Mesogenic Siloxane Epoxy Resin for Heat Conduction and Adhesion

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Solution Overview

Problem

Electronic component devices face challenges with heat dissipation due to low heat conductivity of cured thermosetting resin products and are prone to warping, leading to detachment issues due to thermal stress.

Innovation Solution

Development of an epoxy resin with a mesogenic and siloxane structure, which combines high heat conductivity with low elasticity, achieved through specific molecular formulations and curing processes, forming high-order structures that enhance thermal management and adhesion.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If a cured product of a thermosetting resin is used for heat dissipation, then heat conductivity is required to be improved, but the inherent low heat conductivity of conventional thermosetting resin cured products prevents effective heat dissipation

Engineering Contradiction:
Improveheat conductivityVSAvoidheat dissipation capability
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

The patent changes the molecular structure parameters of the epoxy resin by introducing mesogenic groups (rigid aromatic structures) and siloxane bonds into the molecular chain. This structural modification enables the cured product to achieve high heat conductivity while maintaining the thermosetting resin's beneficial properties, directly resolving the heat dissipation problem

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite molecular structure combining epoxy resin with mesogenic groups and siloxane bonds. This composite approach integrates the heat-resistant and adhesive properties of epoxy resin with the high heat conductivity and flexibility of mesogenic and siloxane structures, achieving both thermal management and mechanical stability

Inventive Principle:
Principle #40Composite materials

2Volume of moving object

If the electronic component device is made thinner, then miniaturization is achieved, but the difference in thermal expansion coefficient between chip and substrate causes warping and detachment

Engineering Contradiction:
Improvedevice thicknessVSAvoidstructural stability under thermal stress
Core Design Contradiction:
Volume of moving objectVSStability of the object's composition

Solution Approach 1:

The patent modifies the elasticity parameter of the cured product by incorporating siloxane bonds, which provide flexible Si-O-Si linkages in the molecular chain. This increases the elasticity and flexibility of the cured product, enabling it to withstand thermal expansion differences and prevent warping and detachment in thin devices

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a flexible cured product structure through siloxane incorporation that can accommodate dimensional changes and stress in thin electronic devices. The flexible molecular structure acts as a buffer against thermal stress, preventing warping and maintaining adhesion in miniaturized devices

Inventive Principle:
Principle #30Flexible shells and thin films

3Stability of the object's composition

If the elasticity of the cured product is decreased to suppress detachment, then adhesion stability is improved, but the heat conductivity must be maintained at high levels

Engineering Contradiction:
Improveadhesion stabilityVSAvoidheat conductivity
Core Design Contradiction:
Stability of the object's compositionVSTemperature

Solution Approach 1:

The patent merges multiple functional groups into a single epoxy resin molecule: mesogenic groups for heat conductivity, siloxane bonds for elasticity and flexibility, and epoxy groups for crosslinking and adhesion. This combination achieves both high heat conductivity and low elasticity simultaneously, resolving the contradiction between thermal management and adhesion stability

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent designs an epoxy resin with multi-functionality: the mesogenic structure provides heat conduction pathways, the siloxane bonds provide flexibility and stress relief, and the epoxy groups provide crosslinking and adhesion. This multi-functional molecule addresses multiple requirements (heat dissipation, flexibility, adhesion) simultaneously

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The epoxy resin composition effectively improves heat conductivity and reduces the likelihood of detachment from electronic components, addressing both thermal management and mechanical stability concerns.

Implementation Method 1

the epoxy resin composition, a resin sheet, a B-stage sheet, a C-stage sheet, a cured product... having a mesogenic structure... capable of forming a high order structure

Methodology Applied
Scientific EffectSelf-assembly: Self-Assembly

Implementation Method 2

an object of the present invention is to provide an epoxy resin which cured product is superior in heat conductivity, and capable of achieving a low elasticity

Methodology Applied
Scientific EffectElasticity: Elasticity

Data Source

PatentUS11795293B2Epoxy resin, epoxy resin composition, resin sheet, B-stage sheet, C-stage sheet, cured product, metal foil with resin, metal substrate, and power semiconductor device
Publication Date: 2023.10.24 RESONAC CORP
  • US11795293B2 patent drawing
  • US11795293B2 patent drawing
  • US11795293B2 patent drawing

AI summary

An epoxy resin has a mesogenic structure and a siloxane structure. An epoxy resin composition includes the epoxy resin having the mesogenic structure and the siloxane structure, and a curing agent.