Engine Reactor Partition Wall Thermal Resistance

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Solution Overview

Problem

Current engine systems fail to efficiently generate sufficient hydrogen gas through dehydrogenation reactions due to heat shortages, leading to increased hydrocarbon CO2 emissions and reactor volume expansion, as well as catalyst deactivation at low temperatures.

Innovation Solution

The engine system incorporates a reactor unit with a catalyst and a hydrogen medium, featuring a partition wall with varying thermal resistance along the exhaust gas passage, allowing for efficient heat recovery and hydrogen production, with a parallel current flow direction and specific materials for heat transfer optimization.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If the temperature of exhaust gas supplied to the reactor is raised to improve heat recovery efficiency, then the amount of hydrogen generated increases, but the thermal resistance of the partition wall must be increased to protect the catalyst from low temperature deactivation, which deteriorates heat transfer characteristic and increases reactor volume

Engineering Contradiction:
Improvehydrogen generation amountVSAvoidreactor volume
Core Design Contradiction:
ProductivityVSVolume of stationary object

Solution Approach 1:

The partition wall is designed with different thermal resistance values at different locations: the upstream side (inlet side) has higher thermal resistance to protect the catalyst from low-temperature deactivation, while the downstream side has lower thermal resistance to improve heat transfer efficiency and reduce reactor volume. This local differentiation resolves the contradiction between catalyst protection and heat transfer efficiency.

Inventive Principle:
Principle #3Local quality

2Reliability

If the thermal resistance of the partition wall is increased to protect the catalyst, then the catalyst deactivation is prevented, but the heat transfer characteristic deteriorates and reactor volume increases

Engineering Contradiction:
Improvecatalyst activityVSAvoidreactor volume
Core Design Contradiction:
ReliabilityVSVolume of stationary object

Solution Approach 1:

The partition wall implements spatially varying thermal resistance properties: high thermal resistance at the upstream side protects the catalyst from thermal shock and low-temperature deactivation, while low thermal resistance at the downstream side maintains efficient heat transfer, thereby preventing catalyst deactivation without increasing overall reactor volume.

Inventive Principle:
Principle #3Local quality

3Productivity

If heat of engine exhaust gas is used for dehydrogenation reaction, then hydrogen is generated from hydrogenation fuel, but the heat shortage increases the amount of additional hydrocarbon required, leading to increased CO2 emissions

Engineering Contradiction:
Improvehydrogen generation efficiencyVSAvoidCO2 emissions
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The system optimizes the thermal resistance parameters of the partition wall to maximize heat transfer efficiency from exhaust gas to the hydrogenation fuel. By carefully controlling the thermal resistance distribution, the system extracts maximum heat from the exhaust gas, reducing the need for additional hydrocarbon supplementation and thereby reducing CO2 emissions while maintaining high hydrogen generation efficiency.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration enhances hydrogen gas production, reduces reactor volume, and prevents catalyst deactivation, improving heat transfer efficiency and hydrogen productivity while minimizing CO2 emissions.

Implementation Method 1

each of said reactors comprises a partition wall disposed between an exhaust gas passage and a hydrogen medium passage; wherein the thermal resistance of said partition wall of said first reactor positioned on the upstream side is larger than that of said second reactor positioned on the downstream side

Methodology Applied
Scientific EffectHeat transfer: Conduction (thermal)

Implementation Method 2

a reactor unit bearing a catalyst; wherein the hydrogen generated using the heat of the exhaust gas in said reactor unit

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 3

hydrogen medium capable of repeating chemically storing and discharging hydrogen; the hydrogen generated using the heat of the exhaust gas in said reactor unit

Methodology Applied
Scientific EffectDehydrogenation reaction: Decomposition (biological)

Data Source

PatentUS8033255B2Engine system
Publication Date: 2011.10.11 HITACHI LTD
  • US8033255B2 patent drawing
  • US8033255B2 patent drawing
  • US8033255B2 patent drawing

AI summary

An engine system comprising an engine, hydrogen medium capable of repeating chemically storing and discharging hydrogen, an exhaust gas pipe from said engine; and a reactor unit bearing a catalyst;wherein the hydrogen generated using the heat of the exhaust gas in said reactor unit or the mixture of the hydrogen and said hydrogen medium being supplied to said engine;wherein said reactor unit includes at least first reactor and second reactor in said exhaust gas pipe and each of said reactors comprises a partition wall disposed between an exhaust gas passage and a hydrogen medium passage; andwherein the thermal resistance of said partition wall of said first reactor positioned on the upstream side is larger than that of said second reactor positioned on the downstream side, and said hydrogen medium is supplied from said first reactor to said second reactor.