Enzyme-Treated Starch Granules for Gel Strength

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Solution Overview

Problem

Current methods for enhancing the gel forming and thickening properties of starch in food products are limited, as chemical modifications are restricted and enzymatic treatments typically degrade the starch's functionality, while existing combinations of gelling agents often fail to synergistically improve gel strength and exhibit undesirable textures or flavors.

Innovation Solution

Treating starch granules with specific hydrolytic enzymes like amyloglucosidase or glycosyltransferase under controlled conditions without dissolving them, followed by mixing with food materials and heating, to produce enzyme-treated starch granules with enhanced gel forming and thickening abilities.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If chemical modification of starch is performed to enhance gel forming ability, then gel strength is improved, but safety restrictions and processing complexity increase

Engineering Contradiction:
Improvegel strengthVSAvoidsafety restrictions
Core Design Contradiction:
StrengthVSObject-affected harmful factors

Solution Approach 1:

The patent replaces chemical modification methods with enzymatic treatment using starch hydrolases or glycosyltransferases. This substitution eliminates the need for chemical reagents and their associated safety restrictions while achieving enhanced gel forming ability through controlled enzymatic action on starch granules.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the processing parameters from chemical modification to enzymatic treatment conditions, including controlling temperature (10-70°C), pH, and enzyme concentration. This parameter change enables safe processing without chemical modifications while maintaining or enhancing gel strength.

Inventive Principle:
Principle #35Parameter changes

2Strength

If starch is treated with hydrolytic enzymes to improve gel forming ability, then gel strength and viscosity are enhanced, but starch functionality may be degraded

Engineering Contradiction:
Improvegel forming abilityVSAvoidstarch functionality
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent applies partial enzymatic hydrolysis rather than complete degradation. By controlling the enzyme treatment conditions (enzyme type, concentration, temperature, time), only partial hydrolysis occurs on the starch granule surface, enhancing gel forming ability while preserving the core starch functionality and structure.

Inventive Principle:
Principle #16Partial or excessive action

Solution Approach 2:

The enzymatic treatment creates local quality changes on the starch granule surface while preserving the bulk properties. The enzyme acts locally on the granule surface to create enhanced gel forming regions without degrading the overall starch molecule integrity, thus maintaining functionality.

Inventive Principle:
Principle #3Local quality

3Strength

If multiple gelling agents are combined to synergistically improve gel strength, then gel characteristics are enhanced, but complexity and cost increase

Engineering Contradiction:
Improvegel strengthVSAvoidprocess complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent makes a single ingredient (enzyme-treated starch) perform multiple functions: it provides thickening, gel forming, and texture improvement properties that would traditionally require multiple different gelling agents. This eliminates the need for complex combinations of agar, gelatin, gums, and other gelling agents.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent merges the functions of multiple gelling agents into a single modified starch product. The enzymatic treatment integrates thickening and gel forming capabilities into one ingredient, simplifying the formulation process and reducing the number of components required.

Inventive Principle:
Principle #5Merging (Combining)

4Strength

If crosslinked starch with high crosslinking degree is added to enhance gel hardness, then gel hardness is improved, but texture becomes powdery and flavor deteriorates

Engineering Contradiction:
Improvegel hardnessVSAvoidpowdery texture
Core Design Contradiction:
StrengthVSObject-generated harmful factors

Solution Approach 1:

The patent replaces chemical crosslinking with enzymatic treatment. This substitution achieves gel hardening through controlled enzymatic modification rather than chemical crosslinking, avoiding the formation of excessive rigid structures that cause powdery texture and flavor deterioration.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the modification approach from high-degree chemical crosslinking to controlled enzymatic treatment. By adjusting enzyme concentration, treatment time, and temperature, the gel hardness is optimized without exceeding the threshold that would cause textural defects.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resulting enzyme-treated starch granules exhibit high viscosity and form harder gels with improved texture and elasticity, suitable for various food applications without the need for chemical modifications, offering flexibility in food formulation and safety.

Implementation Method 1

treating starch granules with a starch hydrolase or a glycosyltransferase in advance

Methodology Applied
Scientific EffectEnzymatic hydrolysis: Hydrolysis

Implementation Method 2

utilizing an enzyme having characteristics capable of improving a gel forming ability of a starch

Methodology Applied
Scientific EffectEnzyme catalysis: Enzyme

Implementation Method 3

heating the mixture thereby gelatinizing the enzyme-treated starch granules in the mixture

Methodology Applied
Scientific EffectGelatinization: Phase Change

Implementation Method 4

cooling the mixture containing the gelatinized enzyme-treated starch thereby gelling the starch

Methodology Applied
Scientific EffectGelation: Gel

Implementation Method 5

The resulting enzyme-treated starch granules exhibit high viscosity and form harder gels

Methodology Applied
Scientific EffectThickening: Viscometer

Data Source

PatentUS9963581B2Food product containing starch gel, starch granule, production method and use thereof
Publication Date: 2018.05.08 GLICO NUTRITION
  • US9963581B2 patent drawing
  • US9963581B2 patent drawing

AI summary

Here is provided a method of producing a starch gel-containing food, the method comprising the steps of: treating starch granules with an enzyme at a temperature of about 10° C. or higher and about 70° C. or lower to obtain an enzyme-treated starch; mixing a food material, the enzyme-treated starch and water to obtain a mixture; heating the mixture thereby gelatinizing the enzyme-treated starch in the mixture; and cooling the mixture containing the gelatinized enzyme-treated starch thereby gelling the starch to obtain a starch gel-containing food, wherein the enzyme is selected from the group consisting of amyloglucosidase, isoamylase, α-glucosidase, α-amylase having a characteristic capable of improving a gel forming ability of a starch, and cyclodextrin glucanotransferase.