Engineered E. coli for Isopropyl Alcohol Production

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Existing isopropyl alcohol-producing bacteria have low productivity and generate significant amounts of butanol and ethanol as by-products, making it difficult to collect isopropyl alcohol due to the complexity of separation processes.

Innovation Solution

An isopropyl alcohol-producing bacterium, Escherichia coli, is engineered with acetoacetate decarboxylase, isopropyl alcohol dehydrogenase, CoA transferase, and thiolase activities, introduced through gene introduction or promoter enhancement, which allows for the production of isopropyl alcohol with minimal by-product formation, enabling simpler purification.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If existing isopropyl alcohol-producing bacteria are used, then isopropyl alcohol can be produced from plant-derived materials, but the productivity is low and significant amounts of butanol and ethanol by-products are generated

Engineering Contradiction:
Improveisopropyl alcohol productivityVSAvoidby-product alcohols (butanol and ethanol)
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The invention extracts and removes the harmful by-product formation pathways by deleting specific genes (adhE, adhF, bdh, ilvA, ilvE, ilvD, ilvC, ilvB, ilvG, ilvH, ilvO, ilvN, ilvM, ilvL, ilvK, ilvJ, ilvI, ilvF, ilvE, ilvD, ilvC, ilvB, ilvA, ilvO, ilvN, ilvM, ilvL, ilvK, ilvJ, ilvI, ilvF) responsible for producing butanol and ethanol, while retaining and enhancing the desired isopropyl alcohol production pathway through strategic gene overexpression

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention changes the metabolic parameters of the bacterium by overexpressing specific genes (atoB, atoC, atoD, atoA, adhI) to optimize the flux toward isopropyl alcohol production, thereby increasing productivity and altering the product distribution in favor of the desired compound

Inventive Principle:
Principle #35Parameter changes

2Productivity

If existing bacteria produce butanol and ethanol as by-products, then isopropyl alcohol can be produced, but the separation and purification process becomes complicated requiring multiple distillation steps

Engineering Contradiction:
Improveisopropyl alcohol productionVSAvoidseparation and purification process
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The invention extracts and eliminates the source of the separation problem by deleting the genes responsible for by-product formation, thereby removing the need for complex separation equipment and simplifying the purification process to a single distillation step

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention achieves homogeneity in the culture medium by suppressing the formation of different alcohol by-products, resulting in a more uniform composition that requires simpler separation processes

Inventive Principle:
Principle #33Homogeneity

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The engineered bacterium produces isopropyl alcohol with high purity and reduced by-products, facilitating easier and more efficient collection without the need for complex separation steps, thereby simplifying the industrial production process.

Implementation Method 1

bacteria that utilize plant-derived materials to produce isopropyl alcohol

Methodology Applied
Scientific EffectFermentation: Fermentation

Implementation Method 2

acetoacetate decarboxylase activity, an isopropyl alcohol dehydrogenase activity, a CoA transferase activity and a thiolase activity

Methodology Applied
Scientific EffectEnzyme catalysis: Enzyme

Data Source

PatentEP2184354B1Isopropyl alcohol-producing bacterium and method of producing isopropyl alcohol using the same
Publication Date: 2018.08.22 MITSUI CHEMICALS INC
  • EP2184354B1 patent drawingFigure 1

AI summary

The invention provides: an isopropyl alcohol-producing bacterium which has an acetoacetate decarboxylase activity, an isopropyl alcohol dehydrogenase activity, a CoA transferase activity and a thiolase activity having been imparted thereto and is capable of producing isopropyl alcohol from a plant-derived material; a method of producing isopropyl alcohol whereby isopropyl alcohol is produced from a plant-derived material by using this isopropyl alcohol-producing bacterium; and an apparatus therefor.