Epitaxy Template Design for Block Copolymer Lithography Placement Error

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Solution Overview

Problem

Current lithography methods face challenges in achieving precise placement and high resolution of nano-scale features on substrates, leading to defects and placement errors in self-assembled block copolymer patterns, which are critical for advanced device manufacturing.

Innovation Solution

A method is developed to design an epitaxy template using computer-aided optimization techniques, incorporating random error simulation to improve pattern fidelity statistics, allowing for accurate placement and reduced defects in self-assembled block copolymer patterns on substrates, thereby enhancing the precision of lithography features.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional lithography methods are used to pattern substrates, then manufacturing processes are well-established, but feature size reduction and placement precision are limited at nano-scale

Engineering Contradiction:
Improveplacement precisionVSAvoidprocess complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent applies preliminary action by pre-patterning the substrate with an epitaxy template before block copolymer deposition. The template is designed with optimized geometries (e.g., rounded corners, adjusted pitch) that guide the self-assembly process to achieve precise feature placement and reduce defects, thereby improving manufacturing precision without requiring complex real-time control during polymerization.

Inventive Principle:
Principle #10Preliminary action

2Manufacturing precision

If epitaxy templates are used to direct block copolymer self-assembly, then placement accuracy improves, but random errors and defects still occur in patterns

Engineering Contradiction:
Improvepattern fidelityVSAvoidpattern defect rate
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent applies parameter changes by systematically optimizing template design parameters such as feature pitch, corner radius, and geometry to account for and compensate for random errors during self-assembly. By adjusting these parameters, the template design achieves robustness against variations, improving pattern fidelity and reducing defect rates while maintaining placement accuracy.

Inventive Principle:
Principle #35Parameter changes

3Area of moving object

If feature size is reduced to increase density, then substrate capacity increases, but placement errors and defects increase

Engineering Contradiction:
Improvefeature densityVSAvoidplacement accuracy
Core Design Contradiction:
Area of moving objectVSManufacturing precision

Solution Approach 1:

The patent applies preliminary action by pre-designing epitaxy templates with optimized geometries specifically tailored for high-density nanoscale patterning. The templates incorporate features like rounded corners and adjusted pitch that guide block copolymer self-assembly to achieve precise placement even at reduced feature sizes, thereby enabling high feature density without sacrificing placement accuracy.

Inventive Principle:
Principle #10Preliminary action

4Ease of manufacture

If standard epitaxy template designs are used, then manufacturing is simpler, but placement errors occur due to random errors in self-assembly

Engineering Contradiction:
Improvetemplate fabricationVSAvoidplacement precision
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent applies parameter changes by optimizing template design parameters such as feature pitch, corner radius, and geometry to compensate for random errors during self-assembly. These optimized parameters are integrated into standard fabrication workflows, maintaining ease of manufacture while significantly improving placement precision and reducing placement errors in the final patterns.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The optimized epitaxy template design significantly improves the placement accuracy and pattern fidelity of self-assembled block copolymer patterns, reducing defects and ensuring precise alignment with target patterns, which is essential for advanced nanofabrication applications.

Implementation Method 1

A self-assemblable block copolymer is a compound useful in nanofabrication because it may undergo an order-disorder transition on cooling below a certain temperature (order-disorder transition temperature TOD) resulting in phase separation of copolymer blocks

Methodology Applied
Scientific EffectOrder-disorder transition: Phase Change

Implementation Method 2

An example of a suitable block copolymer is, for instance, a polymer having covalently linked blocks of polystyrene (PS) monomer (hydrophobic block) and polymethylmethacrylate (PMMA) monomer (hydrophilic block)

Methodology Applied
Scientific EffectHydrophobic-hydrophilic interaction: Hydrophobe

Implementation Method 3

The self-assembly of the block copolymer may be directed by an epitaxy template with a pattern on a substrate

Methodology Applied
Scientific EffectChemical epitaxy: Epitaxy

Data Source

PatentUS10551736B2Methods for providing lithography features on a substrate by self-assembly of block copolymers
Publication Date: 2020.02.04 ASML NETHERLANDS BV
  • US10551736B2 patent drawing
  • US10551736B2 patent drawing
  • US10551736B2 patent drawing

AI summary

A method of designing an epitaxy template to direct self-assembly of a block copolymer on a substrate into an ordered target pattern involves providing a primary epitaxy template design and then varying the design to optimize a pattern fidelity statistic, such as placement error, relative to the target pattern by modelling predicted self-assembled block copolymer patterns and optimizing pattern placement as a function of a varied design parameter. In addition to varying a design parameter to optimize the pattern fidelity statistic, a random error in the template design is included prior to modelling predicted patterns in order to compensate for expected template inaccuracy in practice. The inclusion of a realistic random error in the template design, in addition to systematic variation of a design parameter, may improve the template design optimization to render the result less sensitive to error which may be inevitable in practice.