Encapsulated Sorbent Capsules for CO2 Separation

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Solution Overview

Problem

Current methods for removing carbon dioxide from gas mixtures, such as those in fossil fuel plants, are inefficient and costly, relying heavily on water-based systems that require significant energy and result in solvent degradation and corrosion, limiting the effectiveness and longevity of carbon capture processes.

Innovation Solution

The use of encapsulated sorbents within polymer-coated capsules that are permeable to carbon dioxide, allowing for efficient separation and regeneration, reducing energy requirements and solvent degradation by isolating the sorbents within a polymer shell, which can withstand higher temperatures and corrosive environments.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If water-based systems are used for CO2 removal, then CO2 separation is achieved, but energy consumption increases and solvent degradation occurs

Engineering Contradiction:
Improveenergy consumptionVSAvoidsolvent degradation
Core Design Contradiction:
Loss of energyVSReliability

Solution Approach 1:

The system divides the CO2 removal process into two distinct functional components: encapsulated sorbent particles for CO2 absorption and water for solvent regeneration. The sorbent is segmented into discrete capsules that can be easily separated from the aqueous phase, allowing the water to be recycled without degradation while the sorbent handles the energy-intensive absorption function.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The encapsulated sorbent acts as an intermediary between the gas phase CO2 and the aqueous regeneration system. The sorbent material (such as amines or metal-organic frameworks) provides the chemical absorption function, while the encapsulation allows easy separation from water, preventing solvent degradation and enabling water recycling without energy-intensive processing.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Quantity of substance

If conventional sorbents are used, then CO2 absorption capacity is achieved, but corrosion and solvent loss increase

Engineering Contradiction:
ImproveCO2 absorption capacityVSAvoidsolvent loss
Core Design Contradiction:
Quantity of substanceVSLoss of substance

Solution Approach 1:

The sorbent is enclosed in encapsulated particles with thin shell structures that provide mechanical protection and contain the sorbent material. This encapsulation prevents solvent loss through evaporation or degradation, while maintaining high CO2 absorption capacity through the sorbent material's chemical properties. The shells are designed to be permeable to CO2 while retaining the sorbent molecules.

Inventive Principle:
Principle #30Flexible shells and thin films

Solution Approach 2:

The system uses composite encapsulated particles combining sorbent materials (such as amines, ionic liquids, or metal-organic frameworks) with protective shell materials. This composite structure maintains high CO2 absorption capacity from the sorbent while the shell prevents corrosion and solvent loss, allowing the system to operate in corrosive environments without significant solvent degradation.

Inventive Principle:
Principle #40Composite materials

3Productivity

If high CO2 loadings are handled, then capture efficiency improves, but process complexity increases

Engineering Contradiction:
Improvecapture efficiencyVSAvoidprocess complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The system extracts the sorbent function into separate encapsulated particles that can be easily separated from the aqueous phase through simple decantation or filtration. This extraction allows the system to handle high CO2 loadings by concentrating the absorption function in the sorbent particles, while the regeneration process remains simple since the water phase can be directly evaporated or heated without complex separation equipment.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The system utilizes changes in physical parameters (such as temperature and phase) to simplify the regeneration process. The encapsulated sorbent particles can be regenerated by heating or by changing the aqueous phase conditions, allowing high CO2 loadings to be handled efficiently while maintaining relatively simple process equipment. The phase change of water during evaporation provides a natural separation mechanism.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances the efficiency and longevity of carbon capture processes by reducing energy consumption, minimizing solvent loss, and enabling novel process designs that can handle higher CO2 loadings and corrosive conditions, while maintaining effective CO2 separation and regeneration.

Implementation Method 1

the polymer coating is permeable to carbon dioxide

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 2

carbon dioxide migrates through the polymer coating and is taken up by the stripping materials

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS11117091B2Separation of a target substance from a fluid or mixture using encapsulated sorbents
Publication Date: 2021.09.14 LAWRENCE LIVERMORE NAT SECURITY LLC
  • US11117091B2 patent drawing
  • US11117091B2 patent drawing
  • US11117091B2 patent drawing

AI summary

Method and apparatus for separating a target substance from a fluid or mixture. Capsules having a coating and stripping solvents encapsulated in the capsules are provided. The coating is permeable to the target substance. The capsules having a coating and stripping solvents encapsulated in the capsules are exposed to the fluid or mixture. The target substance migrates through the coating and is taken up by the stripping solvents. The target substance is separated from the fluid or mixture by driving off the target substance from the capsules.