Ephedrine Formulation pH Stability and Ready-to-Administer Design

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Solution Overview

Problem

Existing injectable ephedrine formulations are not stable and require dilution before administration, leading to pH instability and potential degradation during storage.

Innovation Solution

A stable, ready-to-administer formulation comprising ephedrine sulfate, a tonicity agent, and a citrate buffer, with a pH of 5.2 to 5.4, which maintains a pH drift of less than 0.3 units after storage for at least 6 months at room temperature.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If ephedrine is formulated as a ready-to-administer injectable solution, then convenience of administration is improved, but pH stability deteriorates during storage

Engineering Contradiction:
Improvereadiness for administrationVSAvoidpH stability
Core Design Contradiction:
Ease of operationVSStability of the object's composition

Solution Approach 1:

The patent applies parameter changes by optimizing the pH range to 4.5-5.5 and controlling buffer concentration (1-10 mM citrate buffer) to achieve both readiness for administration and long-term pH stability. This resolves the contradiction by finding the optimal parameter window where the formulation remains stable during storage while requiring no dilution before use.

Inventive Principle:
Principle #35Parameter changes

2Ease of operation

If ephedrine formulation is stored at room temperature for long durations, then accessibility and ease of use are improved, but pH drift and degradation increase

Engineering Contradiction:
Improvestorage accessibilityVSAvoidpH stability
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The formulation incorporates citrate buffer and tonicity agents during manufacturing to pre-establish pH stability before storage. This preliminary action ensures that when the product is stored at room temperature for extended periods, the pH remains stable within 0.3 units drift, maintaining reliability without requiring refrigeration or special storage conditions.

Inventive Principle:
Principle #10Preliminary action

3Quantity of substance

If ephedrine sulfate is used at higher concentrations, then therapeutic effectiveness is improved, but impurity formation increases during storage

Engineering Contradiction:
Improveephedrine concentrationVSAvoidimpurity formation
Core Design Contradiction:
Quantity of substanceVSObject-generated harmful factors

Solution Approach 1:

The citrate buffer acts as an intermediary that stabilizes the pH environment, preventing ephedrine degradation and impurity formation even at therapeutic concentrations of 5 mg/mL. The buffer mediates between the ephedrine sulfate and the aqueous environment, maintaining pH within the stable range and minimizing harmful degradation products during long-term storage.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The formulation maintains stability and potency of ephedrine, with minimal impurity formation and pH stability, allowing for direct administration without prior dilution.

Implementation Method 1

a citrate buffer, with a pH of 5.2 to 5.4, which maintains a pH drift of less than 0.3 units after storage for at least 6 months

Methodology Applied
Scientific EffectBuffering:

Implementation Method 2

a tonicity agent

Methodology Applied
Scientific EffectOsmotic pressure: Osmotic Pressure

Data Source

PatentEP4440559B1Ephedrine liquid formulations
Publication Date: 2025.12.31 FRESENIUS KABI AUSTRIA GMBH
  • EP4440559B1 patent drawingFigure 1
  • EP4440559B1 patent drawingFigure 2
  • EP4440559B1 patent drawing

AI summary

The present invention provides a formulation that includes a therapeutically effective amount of ephedrine or a pharmaceutically acceptable salt thereof, and a method for preparing the formulation. In some embodiments, the formulation includes a tonicity agent, a citrate buffer, water, and has a pH of about 5.2-5.4. The formulation of the invention is stable and ready-to-administer.