Encapsulated Acid Agents for Deep Wellbore Stimulation

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Solution Overview

Problem

Current methods for acidizing and descaling in hydrocarbon-bearing formations face issues with non-uniformity and rapid consumption of strong acids, leading to shallow and uneven wormhole formation, which hampers efficient hydrocarbon extraction.

Innovation Solution

The use of encapsulated treatment agents activated by acoustic or electromagnetic fields at specific depths within the wellbore, allowing for targeted release of descaling or acid stimulation agents, thereby enhancing the formation of deep and uniform fluid pathways.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Speed

If strong acid is used for filter cake removal and formation acidizing, then the acid reacts quickly with the formation to create wormholes, but the reaction is instantaneous and non-uniform, depleting the acid immediately and creating shallow, non-uniform wormholes that do not penetrate deep into the formation

Engineering Contradiction:
Improveacid reaction speedVSAvoidwormhole uniformity and depth
Core Design Contradiction:
SpeedVSManufacturing precision

Solution Approach 1:

The acid treatment is segmented into multiple stages using microcapsules of different sizes and acid concentrations. The microcapsules are injected in sequence, with smaller capsules penetrating deeper into the formation first, followed by larger capsules that create wider pathways near the wellbore. This segmentation allows for controlled, uniform wormhole development at different depths rather than instantaneous bulk reaction.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The microcapsules are pre-positioned and injected into the formation before the acid reaction begins. The capsules travel through the formation and release acid at predetermined locations, ensuring that the acid is delivered to the desired depth before reacting. This preliminary positioning prevents the acid from reacting immediately upon contact with the formation face, allowing for deep penetration and uniform wormhole creation.

Inventive Principle:
Principle #10Preliminary action

2Duration of action of moving object

If ester of acid is used to extend stability time before hydrolysis, then the acid reaction time is extended, but the amount of time the ester is stable may not be sufficient to deliver the ester to the desired treatment site in extended horizontal well bores

Engineering Contradiction:
Improveester stability durationVSAvoidwellbore length
Core Design Contradiction:
Duration of action of moving objectVSLength of stationary object

Solution Approach 1:

The treatment is divided into multiple microcapsule injections rather than relying on a single ester formulation to travel the entire wellbore length. Each microcapsule batch travels a manageable distance before acidification, and subsequent batches follow to extend and uniform the wormholes. This segmentation allows the treatment to effectively cover extended horizontal wellbores of 30 kilometers or more.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The microcapsule shell acts as an intermediary carrier that protects the acid until the desired location is reached. The shell material and thickness are engineered to provide sufficient stability for the capsule to traverse the wellbore length, then degrade at the target zone to release the acid. This intermediary approach allows precise delivery of acid to deep treatment zones without premature reaction.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Length of stationary object

If encapsulated treatment agents are used to extend stability and enable targeted delivery, then the acid can be delivered to the desired depth, but the system complexity increases with encapsulation materials and activation mechanisms

Engineering Contradiction:
Improvetreatment depthVSAvoidencapsulation and activation system complexity
Core Design Contradiction:
Length of stationary objectVSDevice complexity

Solution Approach 1:

The microcapsules are designed to self-activate through environmental triggers encountered during downhole travel, such as temperature changes, pressure variations, or contact with formation fluids. This self-service activation eliminates the need for complex external activation systems, reducing overall system complexity while still enabling targeted deep delivery of the acid treatment.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The encapsulation material properties are carefully selected and tuned to change state at specific downhole conditions (temperature, pressure, pH). By changing physical or chemical parameters of the capsule shell, the system achieves controlled acid release at the target depth without requiring complex mechanical activation mechanisms, thus balancing delivery capability with system simplicity.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables precise and efficient removal of scale deposits and acid stimulation, increasing hydrocarbon flow rates and reducing the need for excessive treatment agents and well intervention, while minimizing damage to the well structure.

Implementation Method 1

activating an acoustic or an electromagnetic source at the desired depth within the formation, and generating an acoustic field or an electromagnetic field

Methodology Applied
Scientific EffectAcoustic field generation: Acoustics

Implementation Method 2

activating an acoustic or an electromagnetic source at the desired depth within the formation, and generating an acoustic field or an electromagnetic field

Methodology Applied
Scientific EffectElectromagnetic field generation: Electromagnetic Induction

Implementation Method 3

a treatment agent has been encapsulated in a material susceptible to acoustic activation. At a predetermined time, an acoustic emission source is activated, degrading the encapsulant, and releasing the treatment agent

Methodology Applied
Scientific EffectAcoustic activation: Acoustic Cavitation

Implementation Method 4

The acids react with the portions of the filter cake and the hydrocarbon-bearing formation susceptible to acid degradation upon contact

Methodology Applied
Scientific EffectAcid degradation: Chemical Bonding

Implementation Method 5

Esters of acids can hydrolyze in the presence of water into organic acids to form acidic solutions. As an acidic solution forms, the resulting acid is consumed, which drives the reversible hydrolysis reaction to completion

Methodology Applied
Scientific EffectHydrolysis: Hydrolysis

Data Source

PatentUS11486242B2Methods for targeted chemical treatment of well bores
Publication Date: 2022.11.01 SAUDI ARABIAN OIL CO
  • US11486242B2 patent drawing

AI summary

A method for wellbore treatment. The method including preparing an encapsulated treatment agent via polymerization, feeding the encapsulated treatment agent into the wellbore, delivering the encapsulated treatment agent to a desired depth within a formation in the wellbore, activating an acoustic or an electromagnetic source at the desired depth within the formation, and generating an acoustic field or an electromagnetic field. The acoustic field or electromagnetic field activates the encapsulant thereby releasing the treatment agent into the wellbore and a desired depth.