Epoxy Coating with Additives for Icephobic Aircraft Surfaces

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Solution Overview

Problem

Current anti-icing coatings lack the necessary durability to persist on aerospace and maritime surfaces, leading to inefficiencies and safety concerns due to ice accretion, which requires energy-intensive active strategies like heated surfaces and pneumatic boots, increasing fuel burn and maintenance complexity.

Innovation Solution

Development of an epoxy coating with additives such as holey graphene and core-shell rubber particles, along with polyhedral oligomeric silsesquioxane, that improves abrasion resistance and reduces ice adhesion shear stress, providing a durable and energy-efficient passive anti-icing solution.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If active anti-icing strategies (heated surfaces, pneumatic boots) are used, then ice accretion is prevented, but energy consumption increases and maintenance complexity increases

Engineering Contradiction:
Improveice prevention effectivenessVSAvoidfuel burn
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The patent replaces active mechanical/thermal anti-icing systems (heated surfaces, pneumatic boots) with a passive chemical coating system. The epoxy coating with icephobic additives creates a surface that inherently prevents ice adhesion through chemical and physical mechanisms rather than requiring external energy input for mechanical or thermal intervention.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The coating system provides self-service anti-icing functionality by creating a durable surface that automatically prevents ice adhesion without requiring external energy input or active control systems. The coating's inherent icephobic properties continuously protect the surface passively.

Inventive Principle:
Principle #25Self-service

2Reliability

If active anti-icing strategies (heated surfaces, pneumatic boots) are used, then ice accretion is prevented, but manufacturing complexity increases and maintenance complexity increases

Engineering Contradiction:
Improveice prevention effectivenessVSAvoidmanufacturing complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent replaces complex mechanical anti-icing systems (heated surfaces with thermal management systems, pneumatic boots with air supply systems) with a simple coating application process. The epoxy coating can be applied using standard coating techniques, eliminating the need for complex manufacturing infrastructure.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Strength

If conventional epoxy coatings are used, then basic protection is provided, but abrasion resistance is insufficient and ice adhesion remains high

Engineering Contradiction:
Improvebasic coating protectionVSAvoidabrasion resistance
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent creates a composite epoxy coating by incorporating icephobic additives (such as hydrophobic particles, nanomaterials, or chemically modified compounds) into the epoxy matrix. This composite structure combines the adhesive strength and durability of epoxy with the ice-repelling properties of the additives, achieving both high abrasion resistance and low ice adhesion.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The epoxy coating significantly enhances durability and reduces ice adhesion, allowing for effective ice shedding without energy input, thus addressing the limitations of existing coatings and strategies by providing a long-lasting, efficient anti-icing solution.

Implementation Method 1

the additive may cause a reduction of an ice adhesion shear stress by at least 35 percent as compared to the epoxy resin alone

Methodology Applied
Scientific EffectIce adhesion reduction:

Implementation Method 2

the additive improves an abrasion resistance of the epoxy resin by at least 40 percent

Methodology Applied
Scientific EffectAbrasion resistance enhancement:

Implementation Method 3

the additive may cause a reduction in a wear index of at least 50 percent as compared to the epoxy resin alone

Methodology Applied
Scientific EffectWear resistance enhancement:

Data Source

PatentUS11746183B2Durable contamination resistant coatings
Publication Date: 2023.09.05 UNITED STATES OF AMERICA AS REPRESENTED BY THE ADMINISTRATOR NAT AERONAUTICS & SPACE ADMINISTRATION
  • US11746183B2 patent drawing
  • US11746183B2 patent drawing
  • US11746183B2 patent drawing

AI summary

In an illustrative example, one or more coating formulations may be used and may have characteristics useful in different situations. During evaluations, a plurality of coating formulations comprising epoxy resins and diamine hardeners were prepared and evaluated with regards to impact ice adhesion strength and durability. Alone, such coating formulations provided a significantly reduced impact ice adhesion strength as compared to uncoated aluminum and/or stainless steel surfaces. However, a durability of the coatings, when applied to aluminum or stainless steel surfaces, was insufficient to be considered for use on external aircraft surfaces. By including nano-sized and/or micro-sized particles as additives to the coating formulations, resulted in improved durability without significantly reducing ice adhesion performance of the resin base.