Engineered Coal Char Adsorbent for Phosphate Removal

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Solution Overview

Problem

Environmental phosphorus pollution from agricultural runoff and industrial effluents leads to eutrophication and soil fertility depletion, necessitating effective adsorbents for phosphate removal and soil rejuvenation.

Innovation Solution

Engineered coal-based lignite adsorbents with increased surface area and impregnated Ca2+ and Mg2+ ions are used to treat wastewater and rebuild soil fertility by adsorbing phosphates and other nutrients, offering a low-cost, environmentally friendly solution.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If pyrolyzed lignite coal is used as an adsorbent, then phosphate uptake capacity is improved, but manufacturing complexity increases

Engineering Contradiction:
Improvephosphate uptake capacityVSAvoidmanufacturing complexity
Core Design Contradiction:
Quantity of substanceVSDevice complexity

Solution Approach 1:

The patent applies parameter changes by controlling pyrolysis temperature (500-900°C) and duration to transform lignite coal into activated carbon with enhanced porous structure and surface area, thereby improving phosphate adsorption capacity while managing manufacturing complexity through optimized process parameters

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates composite materials by impregnating pyrolyzed lignite coal with metal ions (Ca2+, Mg2+, Fe3+) to form composite adsorbents that combine the porous structure of activated carbon with the phosphate-binding capabilities of metal ions, enhancing uptake capacity while adding controlled complexity to the manufacturing process

Inventive Principle:
Principle #40Composite materials

2Area of stationary object

If surface area is increased through pyrolysis, then adsorption capacity is improved, but production cost increases

Engineering Contradiction:
Improvesurface areaVSAvoidproduction cost
Core Design Contradiction:
Area of stationary objectVSEase of manufacture

Solution Approach 1:

The patent utilizes parameter changes by optimizing pyrolysis conditions (temperature, time, atmosphere) to achieve maximum surface area development at economically viable processing costs, transforming low-cost lignite coal into high-surface-area activated carbon

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs inexpensive lignite coal as the starting material, which is abundant and low-cost, and transforms it through relatively simple pyrolysis into a disposable or regenerable adsorbent product that provides high surface area at low production cost

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Reliability

If metal ions are impregnated to enhance phosphate binding, then adsorption selectivity is improved, but ease of operation decreases

Engineering Contradiction:
Improveadsorption selectivityVSAvoidease of operation
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The patent applies preliminary action by pre-impregnating the pyrolyzed lignite coal with metal ions (Ca2+, Mg2+, Fe3+) before deployment, so that the adsorbent is pre-equipped with enhanced phosphate-binding sites, improving selectivity while simplifying operation during actual use

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The engineered coal-based lignite adsorbents demonstrate enhanced phosphate uptake capacity, effectively treating contaminated water and slowly releasing nutrients to improve soil fertility, addressing both water remediation and soil rejuvenation needs.

Implementation Method 1

The presently-disclosed subject matter provides adsorbents and methods for removing phosphates from water

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

the impregnated pyrolyzed lignite coal further comprises impregnated Ca2+ and Mg2+

Methodology Applied
Scientific EffectIon Exchange: Ion Exchange

Data Source

PatentUS11819820B2Engineered coal char
Publication Date: 2023.11.21 MISSISSIPPI STATE UNIVERSITY
  • US11819820B2 patent drawing
  • US11819820B2 patent drawing
  • US11819820B2 patent drawing

AI summary

Provided herein are an adsorbent and method of treating water using the adsorbent. The adsorbent includes thermally- and chemically-treated lignite coal. The method includes contacting wastewater with the treated lignite coal.