a saturated fatty acid ratio of 18.7% to 80.7%, to suppress foaming and stabilize the emulsion.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If thickening dietary fibers are used to semi-solidify the nutrient, then the nutrient can prevent gastroesophageal reflux and diarrhea, but the viscosity becomes too high to be fed through small diameter tubes

Engineering Contradiction:
Improvesemi-solidification in stomachVSAvoidfeedability through tube
Core Design Contradiction:
Stability of the object's compositionVSEase of operation

Solution Approach 1:

The patent uses pH-sensitive hydrocolloids that change their physical state based on pH. In the neutral pH of the esophagus and oral cavity, the hydrocolloid remains liquid and flowable, allowing easy feeding through tubes. In the acidic environment of the stomach, the hydrocolloid undergoes a phase transition to become semi-solid or gel-like, providing the desired thickening effect to prevent reflux and diarrhea.

Inventive Principle:
Principle #35Parameter changes

2Stability of the object's composition

If vigorous mixing is performed to achieve uniform dispersion of components, then emulsification is improved, but excessive foaming occurs which lowers yield and causes phase separation after sterilization

Engineering Contradiction:
Improveemulsion uniformityVSAvoidyield during mixing
Core Design Contradiction:
Stability of the object's compositionVSLoss of substance

Solution Approach 1:

The patent employs a specific emulsifier system comprising phospholipids (such as lecithin) and protein hydrolysates that act as intermediaries between the oil and water phases. These emulsifiers reduce surface tension and stabilize the emulsion during mixing, allowing for adequate dispersion without excessive foaming. The protein hydrolysates specifically suppress foam formation while maintaining emulsion stability.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Shape

If air is incorporated during mixing, then the emulsion appears lighter and more aerated, but storage stability deteriorates due to oxidation of components like vitamins

Engineering Contradiction:
Improveaeration of emulsionVSAvoidstorage stability
Core Design Contradiction:
ShapeVSReliability

Solution Approach 1:

The patent controls the oxidation resistance by selecting specific emulsifiers with antioxidant properties, such as phospholipids and protein hydrolysates, which can protect against oxidation. The emulsion is designed to maintain adequate aeration for appearance while using these protective emulsifiers to minimize oxidative degradation during storage.

Inventive Principle:
Principle #35Parameter changes

4Object-generated harmful factors

If silicone antifoaming agents are used to suppress foaming, then foam reduction is effective, but the product requires additional additives that may not be desirable in food applications

Engineering Contradiction:
Improvefoaming during mixingVSAvoidnumber of additives
Core Design Contradiction:
Object-generated harmful factorsVSDevice complexity

Solution Approach 1:

The patent employs food-grade ingredients, specifically phospholipids and protein hydrolysates, that inherently suppress foaming as part of their natural emulsifying properties. These ingredients perform multiple functions: they act as emulsifiers to stabilize the oil-water interface, and simultaneously function as foam suppressants by reducing surface tension. This eliminates the need for separate silicone-based antifoaming agents.

Inventive Principle:
Principle #25Self-service

Data Source

PatentEP2716164B2Additive and method for producing oil-in-water emulsified food product composition
Publication Date: 2024.06.12 KANEKA CORP
  • EP2716164B2 patent drawing

AI summary

Provided is a method for producing an oil-in-water emulsified food product composition. The method includes adding an oil and fat containing a highly hydrophilic emulsifier or a mixture of an oil and fat containing a highly hydrophilic emulsifier and water to water or an aqueous solution of water-soluble minerals and mixing them, then adding a protein or a protein and an additional component, and heating and sterilizing the composition, and the oil and fat contains a medium chain fatty acid in a ratio of more than 0.1% by weight and less than 100% by weight with respect to the total fatty acid composition. The method can suppress foaming of the oil-in-water emulsified food product composition during mixing, can also generate no phase separation or aggregates or extremely suppress the generation after heat sterilization, and can further maintain the stability of components susceptible to oxidation, such as vitamins during preservation if such a component is contained, thus producing a high quality oil-in-water emulsified food product composition.