Engineered Glass Feedstocks for Transparent Gradient Additive Manufacturing

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Solution Overview

Problem

Conventional glass processing methods struggle to achieve custom-tailored composition profiles, particularly in additive manufacturing (AM), due to challenges in controlling the spatial distribution of glass compositions, thermal stresses, and porosity, limiting the production of transparent and optically quality glass components with complex gradients.

Innovation Solution

Direct ink writing (DIW) additive manufacturing is used to introduce composition gradients via continuous in-line mixing of glass-forming species, with dopants incorporated during the formation of a low-density form (LDF), which is then heat-treated to achieve transparent glass structures with controlled compositional changes.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional melt production methods are used to produce glass, then glass components can be manufactured with relatively simple processes, but custom-tailored composition profiles and spatial distribution of compositions cannot be achieved

Engineering Contradiction:
Improvespatial distribution of compositionVSAvoidprocess complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The glass component is manufactured layer by layer through additive manufacturing, where each layer can have a different composition. This segmentation allows precise control over the spatial distribution of compositions, enabling custom-tailored composition profiles that cannot be achieved with conventional melt production methods.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different regions of the glass component are assigned different compositions based on local requirements. The additive manufacturing process enables each location to receive the specific composition needed, achieving local quality optimization throughout the component.

Inventive Principle:
Principle #3Local quality

2Reliability

If selective laser melting or G3DP methods are used to manufacture glass via additive manufacturing, then single composition glass can be formed, but thermally induced stresses and trapped porosity prevent optical quality

Engineering Contradiction:
Improveoptical qualityVSAvoidmanufacturing processability
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The composition of the glass-forming material is specifically designed with parameters optimized for additive manufacturing. This includes controlling particle size, shape, and composition to enable dense packing and minimize porosity. The material parameters are tuned to reduce thermal stresses during manufacturing while maintaining optical quality.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The glass-forming material is formulated as a composite with specific particle characteristics. By controlling the composite structure at the material level, the process achieves both manufacturability and optical quality, overcoming the limitations of previous single-material approaches.

Inventive Principle:
Principle #40Composite materials

3Length of stationary object

If diffusion-based methods are used to create composition gradients in glass, then symmetric parabolic profiles can be achieved, but maximum achievable diameters are limited to approximately 20 mm

Engineering Contradiction:
Improveglass component diameterVSAvoidcomposition profile control
Core Design Contradiction:
Length of stationary objectVSManufacturing precision

Solution Approach 1:

The composition gradient is built into the glass component during the additive manufacturing process itself, rather than being created afterward through diffusion. This preliminary action allows large-scale components to achieve precise composition profiles without relying on limited diffusion processes.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The thermal diffusion process is replaced with a direct material deposition approach. Instead of using heat-driven diffusion to create gradients, the additive manufacturing process directly places materials with the desired composition distribution, eliminating the size limitations of diffusion-based methods.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

4Manufacturing precision

If multiple feedstocks with multiple compositions are processed together via additive manufacturing, then custom composition profiles can be introduced, but feedstock characteristics critically affect processability, yield, transparency, and homogeneity

Engineering Contradiction:
Improvecustom composition profilesVSAvoidfeedstock engineering complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The feedstocks are engineered with specifically controlled parameters including particle size, shape, and composition. These parameter changes optimize the feedstocks for additive manufacturing, enabling multiple compositions to be processed together while maintaining processability, yield, transparency, and homogeneity.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

Multiple feedstocks are formulated as engineered composites with tailored characteristics. Each feedstock is designed as a composite material with specific properties that enable them to work together in the additive manufacturing process, achieving custom composition profiles while maintaining overall processability and quality.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables the production of optical and non-optical glass components with custom composition profiles, overcoming limitations of conventional methods by achieving larger, thermally stable, and optically superior glass structures with precise control over material properties.

Implementation Method 1

heat treating the formed structure for converting the glass-forming material to glass

Methodology Applied
Scientific EffectVitrification: Vitrification

Implementation Method 2

continuous in-line mixing of glass-forming species

Methodology Applied
Scientific EffectDiffusion: Diffusion

Data Source

PatentUS12351718B2Engineered feedstocks for additive manufacture of glass
Publication Date: 2025.07.08 LAWRENCE LIVERMORE NAT SECURITY LLC
  • US12351718B2 patent drawing
  • US12351718B2 patent drawing
  • US12351718B2 patent drawing

AI summary

According to one embodiment, a method includes forming a structure by printing an ink, the ink including a glass-forming material, and heat treating the formed structure for converting the glass-forming material to glass. According to another embodiment, an ink composition includes a glass-forming material and a solvent.