EPEI Stabilizer in High Anionic Liquid Laundry Compositions

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Solution Overview

Problem

Existing liquid laundry compositions face challenges in being physically stable, environmentally friendly, and cost-effective, particularly for high anionic, high foaming compositions, where traditional stabilizers like hydrotropes or nonionic surfactants can negatively impact foamability and chemical usage.

Innovation Solution

Increasing the level of EPEI (ethoxylated polyethyleneimine) above 2% weight percentage allows for a reduction in non-ionic surfactant levels without affecting foamability, maintaining isotropic phase behavior and stability in a concentrated liquid laundry composition.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If traditional stabilizers like hydrotropes or nonionic surfactants are used to stabilize high anionic compositions, then physical stability is improved, but foamability is negatively impacted

Engineering Contradiction:
Improvephysical stabilityVSAvoidnegative impact on foamability
Core Design Contradiction:
Stability of the object's compositionVSObject-generated harmful factors

Solution Approach 1:

The patent changes the chemical parameter by substituting traditional stabilizers (hydrotropes and nonionic surfactants) with EPEI (ethoxylated polyethyleneimine). This parameter change maintains physical stability through a different mechanism that does not interfere with foam generation, thereby resolving the contradiction between stability and foamability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs EPEI as a more cost-effective stabilizing agent compared to traditional nonionic surfactants and hydrotropes. This substitution reduces chemical usage costs while avoiding the foamability suppression issues associated with conventional stabilizers

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Stability of the object's composition

If high levels of nonionic surfactants are used to stabilize concentrated liquid laundry composition, then isotropic phase behavior is maintained, but chemical usage increases and foamability is reduced

Engineering Contradiction:
Improveisotropic phase behaviorVSAvoidchemical usage
Core Design Contradiction:
Stability of the object's compositionVSQuantity of substance

Solution Approach 1:

The patent extracts or removes nonionic surfactants from the formulation by replacing them with EPEI. This extraction eliminates the need for high levels of nonionic surfactants while maintaining isotropic phase behavior through the stabilizing properties of EPEI, thereby reducing overall chemical usage

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

EPEI serves multiple functions in the composition: it acts as a stabilizer maintaining isotropic phase behavior, a foam booster enhancing foamability, and a cost-effective alternative to traditional surfactants. This multi-functionality allows the formulation to achieve stability without relying on high levels of nonionic surfactants

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Object-generated harmful factors

If concentrated liquid laundry composition is formulated with high anionic content for high foaming performance, then foamability is improved, but physical stability becomes challenging to maintain

Engineering Contradiction:
ImprovefoamabilityVSAvoidphysical stability
Core Design Contradiction:
Object-generated harmful factorsVSStability of the object's composition

Solution Approach 1:

EPEI acts as an intermediary substance that mediates between the high anionic surfactant content and the physical stability requirement. It provides the necessary stabilization mechanism that allows high anionic formulations to maintain both their high foaming performance and physical stability without contradiction

Inventive Principle:
Principle #24Intermediary (Mediator)

Data Source

PatentEP4305140B1composition
Publication Date: 2024.07.17 UNILEVER IP HLDG BV
  • EP4305140B1 patent drawing
  • EP4305140B1 patent drawing
  • EP4305140B1 patent drawing

AI summary

A concentrated liquid laundry composition comprising at least 2.0% wt. a polyamine cleaning polymer, from 30 to 35% wt. of the composition anionic surfactant, optional non-ionic surfactant, and water and wherein the non-ionic surfactant, it is present at less than 10% wt. of the total weight of non-ionic surfactant and anionic surfactant.