Enzymatic Hydrolysis of Spent Coffee Grounds for High Yield

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Solution Overview

Problem

Current methods for producing instant coffee face challenges in achieving high yield while minimizing the consumption of green coffee beans and reducing the production of off-flavors and toxic substances, particularly due to high temperature hydrolysis methods that lead to decomposition products like 5-HMF, which inhibit enzyme activity and affect aroma retention.

Innovation Solution

A process involving low-temperature extraction of roasted and ground coffee beans with water at 80°C or less, followed by steam explosion and enzymatic hydrolysis using carbohydrate and carboxylic ester hydrolysing enzymes, with optional pre-treatment and post-treatment steps to enhance enzyme accessibility and activity, and the use of coffee-derived surfactants to improve yield and aroma preservation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If wet thermal hydrolysis is performed at elevated temperatures (180°C or above) to increase yield, then the amount of hydrolysis products increases, but off-flavours, toxic substances, and degradation of solubilised components are produced

Engineering Contradiction:
Improveyield of hydrolysis productsVSAvoidoff-flavours and toxic substances
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the temperature parameter from high (180°C or above) to low (below 100°C) to resolve the contradiction. This parameter change allows the hydrolysis process to proceed at temperatures that prevent the formation of off-flavours and toxic substances while still achieving effective breakdown of polymeric carbohydrates through enzymatic action

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces the thermal mechanism (high-temperature hydrolysis) with an enzymatic mechanism. Instead of using heat to break down carbohydrates, the invention uses enzymes such as mannanases, cellulases, and hemicellulases to catalyze the hydrolysis reaction at low temperatures, thereby avoiding the harmful effects of high temperature while maintaining high productivity

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Productivity

If high temperature hydrolysis is used to increase yield, then more solubilised components are recovered, but enzyme activity is inhibited by decomposition products like 5-HMF

Engineering Contradiction:
Improveyield of solubilised componentsVSAvoidenzyme activity
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent changes the temperature parameter to below 100°C, which prevents the formation of decomposition products like 5-HMF that would otherwise inhibit enzyme activity. This parameter change ensures that enzyme activity is maintained throughout the hydrolysis process while still achieving high yield of solubilised components

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies preliminary action by pre-treating the coffee grounds with steam or other methods before enzymatic hydrolysis to make the polymeric carbohydrates more accessible to enzymes. This preliminary treatment enhances enzyme efficiency and yield without requiring high temperatures that would produce inhibitory decomposition products

Inventive Principle:
Principle #10Preliminary action

3Productivity

If traditional extraction methods are used, then the process is simple, but the yield of total solids is limited to 50-60%

Engineering Contradiction:
Improveyield of total solidsVSAvoidprocess complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent segments the extraction process into multiple sequential steps: initial water extraction, steam explosion pre-treatment, and enzymatic hydrolysis. Each step targets different components of the coffee grounds, progressively increasing the overall yield of total solids from the initial 50-60% to 65% or more by recovering additional solids that would otherwise remain trapped in the grounds

Inventive Principle:
Principle #1Segmentation

4Quantity of substance

If green bean consumption is reduced to lower production cost, then the amount of coffee beans used decreases, but maintaining high yield becomes more challenging

Engineering Contradiction:
Improvegreen bean consumptionVSAvoidyield per kg of green beans
Core Design Contradiction:
Quantity of substanceVSProductivity

Solution Approach 1:

The patent changes the extraction parameters (temperature, use of steam explosion, enzymatic treatment) to maximize the recovery of solids from each kilogram of green beans. These parameter changes enable the process to achieve 65% or more yield, meaning less than 1.54 kg of green beans are needed per kg of final product, thereby reducing green bean consumption while maintaining high productivity

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This process achieves a high yield of instant coffee with reduced production of decomposition products, higher retention of aroma compounds, and improved enzyme activity, resulting in a higher yield of total solids (up to 75% or more) with better flavor preservation.

Implementation Method 1

Extracting roast and ground coffee beans with water having a temperature of 80°C or less, to produce a first extract

Methodology Applied
Scientific EffectExtraction:

Implementation Method 2

steam exploding the spent coffee grounds, wherein the steam explosion is performed in the temperature range of 50-170°C, at a pressure of 0.1 to 10 bar for 0.1 to 5 hours

Methodology Applied
Scientific EffectSteam explosion: Steam Explosion

Implementation Method 3

Hydrolysing the aqueous suspension using a hydrolysing enzyme to produce a second extract

Methodology Applied
Scientific EffectEnzymatic hydrolysis: Hydrolysis

Implementation Method 4

carbohydrate and carboxylic ester hydrolysing enzymes

Methodology Applied
Scientific EffectEnzyme: Enzyme

Implementation Method 5

coffee-derived surfactants which are provided by alkaline catalysed transesterification reactions of sugars and coffee oil

Methodology Applied
Scientific EffectSurfactant: Surfactant

Data Source

PatentEP3166417B2Production of an instant coffee product in high yield
Publication Date: 2023.09.20 GEA PROCESS ENG

AI summary

Disclosed herein is a process for production of an instant coffee product in a high yield, comprising the steps of extracting roast and ground coffee beans with water having a temperature of 80°C or less, to produce a first extract and spent coffee grounds, adding water to the spent coffee grounds to produce an aqueous suspension, hydrolysing the aqueous suspension using a hydrolysing enzyme to produce a second extract and spent remains, adding the first extract to the second extract, optionally after concentration and/or drying of the second extract, to obtain a combined extract, and drying the combined extract to obtain an instant coffee product. The high yield is obtained due to the reduction of enzyme inhibiting substances.