ENZ Material Layer on Patterned Substrate for Tunable Emissivity

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Solution Overview

Problem

Existing technologies face challenges in controlling and manipulating the emissivity of real-world objects to achieve targeted thermal emission spectra, as they typically exhibit broadband emission characteristics similar to ideal blackbodies, rather than allowing for narrow, temperature-stable bands of emitted frequencies.

Innovation Solution

The development of a device with a substrate featuring a pattern of surface features and an Epsilon-Near-Zero (ENZ) material layer, which supports ENZ absorption modes, allowing for tunable emissivity/absorptivity characteristics by focusing electromagnetic radiation within the material's volume, independent of polarization and angle, thereby enabling controlled thermal emission.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Length of moving object

If conventional materials or structures are used, then broadband emission similar to ideal blackbodies is achieved, but narrow, temperature-stable bands of emitted frequencies cannot be obtained

Engineering Contradiction:
Improveemission band widthVSAvoidtemperature stability
Core Design Contradiction:
Length of moving objectVSReliability

Solution Approach 1:

The patent applies local quality by using a patterned substrate with specific geometric features (e.g., holes, pillars, or grooves) that create localized electromagnetic resonances. These local structural modifications enable narrowband emission at specific frequencies while maintaining temperature stability, contrasting with the uniform broadband emission of conventional blackbodies.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent employs composite structures combining the patterned substrate with ENZ material layers. This composite approach leverages the complementary properties of both components: the substrate provides geometric resonance for frequency selection, while the ENZ layer enhances absorption and emission at the resonant frequencies, achieving narrowband, temperature-stable thermal emission.

Inventive Principle:
Principle #40Composite materials

2Adaptability or versatility

If ENZ material layer is added to patterned substrate, then tunable narrowband emissivity is achieved, but device structure becomes more complex

Engineering Contradiction:
Improveemissivity tunabilityVSAvoidstructure complexity
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The patent utilizes parameter changes by varying the ENZ material properties (such as doping concentration or layer thickness) to tune the emissivity characteristics. This allows adjustment of the emission wavelength and bandwidth without fundamentally changing the overall device structure, maintaining simplicity while achieving adaptability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The ENZ material layer acts as an intermediary between the patterned substrate and the emitted radiation. It enhances the electromagnetic field interaction at the substrate resonances, converting the geometric resonance into enhanced absorption and emission while maintaining a relatively simple layered structure.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Ease of operation

If conventional thermal emission is used, then broadband omnidirectional light emission is achieved, but controlled spectral output cannot be obtained

Engineering Contradiction:
Improveemission controlVSAvoidspectral distribution
Core Design Contradiction:
Ease of operationVSIllumination intensity

Solution Approach 1:

The patent segments the emission spectrum by using the patterned substrate to create discrete resonant frequencies. Instead of continuous broadband emission, the structure produces distinct spectral lines at specific wavelengths, enabling controlled spectral output while maintaining ease of operation through simple thermal heating.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patterned substrate incorporates curved or rounded geometric features (such as spherical holes or cylindrical pillars) that support specific resonant modes. These curved structures enable directional control and spectral selectivity in the emission pattern, allowing controlled spectral output while maintaining operational simplicity.

Inventive Principle:
Principle #14Spheroidality (Curvature)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This solution achieves tunable narrowband emissivity/absorptivity for unpolarized light, allowing access to emissivity/absorptivity at incident light angles around the surface normal and beyond, with distinct maxima in the emissivity/absorptivity at designed wavelengths, effectively creating a non-blackbody thermal emission spectrum.

Implementation Method 1

a layer comprising a material having an Epsilon-Near-Zero (ENZ) condition for a wavelength range... supporting ENZ absorption modes, allowing for tunable emissivity/absorptivity characteristics by focusing electromagnetic radiation within the material's volume

Methodology Applied
Scientific EffectEpsilon-Near-Zero (ENZ) absorption modes: Absorption (EM radiation)

Implementation Method 2

the pattern of surface features is configured to orient the layer such that emissivity/absorptivity thereof in the wavelength range is substantially independent of a polarization and/or an angle of radiation

Methodology Applied
Scientific EffectPolarization independence through surface feature orientation: Polarisation

Implementation Method 3

Objects at temperatures above absolute zero (0K) radiate electromagnetic energy... described by Planck's law of thermal radiation

Methodology Applied
Scientific EffectThermal radiation: Thermal Radiation

Implementation Method 4

Kirchoff's law of thermal radiation links the emissivity and absorption of an object at thermal equilibrium. For a given energy, the emissivity of an object is equal to its absorption

Methodology Applied
Scientific EffectKirchoff's law of thermal radiation: Absorption (EM radiation)

Data Source

PatentUS12019208B2Surface with tunable emissivity based on epsilon-near-zero materials and patterned substrates
Publication Date: 2024.06.25 THIRD FLOOR MATERIALS INC
  • US12019208B2 patent drawing
  • US12019208B2 patent drawing
  • US12019208B2 patent drawing

AI summary

A device includes a substrate having a pattern of surface features on a surface thereof, and a layer including a material having an Epsilon-Near-Zero (ENZ) condition for a wavelength range. The layer extends on the surface of the substrate and along the pattern of surface features. Related devices and fabrication methods are also discussed.